Critical Constants of Organic Compounds
Chris D. Muzny, Vladimir Diky, Andrei Kazakov, Robert D. Chirico, and Michael Frenkel
The parameters of the liquid-gas critical point are important
constants in determining the behavior of fluids. This table lists the
critical temperature, pressure, and molar volume, as well as the
normal boiling point, for over 850 organic substances. The properties
and their units are:
Tb
: Normal boiling point in K at a pressure of 101.325 kPa (1 atmosphere);
an “s” following the value indicates a sublimation
point (temperature at which the solid is in equilibrium
with the gas at a pressure of 101.325 kPa)
Tc
: Critical temperature in K
Pc
: Critical pressure in MPa
Vc
: Critical molar volume in cm3
mol–1
The listed values of the critical constants are critically evaluated
using the NIST ThermoData Engine, TDE (Ref. 1), designed to
implement the dynamic data evaluation concept (Refs. 2–5). This
concept requires large electronic databases capable of storing essentially
all relevant experimental data known to date with detailed
descriptions of metadata and uncertainties. The combination of
these electronic databases with expert-system software, designed
to automatically generate recommended property values based on
available experimental and predicted data, leads to the ability to
produce critically evaluated data dynamically or “to order.” The
evaluated data have been generated only for compounds for which
experimental data for critical properties are available. Group contribution
methods such as Joback-Reed (Ref. 6), ConstantinouGani
(Ref. 7), Marrero-Pardillo (Ref. 8), and Wilson-Jasperson
(Ref. 9) as well as quantitative structure-property relationship
(QSPR) methods (Ref. 5) were used within the TDE environment
to validate available experimental data. Each recommended value
in the table is characterized with a combined expanded uncertainty
(Ref. 10) (level of confidence, approximately 95%) listed in parentheses.
Only references to original experimental data actually
used by TDE to generate critically evaluated data are indicated for
each compound. Compounds are listed alphabetically by name.
The values of the normal boiling temperatures provided in the
table along with the combined expanded uncertainities listed
in parentheses have also been critically evaluated using TDE.
Additional details on the determination of the normal boiling
temperatures using TDE can be found in the Physical Constants
of Organic Compounds table in Section 3. The remaining values
