C8860 Synthesic Methods of Green Chemistry (Selected Chapters)

Faculty of Science
Spring 2022
Extent and Intensity
2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).
Teacher(s)
doc. RNDr. Pavel Pazdera, CSc. (lecturer)
Guaranteed by
doc. RNDr. Pavel Pazdera, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Contact Person: doc. RNDr. Pavel Pazdera, CSc.
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science
Prerequisites
The successful encompassment of Organic chemistry incl. organic synthesis, coordination and catalysis of organic reactions.
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
Course objectives
In the end of this course, the student will be able to understand the principles and goals of Green Chemistry and to apply these for the designing of organic syntheses according to Chemistry for sustainable development and cleaner production. The student will be able to apply progressive methods and techniques of Green Chemistry.
Syllabus
  • Sustainable development and sustainability in chemistry (Green chemistry, cleaner production). Resources and principles.
  • Phase transfer catalysis (PTC), principles, catalysts, lipophility of ions. Two-phase systems s-l, l-l, g-l, tri-phase systems. Inverted PTC. Applications in synthesis.
  • Micellar catalysis, surfactants and syntheses in water. Principles, materials, synthetic applications.
  • Sonochemistry, principles, cavitation, comparison with PTC, apparatus, synthetic applications. Influence on heterogenous s-l, l-l, g-l) and homogenous reactions. Activation of heterogenous catalysts (metals).
  • Microwaves (MW) and synthesis. Principles, application methods and techniques.Synthetic applications.
  • Solid supported reactions, principles, materials, synthetic applications
  • Ionic liquids, ionic liquids as solvents and catalysts, comparison with classic solvent, synthetic applications.
  • Supercritical liquids (Sc-l), Sc-water and Sc-carbon dioxide.
  • Sophistic approach as method of green chemistry.
Literature
  • Green chemistry and processes, M. Doble., A.K. Kruthiventi, Elselvier, AP London 2007.
  • Green chemistry, an introductory text, M. Lancaster, RSC London 2002.
Teaching methods
Lectures.
Assessment methods
Oral exam. Discourse about tree problems connected with the content of course.
Language of instruction
Czech
Further comments (probably available only in Czech)
The course is taught once in two years.
Information on the per-term frequency of the course: každý lichý rok.
The course is taught: every week.
General note: Znalosti budou vyžadovány u státní závěrečné zkoušky z organické chemie v magisterském studijním programu!.
The course is also listed under the following terms Spring 2008 - for the purpose of the accreditation, Spring 2011 - only for the accreditation, Spring 2000, Spring 2002, Spring 2003, Spring 2004, Spring 2005, Spring 2006, Spring 2007, Spring 2008, Spring 2009, Spring 2010, Spring 2011, Spring 2012, spring 2012 - acreditation, Spring 2013, Spring 2014, Spring 2015, Spring 2017, Spring 2019, Spring 2020.
  • Enrolment Statistics (recent)
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