C8810 Chemistry of transition elements.

Faculty of Science
Spring 2009
Extent and Intensity
2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).
Teacher(s)
doc. RNDr. Josef Novosad, CSc. (lecturer)
Guaranteed by
doc. RNDr. Josef Novosad, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Timetable
Wed 8:00–9:50 C12/311
Prerequisites
General Chemistry, Inorganic Chemistry I and II
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
Course objectives
The course covers an introduction to the principles underlying the chemistry of the d- and f-block metals. The main focus will be on the aspects of structure, bonding, chemical thermodynamics and spectroscopy, which underpin studies of the chemistry of these elements. At the end of the course students should be able to understand and explain synthesis, reactivity, and properties of transition metal compounds, supported by discussion of structure and bonding and their implications. The aim, on completion of the course, is that a student will be equipped to recognise the key classes of transition metal compound, their methods of characterisation, possible synthetic routes and anticipated reactivity.
Syllabus
  • 1. Coordination compounds, ligands and their classification, coordination numbers. 2. Bonding in co rdination compounds, ligand-field theory. 3. Stereochemistry of coordination compounds. 4. Isomerism of coordination compounds, stereochemically nonrigid and fluxional molecules and ions. 5. General periodic trends among transition metals. Group 11- the coinage metals. 6. Group 12 (zinc, cadmium, mercury). 7. Transition metals of group 3-the scandium family and rare earths, the lanthanide contraction. 8. Transition metals of group 4 (titanium, zirkonium, hafnium). 9. Transition metals of group 5 (vanadium, niobium, tantalum). 10. Transition metals of group 6 (chromium, molybdenum, tungsten) and transition metals of group 7 (manganese, technetium, rhenium). 11. Isopoly and heteropolyanions. 12. The iron triad. 13. Platinum metals. 14. Multiply bonded dinuclear complexes. 15. Clusters with metal-metal bonds.
Literature
  • GREENWOOD, N. N. and A. EARNSHAW. Chemistry of the elements (Orig.) : Chemie prvků. Sv. 1 : Chemie prvků. Sv. 2. info
  • Cotton F.A., Murillo C., Wilkinson G., Bochmann M., Grimes R.: Advanced Inorganic Chemistry, 6th Ed., Wiley-Interscience, New York 1999.
  • Housecroft C. E.: The Heavier d-Block Metals, Oxford Univ. Press, Oxford 1999.
  • Jones CH. J.: d- and f-Block Chemistry, Royal Society of Chemistry, Cambridge 2001
Assessment methods
The course has a form of lectures, oral exam.
Language of instruction
Czech
Further Comments
The course is taught annually.
The course is also listed under the following terms Spring 2008 - for the purpose of the accreditation, Spring 2011 - only for the accreditation, Spring 2000, Spring 2001, Spring 2002, Spring 2003, Spring 2004, Spring 2005, Spring 2006, Spring 2008, Spring 2010, Spring 2011, spring 2012 - acreditation, Spring 2013, Spring 2014.
  • Enrolment Statistics (Spring 2009, recent)
  • Permalink: https://is.muni.cz/course/sci/spring2009/C8810