Kyselá katalýza - protonizace subtrátu s+HA<-k-1--k1-->HS+ + A- ---+X---k2-->P+Q+HA koncentrace: S= 100 A-= 0 konstantk1= 1,00E-02 výchozí HA= 5 X= 100 k-1= 5,00E-02 HS+= 0 P= 0 k2= 1,00E-04 Q= 0 časový krok= 1 t/ s S HA HS+ A- X P (Q) HA+A- v=dP/dt 0 100 5 0 0 100 0 5 19,50E+01 0,00E+005,00E+005,00E+001,00E+020,00E+00 5 0 29,63E+01 1,50E+003,50E+003,50E+009,98E+012,50E-01 5 0,25 39,54E+01 7,91E-014,21E+004,21E+009,96E+013,72E-01 5 0,122194 49,55E+01 1,10E+003,90E+003,90E+009,95E+015,49E-01 5 0,176502 59,53E+01 9,61E-014,04E+004,04E+009,93E+017,00E-01 5 0,151378 69,52E+01 1,02E+003,98E+003,98E+009,91E+018,62E-01 5 0,161966 79,50E+01 9,97E-014,00E+004,00E+009,90E+011,02E+00 5 0,156797 89,48E+01 1,01E+003,99E+003,99E+009,88E+011,18E+00 5 0,158599 99,47E+01 1,01E+003,99E+003,99E+009,87E+011,33E+00 5 0,15734 109,45E+01 1,01E+003,99E+003,99E+009,85E+011,49E+00 5 0,157423 119,44E+01 1,01E+003,99E+003,99E+009,84E+011,65E+00 5 0,156922 129,42E+01 1,01E+003,99E+003,99E+009,82E+011,81E+00 5 0,156675 139,40E+01 1,01E+003,99E+003,99E+009,80E+011,96E+00 5 0,15632 149,39E+01 1,01E+003,99E+003,99E+009,79E+012,12E+00 5 0,156012 159,37E+01 1,01E+003,99E+003,99E+009,77E+012,27E+00 5 0,155685 169,36E+01 1,01E+003,99E+003,99E+009,76E+012,43E+00 5 0,155367 179,34E+01 1,01E+003,99E+003,99E+009,74E+012,58E+00 5 0,155047 189,33E+01 1,02E+003,98E+003,98E+009,73E+012,74E+00 5 0,154728 199,31E+01 1,02E+003,98E+003,98E+009,71E+012,89E+00 5 0,15441 209,30E+01 1,02E+003,98E+003,98E+009,70E+013,05E+00 5 0,154093 219,28E+01 1,02E+003,98E+003,98E+009,68E+013,20E+00 5 0,153776 229,27E+01 1,02E+003,98E+003,98E+009,66E+013,35E+00 5 0,15346 239,25E+01 1,02E+003,98E+003,98E+009,65E+013,51E+00 5 0,153145 249,24E+01 1,02E+003,98E+003,98E+009,63E+013,66E+00 5 0,152831 259,22E+01 1,02E+003,98E+003,98E+009,62E+013,81E+00 5 0,152517 269,21E+01 1,02E+003,98E+003,98E+009,60E+013,97E+00 5 0,152204 279,19E+01 1,02E+003,98E+003,98E+009,59E+014,12E+00 5 0,151892 289,18E+01 1,02E+003,98E+003,98E+009,57E+014,27E+00 5 0,15158 299,16E+01 1,03E+003,97E+003,97E+009,56E+014,42E+00 5 0,151269 309,15E+01 1,03E+003,97E+003,97E+009,54E+014,57E+00 5 0,150959 319,13E+01 1,03E+003,97E+003,97E+009,53E+014,72E+00 5 0,150649 329,12E+01 1,03E+003,97E+003,97E+009,51E+014,87E+00 5 0,150341 339,10E+01 1,03E+003,97E+003,97E+009,50E+015,02E+00 5 0,150033 349,09E+01 1,03E+003,97E+003,97E+009,48E+015,17E+00 5 0,149725 359,07E+01 1,03E+003,97E+003,97E+009,47E+015,32E+00 5 0,149418 369,06E+01 1,03E+003,97E+003,97E+009,45E+015,47E+00 5 0,149113 379,04E+01 1,03E+003,97E+003,97E+009,44E+015,62E+00 5 0,148807 389,03E+01 1,03E+003,97E+003,97E+009,42E+015,77E+00 5 0,148503 399,01E+01 1,04E+003,96E+003,96E+009,41E+015,92E+00 5 0,148199 409,00E+01 