of the normal boiling temperatures (without uncertainities) are
taken from the compilation presented in the 91st Edition of the
CRC Handbook of Chemistry and Physics.
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
Acetaldehyde C2
H4
O 293.9(0.6) 462(8) 7.5(1) 154(5) 11–13
Acetic acid C2
H4
O2
391.0(0.2) 593(2) 5.79(0.03) 171(2) 14–21
Acetic anhydride C4
H6
O3
412.6(0.3) 606(1) 4.00(0.08) 294(12) 22
Acetone C3
H6
O 329.23(0.07) 508.1(0.2) 4.7(0.1) 221(20) 18, 23–31
Acetonitrile C2
H3
N 354.8(0.2) 545.47(0.07) 4.88(0.01) 173(59) 32–40
Acetophenone C8
H8
O 475.2(0.2) 709.5(0.7) 4.01(0.05) 373(40) 11, 41
Acetylene C2
H2
188.45 s 308.4(0.4) 6.24(0.04) 119(11) 42–48
Acrylonitrile C3
H3
N 350.3(0.2) 540(2) 4.6(0.1) 211(10) 49
Allene C3
H4
238.3(0.3) 394(4) 6.5(0.7) 167(8) 50
Allyl alcohol C3
H6
O 370.0(0.5) 539.8(0.6) 5.76(0.04) 222(9) 51
Allylamine C3
H7
N 327(2) 540.0(0.7) 4.83(0.03) 217(11) 52
Allyl ethyl ether C5
H10
O 338(4) 518(10) 3(2) 320(10) 21
2-Aminobiphenyl C12
H11
N 571.4(0.2) 838(2) 3.52(0.03) 548(99) 53
2-Aminoethanol C2
H7
NO 443.4(0.4) 671(3) 8.0(0.5) 207(13) 41
2-(2-Aminoethoxy)ethanol C4
H11
NO2
496.2(0.1) 721(4) 4.88(0.1) 333(19) 54
N-(2-Aminoethyl)ethanolamine C4
H12
N2
O 515(5) 739(2) 4.53(0.09) 340(17) 55
Amyl orthosilicate C20
H44
O4
Si 714(14) 57
Aniline C6
H7
N 457.2(0.4) 704(7) 5.3(0.1) 291(3) 39, 40, 58–60
Anisole C7
H8
O 426.8(0.2) 646.1(0.2) 4.2(0.1) 355(12) 25, 39, 40, 49
Benzene C6
H6
353.23(0.07) 562.0(0.1) 4.90(0.02) 257(11) 19, 27, 28, 34, 61–97
Benzeneacetic acid C8
H8
O2
541(2) 766(8) 3.9(0.3) 372(16) 98
Benzenebutanoic acid C10
H12
O2
569(2) 783(8) 3.2(0.2) 493(18) 98
Benzeneethanol C8
H10
O 493(3) 724(4) 4.0(0.2) 390(15) 99
Benzeneheptanoic acid C13
H18
O2
585(27) 798(8) 2.5(0.3) 662(21) 98
Benzenehexanoic acid C12
H16
O2
574(27) 794(8) 2.6(0.3) 611(20) 98
Benzenepentanoic acid C11
H14
O2
583(1) 790(8) 3.1(0.2) 526(19) 98
Benzenepropanoic acid C9
H10
O2
557(2) 776(8) 3.5(0.2) 440(17) 98
Benzo[b]thiophene C8
H6
S 494.0(0.4) 764(2) 4.68(0.04) 359(59) 100
Benzonitrile C7
H5
N 464(1) 691(9) 4.22(0.04) 348(7) 39, 40, 101, 102
Benzophenone C13
H10
O 579.0(0.2) 830(2) 3.0(0.1) 568(44) 101
Benzyl alcohol C7
H8
O 478.4(0.2) 715(3) 4.3(0.2) 333(13) 103
[1,1’-Bicyclohexyl]-2-one C12
H20
O 537 787(70) 3(7) 584(20) 104
	 6-59
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
1,1’-Bicyclopentyl C10
H18
463.61(0.03) 690(2) 3.27(0.03) 497(41) 105
Biphenyl C12
H10
528.3(0.3) 773(5) 3.43(0.06) 481(69) 39, 106–109
Bis(2-aminoethyl)amine C4
H13
N3
