Vznik nové fáze https://encrypted-tbn0.gstatic.com/images?q=tbn:ANd9GcRpl8b0fYG19__S0vxiGLEroIAJTN7scugsMmubHWUcOLc BETLD Termodynamika nové fáze Povrchová energie kulovitého precipitátu http://homepage.univie.ac.at/wolfgang.lechner/images/cnt.png Homogenní a heterogenní nukleace z liquidu http://www.matter.org.uk/matscicdrom/manual/nu.html driving force for solidification, DGv exists below the equilibrium melting temperature, Tm and that this is approximately proportional to the degree of undercooling DT: http://www.matter.org.uk/matscicdrom/manual/images/image118.gif http://www.matter.org.uk/matscicdrom/manual/images/image119.gif http://www.matter.org.uk/matscicdrom/manual/images/image124.gif http://www.matter.org.uk/matscicdrom/manual/images/image125.gif Homogenní nukleace: Heterogenní nukleace: http://www.matter.org.uk/matscicdrom/manual/images/image120.gif http://www.matter.org.uk/matscicdrom/manual/images/image122.gif http://www.matter.org.uk/matscicdrom/manual/images/image123.gif http://www.matter.org.uk/matscicdrom/manual/images/image126.gif http://www.matter.org.uk/matscicdrom/manual/images/image127.gif http://www.matter.org.uk/matscicdrom/manual/images/image128.gif q..úhel smáčení http://nptel.iitm.ac.in/courses/103104045/lecture20/images/01.jpg Snížené energetické bariéry http://www.matter.org.uk/matscicdrom/manual/images/image129.gif Homogenní a heterogenní nukleace v tuhém stavu http://www.matter.org.uk/matscicdrom/manual/images/image131.gif http://www.matter.org.uk/matscicdrom/manual/images/image130.gif http://www.matter.org.uk/matscicdrom/manual/images/image132.gif \begin{figure}\resizebox{6in}{!} {\epsfig{file=figures/Nucleation/grain_bndy_ppct.eps}} \end{figure} http://pruffle.mit.edu/~ccarter/3.21/Lecture_25/ \begin{figure}\resizebox{6in}{!} {\epsfig{file=figures/Nucleation/beta_phase_part.eps}} \end{figure} Interfacial structure for (a) coherent and (b) semicoherent interfaces between matrix phase and particle phase . Smaller dislocation symbols represent coherency dislocations and larger ones in (b) represent anticoherency dislocations. Reálné podmínky http://www.wias-berlin.de/research/ats/Praezipitate/Bilder/image005.gif Způsoby překonání nukleační bariéry \begin{figure}\resizebox{6in}{!} {\epsfig{file=figures/Nucleation/hetero_nuc_regimes.eps}} \end{figure} Metody usnadňující dosažení rovnovážného stavu http://www.photon-hammer.com/images/gallery/section_04/06.jpg http://www.photon-hammer.com/gallery.php http://www.specialchem4polymers.com/documents/indexables/contents/441/images/nucleation3.gif http://www.specialchem4polymers.com/tc/polyolefin-nucleators/?id=principle Faktory ovlivňující růst nové fáze http://www.crystals.leeds.ac.uk/uploads/pics/Nucleation7_520.jpg http://archive.sciencewatch.com/sciencewatch/dr/fmf/images-fmf/2009/09novfmfKlueF2XL.gif Diskuse https://encrypted-tbn2.gstatic.com/images?q=tbn:ANd9GcRYFymVFHFrL-aOMyFaSkfH0BbvQYK43J5dAFnR8UoRfKY jJSKJ