1,04E+003,96E+003,96E+009,39E+016,06E+00 5 0,147896 418,98E+01 1,04E+003,96E+003,96E+009,38E+016,21E+00 5 0,147593 428,97E+01 1,04E+003,96E+003,96E+009,36E+016,36E+00 5 0,147291 438,95E+01 1,04E+003,96E+003,96E+009,35E+016,51E+00 5 0,14699 448,94E+01 1,04E+003,96E+003,96E+009,33E+016,65E+00 5 0,14669 458,92E+01 1,04E+003,96E+003,96E+009,32E+016,80E+00 5 0,14639 468,91E+01 1,04E+003,96E+003,96E+009,31E+016,94E+00 5 0,146091 478,90E+01 1,04E+003,96E+003,96E+009,29E+017,09E+00 5 0,145792 488,88E+01 1,04E+003,96E+003,96E+009,28E+017,24E+00 5 0,145495 498,87E+01 1,04E+003,96E+003,96E+009,26E+017,38E+00 5 0,145198 508,85E+01 1,05E+003,95E+003,95E+009,25E+017,53E+00 5 0,144901 518,84E+01 1,05E+003,95E+003,95E+009,23E+017,67E+00 5 0,144606 528,82E+01 1,05E+003,95E+003,95E+009,22E+017,82E+00 5 0,144311 538,81E+01 1,05E+003,95E+003,95E+009,20E+017,96E+00 5 0,144016 548,79E+01 1,05E+003,95E+003,95E+009,19E+018,10E+00 5 0,143723 558,78E+01 1,05E+003,95E+003,95E+009,18E+018,25E+00 5 0,14343 568,77E+01 1,05E+003,95E+003,95E+009,16E+018,39E+00 5 0,143137 578,75E+01 1,05E+003,95E+003,95E+009,15E+018,53E+00 5 0,142846 588,74E+01 1,05E+003,95E+003,95E+009,13E+018,67E+00 5 0,142555 598,72E+01 1,05E+003,95E+003,95E+009,12E+018,82E+00 5 0,142264 608,71E+01 1,06E+003,94E+003,94E+009,10E+018,96E+00 5 0,141975 618,70E+01 1,06E+003,94E+003,94E+009,09E+019,10E+00 5 0,141686 628,68E+01 1,06E+003,94E+003,94E+009,08E+019,24E+00 5 0,141397 638,67E+01 1,06E+003,94E+003,94E+009,06E+019,38E+00 5 0,14111 648,65E+01 1,06E+003,94E+003,94E+009,05E+019,52E+00 5 0,140822 658,64E+01 1,06E+003,94E+003,94E+009,03E+019,66E+00 5 0,140536 668,63E+01 1,06E+003,94E+003,94E+009,02E+019,80E+00 5 0,14025 678,61E+01 1,06E+003,94E+003,94E+009,01E+019,94E+00 5 0,139965 688,60E+01 1,06E+003,94E+003,94E+008,99E+011,01E+01 5 0,139681 698,58E+01 1,06E+003,94E+003,94E+008,98E+011,02E+01 5 0,139397 708,57E+01 1,06E+003,94E+003,94E+008,96E+011,04E+01 5 0,139114 718,56E+01 1,07E+003,93E+003,93E+008,95E+011,05E+01 5 0,138831 728,54E+01 1,07E+003,93E+003,93E+008,94E+011,06E+01 5 0,138549 738,53E+01 1,07E+003,93E+003,93E+008,92E+011,08E+01 5 0,138268 748,52E+01 1,07E+003,93E+003,93E+008,91E+011,09E+01 5 0,137988 758,50E+01 1,07E+003,93E+003,93E+008,89E+011,11E+01 5 0,137708 768,49E+01 1,07E+003,93E+003,93E+008,88E+011,12E+01 5 0,137428 778,47E+01 1,07E+003,93E+003,93E+008,87E+011,13E+01 5 0,13715 788,46E+01 1,07E+003,93E+003,93E+008,85E+011,15E+01 5 0,136872 798,45E+01 1,07E+003,93E+003,93E+008,84E+011,16E+01 5 0,136594 808,43E+01 1,07E+003,93E+003,93E+008,83E+011,17E+01 5 0,136317 818,42E+01 1,07E+003,93E+003,93E+008,81E+011,19E+01 5 0,136041 828,41E+01 1,08E+003,92E+003,92E+008,80E+011,20E+01 5 0,135766 838,39E+01 1,08E+003,92E+003,92E+008,79E+011,21E+01 