479.6(0.3) 710(2) 4.43(0.07) 350(21) 55
1,1-Bis(difluoromethoxy)-1,2,2,2-
tetrafluoroethane
C4
H2
F8
O2
319.78(0.08) 450(1) 2.40(0.08) 410(4) 110
Bis(difluoromethyl) ether C2
H2
F4
O 278.6(0.4) 420.2(0.1) 4.16(0.06) 223(13) 111
Bis(2-ethylhexyl) phthalate C24
H38
O4
657 835(9) 1.1(0.2) 1495(27) 112
Bis(2-hydroxyethyl)methylamine C5
H13
NO2
518(1) 742(4) 4.2(0.4) 404(17) 54
Bis(2,2,2-trifluoroethyl) ether C4
H4
F6
O 336.91 476.31(0.09) 2.78(0.01) 365(1) 113
Bis(trimethylsilyl)methane C7
H20
Si2
406 573.9(0.3) 114
Bromochlorodifluoromethane CBrClF2
269.2(0.7) 428(12) 4.31(0.01) 229(16) 115
Bromodifluoromethane CHBrF2
257.5(0.5) 412.0(0.3) 5.2(0.1) 173(18) 116
Bromoethane C2
H5
Br 311.3(0.6) 503.9(0.4) 6.2(0.1) 214(10) 117, 118
1-Bromo-2-fluorobenzene C6
H4
BrF 427 669.6(0.6) 4.3(0.6) 342(18) 119
1-Bromo-3-fluorobenzene C6
H4
BrF 423 652.0(0.4) 4.2(0.6) 337(18) 119
1-Bromo-4-fluorobenzene C6
H4
BrF 423(2) 654.8(0.4) 4.2(0.2) 338(18) 119
1-Bromopropane C3
H7
Br 343.9(0.2) 536.9(0.1) 4.33(0.06) 271(6) 120
Bromotrifluoromethane CBrF3
215.3(0.4) 340.06(0.05) 3.96(0.01) 199(6) 121
1-Bromo-2-(trifluoromethyl)benzene C7
H4
BrF3
440.7 656.5(0.4) 3.3(0.8) 415(24) 119
1-Bromo-3-(trifluoromethyl)benzene C7
H4
BrF3
424.7 627.1(0.4) 3.2(0.7) 413(24) 119
1-Bromo-4-(trifluoromethyl)benzene C7
H4
BrF3
433 629.8(0.4) 3.2(0.8) 413(24) 119
1,3-Butadiene C4
H6
268.5(0.2) 425(1) 4.35(0.07) 221(23) 122, 123
Butanal C4
H8
O 347.9(0.2) 537(2) 4.41(0.1) 258(9) 104, 124
Butane C4
H10
272.6(0.5) 425.2(0.1) 3.79(0.01) 257(4) 29, 125–139
1,4-Butanediamine C4
H12
N2
429(10) 651(7) 4.5(0.5) 317(14) 140
1,2-Butanediol C4
H10
O2
469.57(0.06) 680(2) 5.4(0.1) 298(12) 141
1,3-Butanediol C4
H10
O2
481.3(0.1) 679(17) 4.7(0.1) 302(67) 54, 141
1,4-Butanediol C4
H10
O2
502.6(0.4) 724(4) 5.5(0.2) 307(14) 49, 55
Butanenitrile C4
H7
N 390.8(0.4) 585.40(0.07) 3.82(0.05) 265(6) 35, 39, 40, 142
1-Butanethiol C4
H10
S 371.5(0.5) 570.1(0.6) 4.01(0.02) 324(12) 143, 144
Butanoic acid C4
H8
O2
436.8(0.1) 623(6) 4.0(0.3) 292(10) 145–147
1-Butanol C4
H10
O 390.8(0.2) 563.0(0.4) 4.43(0.07) 280(14) 34, 80, 148–155
2-Butanol C4
H10
O 372.5(0.2) 535(4) 4.2(0.1) 269(4) 148, 149, 153, 156
2-Butanone C4
H8
O 352.8(0.2) 537(1) 4.18(0.02) 274(30) 25, 30, 33, 34, 38, 157
1-Butene C4
H8
276.87(0.08) 419.3(0.1) 4.00(0.05) 236(14) 123, 158–161
cis-2-Butene C4
H8
274.03(0.09) 435.7(0.2) 4.23(0.02) 235(4) 86, 123, 158
trans-2-Butene C4
H8
266.8(0.2) 428.6(0.1) 4.03(0.02) 238(4) 86, 123, 158
2-Butoxyethanol C6
H14
O2
444(2) 633.9(1) 3.3(0.1) 424(15) 11, 41
