Benzothiazole Biodegradation: 1H-15N HMBC (Appl. Environ. Microbiol., 2001, 67)
n
I n n
--230
6.9 6.8 8^
Benzothiazole Biodegradation: 1H-15N HMBC (Appl. Environ. Microbiol., 2001, 67)
'H NMR 5
'II
N MS y—OH Ľ=v> HO
S
Jh4H5
2D NMR )-OH I >
H4
n v„,
JuU L
H7
-« m
JniH4
3Jh4H5
IHSH7
H5,
JniH5
pn1h4
"II "
6.9 6.8
ppm -250
-240
-230
V)
ppm to
-250
-240
--230
-220
□        g - = =     -O o
ppm
0
,^7
6
^2
N
RhCI4 DMSO
11
in
190 ^ 200 1 210 220 230 3 240 250
120
11
130
O
2 140
150
IC
(02 - 'H (ppm) 9 8
B N1-H2
v
Rh N1-H2 1
B N1-H3
Rh N1-H3
/
B N1
Rh N1
10
8
Rh C3-H2
B C3-H3
•Rh C3-H3
B
B C3-H2'
Rh C6-H6
B C6-H6 Rh C7-H6
B C7-H6
B C2-H2
Rh C4-H2
BCS-B H3~*~"
Rh C5-H3«
K
Rh C2-H2
í
B C2-H3
B C
M./
B C4-H2
B C4-H6 \
10
C8-H
Rh C6-H7 Rh C8-H8
Rh C7-H7 B C7-H7
Rh C5-H8
.Rh C4-H6
•Rh C2-H3
120
130
Rh C3
BC3 Rh C6 BC6 Rh C8 BC8 Rh C7 BC7 BC5 Rh C5
140
BC2
h 50 RhC4
Rh C2 BC4
X
TO
8    * V,
CD 03    00 ID ID CD 03 2) ZD
I I l"ll"
CO OllNCDlI CD CO 00 -J
1
(02 - H (ppm)
1H PENICILINE G
10
H
9.0    8.5    8.0    7.5    7.0    6.5    6.0    5.5    5.0    4.5    4.0    3.5    3.0    2.5    2.0    1.5 ppm
8 6 4 2
				•
			x	
< ( <	) )			
<	1-^ -			1».
8 6 4 2
C02 - 1H (ppm)
50-
Q. Q.
u 100-
ro
CO
150-
200-
H1S16-C10
H8-C7
H13/15-C13/15
H   V1918 H7C7
-Q
H4-C4
H14-C14
H13/15-C11" H12/16-CÍ: H8-C9
H8-C6
H12/16-C12/C16 H7-C9
H1-C2'
H1-C4«
Hl-Cl
H1-C19
H4-C6 H7-C
7
H1-C6
7
H17-C17A H18-C18^
H17/18-C2
H10'/"-C10
7"
H17/18-C1
z
H107"-C12/16
\
H107"-C11
H107"-C9
-50
-100
-150
8
6 4 ô2 - 1H (ppm)
■200