C6820 Mechanisms of Inorganic Reactions

Faculty of Science
Spring 2006
Extent and Intensity
2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).
Teacher(s)
RNDr. Dalibor Dastych, Dr. (lecturer)
Guaranteed by
RNDr. Dalibor Dastych, Dr.
Department of Chemistry – Chemistry Section – Faculty of Science
Contact Person: RNDr. Dalibor Dastych, Dr.
Timetable
Mon 18:00–19:50 03021
Prerequisites
Common knowledge of chemistry, basic chemical courses
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
Course objectives
Mechanisms of complexing reactions, detail analysis of the course of inorganic reactions
Syllabus
  • 1. Reactions in solution, influence of kinetic and activation parameters, classification of reaction types.

    2. Reactions leading to increasing or decreasing of coordination number, changes in geometry, intramolecular rearrangement, redox reactions, chain and oscillating reactions.

    3. Substitution reactions, bond formation and destruction, molecularity of substitutional processes, coordination number and substitutional mechanism, one-electron transfer reactions. 4. Substitution on two-, three, four-, and five-coordinated central atom. Stereochemical effects in course of substitution, trans-effect.

    5. Substitution in octahedral complexes.

    6. Stereochemical exchange of ligands, rotation, pseudorotation, izomerization, rearrangements.

    7. Substitution reactions of carbonyls and similar compounds.

    8. Influence of solvent and complex formation, kinetic parameters of solvent exchange, complex forming mechanisms.

    9. Solvation, salting-out, influence of ions, micelle formation, microemulsions, gels.

    10. Redox reactions, state description, single mechanisms (1st part).

    11. Redox reactions, state description, single mechanisms (2nd part).

    12. Activation, addition, insertion and migration in complexes.

    13. Oxidative reactions and reductive elimination, elimination, homogenous catalysis.

    14. Conclusion, discussion.
Literature
  • TOBE, Martin L. and John BURGESS. Inorganic Reaction Mechanisms. Addison Wesley Longman Ltd., 1999, 674 pp. ISBN 0 582 23677 0. info
  • FITZ, Ingomar. Reaktionstypen in der anorganischen Chemie. Berlin: Akademie-Verlag, 1975, 465 s. info
  • BASOLO, Fred and Ralph G. PEARSON. Mechanizmy neorganičeskich reakcij : izučenije kompleksov metallov v rastvore. 2nd ed. Moskva: Mir, 1971, 592 s. info
Assessment methods (in Czech)
přednáška kolokvium nebo ústní zkouška
Language of instruction
Czech
Further Comments
The course is taught annually.
The course is also listed under the following terms Spring 2008 - for the purpose of the accreditation, Spring 2001, Spring 2002, Spring 2003, Spring 2004, Spring 2005, Spring 2007.
  • Enrolment Statistics (Spring 2006, recent)
  • Permalink: https://is.muni.cz/course/sci/spring2006/C6820