1-tert-Butoxy-2-ethoxyethane C8
H18
O2
421.2 585(3) 2.5(0.4) 546(14) 162
2-Butoxyethyl acetate C8
H16
O3
464.2(0.9) 640(2) 2.7(0.2) 551(21) 144, 163
1-tert-Butoxy-2-methoxyethane C7
H16
O2
404(15) 574(1) 2.8(0.7) 480(13) 162
1-Butoxy-2-propanol C7
H16
O2
445(3) 625(1) 2.7(0.1) 479(20) 32
Butyl acetate C6
H12
O2
381(4) 578(10) 3.16(0.06) 403(6) 162, 164–167
sec-Butyl acetate C6
H12
O2
371(1) 571.1(0.5) 3.01(0.1) 398(14) 164, 165
tert-Butyl acetate C6
H12
O2
399.1(0.1) 541(4) 3.0(0.1) 399(7) 54
Butyl acrylate C7
H12
O2
419.8(0.6) 597.4(0.6) 2.76(0.03) 445(7) 51
Butylamine C4
H11
N 335.86(0.08) 531.9(0.2) 4.20(0.04) 291(13) 168
sec-Butylamine C4
H11
N 317.17(0.07) 514.3(0.2) 4.0(0.2) 284(11) 168
tert-Butylamine C4
H11
N 350.1(0.2) 483.7(0.6) 3.85(0.06) 293(23) 75
Butylbenzene C10
H14
446.4(0.4) 660.5(0.1) 2.89(0.03) 498(18) 79, 86, 88
sec-Butylbenzene C10
H14
442.2(0.3) 652(1) 2.94(0.03) 488(39) 58
tert-Butylbenzene C10
H14
456.4(0.3) 648(1) 3.00(0.03) 474(30) 58, 64
Butyl benzoate C11
H14
O2
522(3) 725(14) 2.4(0.3) 594(10) 169
Butyl butanoate C8
H16
O2
438.1(0.1) 612(3) 2.4(0.2) 550(9) 162
Butylcyclohexane C10
H20
444.8(0.4) 653.1(0.4) 2.57(0.07) 547(14) 170, 171
tert-Butylcyclohexane C10
H20
454.0(0.6) 652.0(0.4) 2.82(0.09) 537(15) 170
tert-Butyl ethyl ether C6
H14
O 345.8(0.1) 509(2) 3.0(0.2) 394(4) 172
Butyl methyl ether C5
H12
O 343.2(0.3) 512.7(0.1) 3.37(0.02) 340(2) 25, 173, 174
Butyl propanoate C7
H14
O2
418.2(0.1) 594(1) 2.8(0.2) 464(10) 162
Butyl vinyl ether C6
H12
O 367(1) 540(1) 3.12(0.01) 379(10) 175
γ-Butyrolactone C4
H6
O2
477.8(0.4) 731(1) 5(1) 246(18) 49
6-60	 Critical Constants of Organic Compounds
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
Chlorobenzene C6
H5
Cl 404.8(0.2) 632.4(0.1) 4.5(0.1) 303(79) 19, 33, 34
1-Chlorobutane C4
H9
Cl 351.5(0.2) 539.2(0.6) 4.1(0.2) 303(11) 119
2-Chlorobutane C4
H9
Cl 341.4 518.6(0.6) 3.4(0.2) 307(14) 119
1-Chloro-2,4-difluorobenzene C6
H3
ClF2
400 609.6(0.4) 4.0(0.7) 333(16) 119
1-Chloro-2,5-difluorobenzene C6
H3
ClF2
401 612.5(0.4) 4.0(0.7) 333(16) 119
1-Chloro-3,4-difluorobenzene C6
H3
ClF2
400 609.2(0.4) 4.0(0.6) 333(16) 119
1-Chloro-3,5-difluorobenzene C6
H3
ClF2
391.7 592.0(0.4) 3.9(0.7) 327(16) 119
1-Chloro-1,1-difluoroethane C2
H3
ClF2
264.03(0.07) 410.31(0.05) 4.06(0.03) 230(6) 113, 176–178
1-Chloro-2,2-difluoroethene C2
HClF2
254.3(0.5) 400.5(0.7) 4.54(0.07) 197(6) 179
Chlorodifluoromethane CHClF2
232.3(0.5) 369.30(0.05) 4.98(0.01) 165(2) 180–191
2-Chloro-2-(difluoromethoxy)-1,1,1-
trifluoroethane
C3
H2
ClF5
