|É Periodický systém Základní vlastnosti chemických prvků Main-Group Elements s Subshell fills Main-Group Elements p Subshell fills □ Inner-Transition Metals /Subshell fills 'Lanthanides 'Actinides 58 Ce www 59 Pr 4rěé 60 Nd Ares1 61 Pm 62 Sm 63 Eu 64 Gd 4rf5flCV 05 Tb m* 66 Dy 67 Ho Ares' 68 Er 4/"es1 69 Tm 70 Yb 7n Lu 90 Th 91 Pa 92 U 93 Np WW Pu 95 Am R Cm 97 Bk 98 Cf 5/--7ir 99 Es 100 Fm 101 Md UK No 103 Lr Metal Metalloid Non meta I s orbital *Th ree two lobes nodal plane ►p-electron never found at the nucleus three perpendicular axes complicated •Five •Four four lobes fifth different *d-orbitaI electron not be found at the nucleus f orbital - does not explain chemical properties 3d -00000- 45 3p -ooo 3s 2P-00-0 2s 1s -O- Electron Element Orbitals Configuration H 1S • 2s 2p, 2p, 2p, 1s1 He • 1s2 U c ® 1S2 2s' Be W ^s2 2s2 B # • © o o ^s2 2s2 2p1 C • • © © o 1s2 2s2 2p2 N • © © © 1S2 2S2 2p* 0 • © © © 1s2 2s2 2p4 F • © © © 1s2 2s2 2p5 Ne • • © © © 1s2 2s2 2p^ Main-Group Elements Main-Group Elements CrystalMaker Element Tables VFI Atomic Radii http://www.crystalmaker.com l H 4 2 He 4 Be J 11 Na 4 * Na Mg I9 20 Ca 38 Sr 37 Rb 55 CS 56 Ba Image generated by CrystalMaker 6.3: interactive crystal & molecular structures visualization for Mac OS X 21 SC • 22 Tl 23 V • 24 Cr J 25 Mn 26 Fe 27 Co • 28 NI J 29 Cu 30 Zn » 39 Y 40 Zr J 41 Nb J 42 MO J 43 Tc J 44 Ru N* 45 Rh 46 Pd 47 Ag ě 48 Cd • 71 Ltl 72 Hf J 73 Ta J 74 W ^ 75 Re •» 76 OS 77 lr ^ 78 Pt J 79 AU V* 80 Hg J 57 La J 58 Ce J 59 60 61 62 63 64 65 Pr Nd Pm Sm Eu Gd Tb 66 Dy • 89 AC 90 Th J 91 Pa 92 U J 93 Np 94 Pu • 95 Am O 96 Cm O 97 Bk o 98 Cf O 5 B • 6 C • 7 N a 13 Al J 14 SI • 15 P 31 Ga 9 32 Ge • 33 AS 49 in 50 Sn 51 Sb • 81 Tl • 82 Pb • 83 Bl • 67 Ho • 68 Er • 69 Tm • 99 Es O 100 Fm O 101 Md o 8 O 16 S 34 Se J 52 Te 84 Po 70 Yb NO 17 CI 4 35 85 At 10 Ne 18 Ar 36 Kr Br 54 53 Xe 86 Rn Scale 10 A Ihesc data arc based on inr.crjr.omic distances in the structures of the dements. (Radii for metals correspond to coordination numbers of 12.) Where no radius value can be found for a particular clement, its radius has been set to a default value of 1 A and a circle is plotted instead of a rendered sphere. Data from Vainshtcin ct al„ 1995; values forO, F, S, CI, Br, I, At, Po, Pm. Rn have been taken from Clcmcnti ct al. 1963- Refeiences: Vainshtein BK, Fridkin VM, lndenbom VL (1995) Structure of Crystals, 3rd Edition. Springer Verlag, Berlin. Clcmcnti E. Raimondi DL Rcinhardt \VP (1963) Journal of Chemical Physics 38:2686- CrystalMaker SOFTWARE 1A Trends in Atomic Radius (A) (show rule 4A 5A 0.77 1.75 ® 0.70 © 1.10 Bi 1.46 6A 0.66 S 1J04 Po 1.5 7A 0.64 3 0.99 Te 1.37 1.33 At 1.4 8A He o 0.5 © 0.70 0.94 Rn 1.4 Fluoride ion Van der Waals radii (1 pm = 1 x1012) 200 pm 150 100 R_- " "S b ■ N/ Group V ..................... ................... 10 20 30 40 50 60 Z 230 pm 150 100 " " f e 0/ Group VI .................... 10 20 30 40 50 60 Z 200 pm 150 100 ^__J, Br___— cy—-—"""""^ Halogens (Group VII) 10 20 30 40 50 60 Z 200 pm 150f 100 He Rare gases 10 20 30 Z 40 50 60 Covalent radii (1pm = 1x10~12) 150 BSaíEs HkBsI : "Ir ""iT-^""11 >.-.■."J I -J v" "> o o Cl ľ G(ŕ ar. n H! ľ Cli. cr : CK. I V^r Ktatí;K3|;4S!:,;:'ís .G9ESEfiE9l 11 lonic \ SIHISBIHHSílElBRillEiSilEiill Oov&l aru Electron Groups Total Bonding Lone Arrangement of Groups Molecular Shape Example 2 2 0 Linear Linear C02#—#—# 3 3 0 Trigonal planar Trigonal planar N03- f 2 1 Bent (or angular) .^Lone o3 n pair 1 Tetrahedral Tetrahedral CH, Triangular pyramidal PF. Lone pair Bent (or angular) hUO filLone Wavelength in meters jq-i: ,0-io 10-8 4 x ,0-77 x jQ-7 io- i_i_I_i i i —| io-- Infrared Mierowa\ rs IO2 Radio waves 104 IM Shortwave AM 6x 10 7x 10 -7 Gamma X rays Ultraviolet rays