5 0,135491 848,38E+01 1,08E+003,92E+003,92E+008,77E+011,23E+01 5 0,135216 858,37E+01 1,08E+003,92E+003,92E+008,76E+011,24E+01 5 0,134943 868,35E+01 1,08E+003,92E+003,92E+008,74E+011,26E+01 5 0,13467 878,34E+01 1,08E+003,92E+003,92E+008,73E+011,27E+01 5 0,134397 888,33E+01 1,08E+003,92E+003,92E+008,72E+011,28E+01 5 0,134125 898,31E+01 1,08E+003,92E+003,92E+008,70E+011,30E+01 5 0,133854 908,30E+01 1,08E+003,92E+003,92E+008,69E+011,31E+01 5 0,133584 918,29E+01 1,08E+003,92E+003,92E+008,68E+011,32E+01 5 0,133314 928,27E+01 1,09E+003,91E+003,91E+008,66E+011,34E+01 5 0,133044 938,26E+01 1,09E+003,91E+003,91E+008,65E+011,35E+01 5 0,132776 948,25E+01 1,09E+003,91E+003,91E+008,64E+011,36E+01 5 0,132508 958,23E+01 1,09E+003,91E+003,91E+008,62E+011,38E+01 5 0,13224 968,22E+01 1,09E+003,91E+003,91E+008,61E+011,39E+01 5 0,131973 978,21E+01 1,09E+003,91E+003,91E+008,60E+011,40E+01 5 0,131707 988,19E+01 1,09E+003,91E+003,91E+008,59E+011,41E+01 5 0,131441 998,18E+01 1,09E+003,91E+003,91E+008,57E+011,43E+01 5 0,131176 1008,17E+01 1,09E+003,91E+003,91E+008,56E+011,44E+01 5 0,130911 1018,16E+01 1,09E+003,91E+003,91E+008,55E+011,45E+01 5 0,130648 1028,14E+01 1,10E+003,90E+003,90E+008,53E+011,47E+01 5 0,130384 1038,13E+01 1,10E+003,90E+003,90E+008,52E+011,48E+01 5 0,130122 1048,12E+01 1,10E+003,90E+003,90E+008,51E+011,49E+01 5 0,129859 1058,10E+01 1,10E+003,90E+003,90E+008,49E+011,51E+01 5 0,129598 1068,09E+01 1,10E+003,90E+003,90E+008,48E+011,52E+01 5 0,129337 1078,08E+01 1,10E+003,90E+003,90E+008,47E+011,53E+01 5 0,129077 1088,07E+01 1,10E+003,90E+003,90E+008,46E+011,54E+01 5 0,128817 1098,05E+01 1,10E+003,90E+003,90E+008,44E+011,56E+01 5 0,128558 1108,04E+01 1,10E+003,90E+003,90E+008,43E+011,57E+01 5 0,128299 1118,03E+01 1,10E+003,90E+003,90E+008,42E+011,58E+01 5 0,128041 1128,01E+01 1,10E+003,90E+003,90E+008,40E+011,60E+01 5 0,127784 1138,00E+01 1,11E+003,89E+003,89E+008,39E+011,61E+01 5 0,127527 1147,99E+01 1,11E+003,89E+003,89E+008,38E+011,62E+01 5 0,127271 1157,98E+01 1,11E+003,89E+003,89E+008,37E+011,63E+01 5 0,127015 1167,96E+01 1,11E+003,89E+003,89E+008,35E+011,65E+01 5 0,12676 1177,95E+01 1,11E+003,89E+003,89E+008,34E+011,66E+01 5 0,126505 1187,94E+01 1,11E+003,89E+003,89E+008,33E+011,67E+01 5 0,126252 1197,93E+01 1,11E+003,89E+003,89E+008,32E+011,68E+01 5 0,125998 1207,91E+01 1,11E+003,89E+003,89E+008,30E+011,70E+01 5 0,125745 1217,90E+01 1,11E+003,89E+003,89E+008,29E+011,71E+01 5 0,125493 1227,89E+01 1,11E+003,89E+003,89E+008,28E+011,72E+01 5 0,125242 1237,88E+01 1,12E+003,88E+003,88E+008,27E+011,73E+01 5 0,124991 1247,86E+01 1,12E+003,88E+003,88E+008,25E+011,75E+01 5 0,12474 1257,85E+01 1,12E+003,88E+003,88E+008,24E+011,76E+01 5 0,12449 1267,84E+01 