O 322.4(0.1) 467.8(0.6) 3.05(0.03) 316(24) 192
Chloroethane C2
H5
Cl 285.4(0.2) 460.3(0.4) 5.24(0.04) 198(11) 193
Chloroethene C2
H3
Cl 259.3(0.3) 425(5) 5.60(0.03) 171(9) 194
1-Chloro-2-fluorobenzene C6
H4
ClF 410.8 633.8(0.4) 4.3(0.6) 319(21) 119
1-Chloro-3-fluorobenzene C6
H4
ClF 401(25) 615.9(0.4) 4.2(0.6) 324(21) 119
1-Chloro-4-fluorobenzene C6
H4
ClF 403 620.1(0.4) 4.2(0.4) 322(18) 119
1-Chloroheptane C7
H15
Cl 432(2) 614(8) 3.1(0.6) 492(14) 119
1-Chlorohexane C6
H13
Cl 408.1(0.5) 599(3) 3.3(0.3) 422(12) 119
Chloromethane CH3
Cl 249.0(0.3) 416.24(0.04) 6.72(0.03) 136(2) 195, 196
2-Chloro-2-methylbutane C5
H11
Cl 358(1) 509.1(0.6) 3.2(0.5) 397(15) 119
3-Chloro-3-methylpentane C6
H13
Cl 389 528(3) 3(1) 414(14) 119
2-Chloro-2-methylpropane C4
H9
Cl 324.0(0.5) 497.8(0.1) 3.7(0.4) 308(13) 34
1-Chlorooctane C8
H17
Cl 456(3) 643(2) 2.5(0.4) 543(13) 119
Chloropentafluoroacetone C3
ClF5
O 280.9(0.9) 410.6(0.1) 2.89(0.01) 277(21) 197
Chloropentafluorobenzene C6
ClF5
391.11 570(1) 3.2(0.2) 367(25) 198
Chloropentafluoroethane C2
ClF5
233.9(0.2) 353.0(0.2) 3.141(0.01) 255(4) 199, 200
1-Chloropentane C5
H11
Cl 381.0(0.3) 571.2(0.4) 3.3(0.2) 361(12) 119
1-Chloropropane C3
H7
Cl 319.3(0.5) 503.3(0.4) 4.56(0.04) 268(24) 118, 193, 201, 202
2-Chloropropane C3
H7
Cl 308.1(0.6) 482.4(0.4) 4.25(0.04) 245(16) 201, 202
1-Chloro-1,2,2,2-tetrafluoroethane C2
HClF4
261.19(0.09) 395.43(0.06) 3.62(0.01) 244(4) 203, 204
4-Chlorotoluene C7
H7
Cl 435.0(0.2) 615.9(0.5) 2.33(0.09) 377(16) 88
2-Chloro-1,1,1-trifluoroethane C2
H2
ClF3
279.1(0.6) 425.0(0.2) 4.02(0.02) 232(6) 205
Chlorotrifluoroethene C2
ClF3
244.8(0.3) 380.1(0.1) 3.95(0.03) 214(12) 206, 207
2-Chloro-1,1,2-trifluoroethyl difluoromethyl
ether
C3
H2
ClF5
O 329.9(0.5) 475.0(0.6) 2.98(0.03) 343(25) 192
Chlorotrifluoromethane CClF3
191.8 301.9(0.2) 3.89(0.01) 180.3(1) 191, 208–216
m-Cresol C7
H8
O 475.3(0.1) 705.8(0.4) 4.4(0.2) 337(12) 39, 40, 217, 218
o-Cresol C7
H8
O 464.1(0.1) 697.6(0.2) 4.2(0.2) 336(12) 217, 218
p-Cresol C7
H8
O 475.0(0.1) 704.6(0.3) 4.1(0.2) 349(13) 217, 218
Cyanogen C2
N2
252.1 397(3) 6.2(0.4) 149(8) 219
Cycloheptane C7
H14
391.9(0.2) 604.2(0.1) 3.85(0.04) 361(12) 34, 220, 221
Cyclohexane C6
H12
353.8(0.7) 553.4(0.3) 4.07(0.01) 307(12) 19, 34, 78, 82, 84, 88, 90,
144, 163, 170, 171,
220, 222–231
Cyclohexanol C6
H12
O 434.0(0.2) 647.1(0.3) 4.3(0.1) 334(33) 49, 232, 233
Cyclohexanone C6
H10
O 428.5(0.1) 665(1) 4.61(0.09) 354(12) 162, 166
Cyclohexene C6
H10
356.0(0.2) 560.45(0.02) 4.43(0.08) 290(20) 86, 201, 202
Cyclohexylamine C6
H13
N 406.8(0.5) 626.8(0.9) 3.9(0.6) 349(15) 170
