C5350 Analytical Chemistry III

Faculty of Science
Autumn 2003
Extent and Intensity
2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).
Teacher(s)
prof. RNDr. Josef Havel, DrSc. (lecturer)
prof. RNDr. Přemysl Lubal, Ph.D. (lecturer)
Guaranteed by
prof. RNDr. Josef Havel, DrSc.
Chemistry Section – Faculty of Science
Prerequisites (in Czech)
C4050 Analytical Chemistry II
Předpokladem je úspěšné absolvování předmětů Analytická chemie I (C3100), Analytická chemie II (C4050) a příslušných laboratorních cvičení z analytické chemie (C3120 a C4190).
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
Course objectives
The course consisting of closed lectures introduces students with advanced analytical techniques and is upgrade to basic courses Analytical chemistry I a Analytical chemistry II. The new trends in analytical chemistry (development of instrumentation, methodology) are presented in lecture. In addition, the interdisciplinary character of present-day analytical chemistry is stressed. The lecture is documented by numerous examples taken from literature or practice.
Syllabus
  • 1. Kinetic methods of chemical analysis. Theory - knowledge of basic terms and their use in analytical chemistry. Instrumentation and their use for analysis.
  • 2. Examples of determination of inorganic and organic compounds. Examples of determination of biochemical compounds. Use of chemometric algorithms, computer applications.
  • 3. Chemical analysis in mixed and non-aqueous solutions. Titration in mixed and non-aqueous milieus, two-phase titration. Application of tenzides in analytical chemistry.
  • 4. Examples of optimisation of analytical methods (use of chemical modeling and chemometrics).
  • 5. Modern trends in chemical analysis (use of computers in "multi-array" data collection and their treatment, joining of analytical techniques - "hyphenated" techniques, miniaturisation, automation).
  • 6. Advanced optical methods and their use in analytical chemistry. Laser analytical spectroscopy - Properties and types of lasers. Analytical interaction of laser beam with matter. Linear methods - examples, optoacoustic, LIF spectroscopy, etc. Nonlinear methods. Special methods - detection of trace amounts, time-resolved spectroscopy, LIDAR far detection.
  • 7. Survey of instrumental methods suitable for organic analysis (Raman, IR, NMR spectroscopy, MS spectrometry, polarimetry, spectropolarimetry a CD spectrometry, refractometry a interferometry) and examples of use.
  • 8. Modern separation methods. Preconcentration of samples - Solid Phase Extraction (SPE). Membrane separation - ultrafiltration , dialysis, elektrodialysis, reverse osmosis. Methods with supercritical state of matter - extraction, chromatography. FFF methods.
  • 9. Analytical methods using radioisotopes. Basic terms. Methods. Description of methods and their use in practice.
  • 10. Surface analysis. Laser ablation. Techniques with photon probe (PES, XPS, UPS, LAMMS, etc.). Techniques with electron probe (EPXMA, SEM, kombinovaná AEM, AES, etc).
  • 11. Techniques with ion probe (RBS, ISS, SIMS, etc.). Techniques with pole probe (FIM, etc.). Microscopy with scanning probe (STM, AFM, etc.).
  • 12. Analytical X-ray spectrometry and their use in structural analysis.
Literature
  • Analytická příručka. Díl I [Zýka, 1988]. Edited by Jaroslav Zýka. 4. upr. vyd. Praha: SNTL - Nakladatelství technické literatury, 1988, 678 s. info
  • Analytická příručka. Edited by Jaroslav Zýka. 4., upr. vyd. Praha: SNTL - Nakladatelství technické literatury, 1988, 831 s. info
  • Sommer L., Základy analytické chemie II, VUTium Brno 2000.
  • HARRIS, Daniel C. Quantitative chemical analysis. 4th ed. New York: W.H. Freeman, 1995, xix, 837 s. ISBN 0-7167-2508-8. info
  • Kellner R., Mermet J.-M., Otto M., Widmer H. M., Analytical Chemistry, Wiley 1998.
  • Aktuální publikace pro dané odvětví (Talanta, Analytica Chimica Acta, Fresenius Journal of Analytical Chemistry, Analytical Chemistry, aj.)
Assessment methods (in Czech)
Znalosti získané na přednášce jsou prověřovány kombinovanou zkouškou(písemná a ústní část).
Language of instruction
Czech
Further comments (probably available only in Czech)
The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.
Listed among pre-requisites of other courses
The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.
  • Enrolment Statistics (Autumn 2003, recent)
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