PřF:C7999 Advanced Methods of NMR - Course Information
C7999 Advanced Methods of NMR Spectroscopy
Faculty of ScienceAutumn 2003
- Extent and Intensity
- 0/0/2. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: k (colloquium). Other types of completion: zk (examination), z (credit).
- Teacher(s)
- RNDr. Dalibor Dastych, Dr. (seminar tutor)
prof. RNDr. Radek Marek, Ph.D. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor) - Guaranteed by
- prof. RNDr. Radek Marek, Ph.D.
Chemistry Section – Faculty of Science
Contact Person: prof. RNDr. Radek Marek, Ph.D. - Prerequisites (in Czech)
- Kurz je určen studentům kateder anorganické a organické chemie. Podmínkou účasti je absolvování jedné z následujících přednášek: NMR - Strukturní analýza C8950, Multinukleární NMR spektroskopie C 6800 nebo Fyzikálně chemické základy NMR C5320
- Course Enrolment Limitations
- The course is also offered to the students of the fields other than those the course is directly associated with.
- fields of study / plans the course is directly associated with
- Analytical Chemistry (programme PřF, D-CH)
- Analytical Chemistry (programme PřF, M-CH)
- Analytical Chemistry (programme PřF, N-CH)
- Analytical Chemistry (programme PřF, N-CH3)
- Inorganic Chemistry (programme PřF, D-CH)
- Inorganic Chemistry (programme PřF, M-CH)
- Inorganic Chemistry (programme PřF, N-CH)
- Inorganic Chemistry (programme PřF, N-CH3)
- Physical Chemistry (programme PřF, D-CH)
- Physical Chemistry (programme PřF, M-CH)
- Organic Chemistry (programme PřF, D-CH)
- Organic Chemistry (programme PřF, M-CH)
- Organic Chemistry (programme PřF, N-CH)
- Organic Chemistry (programme PřF, N-CH3)
- Course objectives
- Advanced methods of 1D and 2D NMR spectroscopy of small molecules.
- Syllabus
- 1. Basic 1D NMR spectra, pulse sequence, acquisition parameters, pulse calibration (direct and indirect), probehead exchange 2. Processing and parameters, temperature measurement 3. Homonuclear 2D chemical shift correlation experiments: 1H-1H COSY, 31P-31P COSY, MQF-COSY, NOESY 4. Heteronuclear 2D chemical shift correlation experiments: 31P-19F HETCOR, COLOC 5. Inverse (proton) detection HSQC, HMQC, HMBC, pulsed-field gradients 6. Measurement of 15N nucleus (direct and indirect detection), nucleus with spin > 1/2 (14N, 17O), 29Si, 77Se, 111 a 113Cd, 117 a 119Sn, 195Pt 7. Selective and shaped pulses, selective NOE, combined (hybrid) experiments - HSQC-TOCSY
- Literature
- Claridge, Timothy D.W. High-Resolution NMR Techniques in Organic Chemistry, Amsterdam, Pergamon, 1999, ISBN 0-08-042798-7
- Braun, S. - Kalinowski, H.O. - Berger, S. 100 and More Basic NMR Experiments, Weinheim, VCH, 1996, ISBN 3-527-29091-5
- Assessment methods (in Czech)
- Výuka probíhá u spektrometru v NMR laboratoři. Zápočet bude udělen po zpracování samostatného projektu (měření a interpretace neznámého vzorku).
- Language of instruction
- Czech
- Further Comments
- The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.
- Enrolment Statistics (Autumn 2003, recent)
- Permalink: https://is.muni.cz/course/sci/autumn2003/C7999