1,12E+003,88E+003,88E+008,23E+011,77E+01 5 0,124241 1277,83E+01 1,12E+003,88E+003,88E+008,22E+011,78E+01 5 0,123992 1287,82E+01 1,12E+003,88E+003,88E+008,20E+011,80E+01 5 0,123744 1297,80E+01 1,12E+003,88E+003,88E+008,19E+011,81E+01 5 0,123496 1307,79E+01 1,12E+003,88E+003,88E+008,18E+011,82E+01 5 0,123249 1317,78E+01 1,12E+003,88E+003,88E+008,17E+011,83E+01 5 0,123002 1327,77E+01 1,12E+003,88E+003,88E+008,15E+011,85E+01 5 0,122756 1337,75E+01 1,12E+003,88E+003,88E+008,14E+011,86E+01 5 0,122511 1347,74E+01 1,13E+003,87E+003,87E+008,13E+011,87E+01 5 0,122266 1357,73E+01 1,13E+003,87E+003,87E+008,12E+011,88E+01 5 0,122022 1367,72E+01 1,13E+003,87E+003,87E+008,11E+011,89E+01 5 0,121778 1377,71E+01 1,13E+003,87E+003,87E+008,09E+011,91E+01 5 0,121535 1387,69E+01 1,13E+003,87E+003,87E+008,08E+011,92E+01 5 0,121292 1397,68E+01 1,13E+003,87E+003,87E+008,07E+011,93E+01 5 0,12105 1407,67E+01 1,13E+003,87E+003,87E+008,06E+011,94E+01 5 0,120808 1417,66E+01 1,13E+003,87E+003,87E+008,04E+011,96E+01 5 0,120567 1427,65E+01 1,13E+003,87E+003,87E+008,03E+011,97E+01 5 0,120327 1437,63E+01 1,13E+003,87E+003,87E+008,02E+011,98E+01 5 0,120087 1447,62E+01 1,14E+003,86E+003,86E+008,01E+011,99E+01 5 0,119847 1457,61E+01 1,14E+003,86E+003,86E+008,00E+012,00E+01 5 0,119608 1467,60E+01 1,14E+003,86E+003,86E+007,98E+012,02E+01 5 0,11937 1477,59E+01 1,14E+003,86E+003,86E+007,97E+012,03E+01 5 0,119132 1487,57E+01 1,14E+003,86E+003,86E+007,96E+012,04E+01 5 0,118895 1497,56E+01 1,14E+003,86E+003,86E+007,95E+012,05E+01 5 0,118658 1507,55E+01 1,14E+003,86E+003,86E+007,94E+012,06E+01 5 0,118422 1517,54E+01 1,14E+003,86E+003,86E+007,93E+012,07E+01 5 0,118186 1527,53E+01 1,14E+003,86E+003,86E+007,91E+012,09E+01 5 0,117951 1537,52E+01 1,14E+003,86E+003,86E+007,90E+012,10E+01 5 0,117717 1547,50E+01 1,15E+003,85E+003,85E+007,89E+012,11E+01 5 0,117483 1557,49E+01 1,15E+003,85E+003,85E+007,88E+012,12E+01 5 0,117249 1567,48E+01 1,15E+003,85E+003,85E+007,87E+012,13E+01 5 0,117016 1577,47E+01 1,15E+003,85E+003,85E+007,85E+012,15E+01 5 0,116783 1587,46E+01 1,15E+003,85E+003,85E+007,84E+012,16E+01 5 0,116552 1597,45E+01 1,15E+003,85E+003,85E+007,83E+012,17E+01 5 0,11632 1607,44E+01 1,15E+003,85E+003,85E+007,82E+012,18E+01 5 0,116089 1617,42E+01 1,15E+003,85E+003,85E+007,81E+012,19E+01 5 0,115859 1627,41E+01 1,15E+003,85E+003,85E+007,80E+012,20E+01 5 0,115629 1637,40E+01 1,15E+003,85E+003,85E+007,79E+012,21E+01 5 0,115399 1647,39E+01 1,15E+003,85E+003,85E+007,77E+012,23E+01 5 0,115171 1657,38E+01 1,16E+003,84E+003,84E+007,76E+012,24E+01 5 0,114942 1667,37E+01 1,16E+003,84E+003,84E+007,75E+012,25E+01 5 0,114714 1677,36E+01 1,16E+003,84E+003,84E+007,74E+012,26E+01 5 0,114487 1687,34E+01 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