Cyclooctane C8
H16
424.2(0.1) 647.2(0.4) 3.55(0.06) 417(28) 34, 170, 220, 221
Cyclopentane C5
H10
322.3(0.1) 511.7(0.2) 4.51(0.07) 264(10) 34, 78, 90, 234–236
Cyclopentanol C5
H10
O 413.5(0.2) 619(1) 4.9(0.1) 288(19) 233
Cyclopentanone C5
H8
O 403.6(0.2) 624(2) 4.59(0.05) 276(17) 233
Cyclopentene C5
H8
317.3(0.2) 506.1(0.2) 4.78(0.05) 252(16) 90, 144, 163, 201, 202
Cyclopropane C3
H6
242(2) 398.2(0.4) 5.58(0.02) 164(9) 237, 238
Decafluorobiphenyl C12
F10
480(2) 640(4) 2.3(0.3) 641(40) 239
1,1,1,2,2,3,4,5,5,5-Decafluoro-3,4-
bis(trifluoromethyl)-pentane
C7
F16
632(5) 240
1,1,1,2,2,3,4,5,5,5-Decafluoro-3-[1,2,2,2-
tetrafluoro-1-(trifluoromethyl)ethyl]-4-
(trifluoromethyl)pentane
C9
F20
399(24) 581(43) 1(2) 800(7) 240
cis-Decahydronaphthalene C10
H18
469.0(0.3) 702(1) 3.2(0.3) 492(19) 241
Critical Constants of Organic Compounds	 6-61
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
trans-Decahydronaphthalene C10
H18
460.4(0.2) 687(1) 3.1(0.1) 499(19) 241
Decamethylcyclopentasiloxane C10
H30
O5
Si5
486(3) 617.4(0.3) 1.04(0.02) 1201(2) 34, 114
Decanal C10
H20
O 485(3) 674(1) 2.6(0.3) 601(14) 163, 242
Decane C10
H22
447.2(0.1) 618.1(0.9) 2.10(0.03) 621(35) 16, 33, 65, 78, 86, 131,
243–252
1,10-Decanediamine C10
H24
N2
535(12) 736(8) 2.4(0.3) 654(28) 140
Decanedioic acid C10
H18
O4
647(5) 845(13) 2.5(0.1) 724(21) 253
Decanoic acid C10
H20
O2
543(1) 724(5) 1.9(0.8) 638(24) 145, 146
1-Decanol C10
H22
O 502(3) 690(10) 2.3(0.1) 624(87) 149, 152, 254, 255
2-Decanol C10
H22
O 484 668.5(0.3) 2.3(0.5) 646(13) 255
3-Decanol C10
H22
O 490(7) 666.1(0.3) 2.3(0.3) 643(13) 255
4-Decanol C10
H22
O 487(3) 663.7(0.3) 2.3(0.1) 643(13) 255
5-Decanol C10
H22
O 489(5) 663.2(0.4) 2.3(0.4) 646(13) 255
2-Decanone C10
H20
O 484(3) 671.8(0.5) 2.2(0.3) 625(25) 256
3-Decanone C10
H20
O 485(4) 668(1) 2.2(0.2) 628(15) 256
4-Decanone C10
H20
O 479.7 662.9(0.5) 2.2(0.2) 636(18) 256
5-Decanone C10
H20
O 477 661.0(0.4) 2.2(0.2) 628(25) 256
1-Decene C10
H20
444(1) 616.0(0.3) 2.157(0.01) 594(3) 257
Decylbenzene C16
H26
571(1) 752(8) 1.72(0.1) 879(29) 258
Dibenzofuran C12
H8
O 558.3(0.3) 824(2) 3.37(0.03) 494(32) 259
Dibenzothiophene C12
H8
S 604.8(0.4) 897(2) 3.9(0.2) 506(108) 260
1,2-Dibromo-1-chloro-1,2,2-trifluoroethane C2
Br2
ClF3
365.9(0.2) 560.6(0.2) 3.61(0.02) 368(4) 261
1,4-Dibromooctafluorobutane C4
Br2
F8
371(25) 532(2) 2.4(0.3) 452(29) 198
Dibutylamine C8
H19
N 435(2) 607.5(0.2) 3.11(0.03) 532(21) 168
1,4-Di-tert-butylbenzene C14
H22
510.4(0.5) 708(2) 2.23(0.01) 732(70) 232
Dibutyl ether C8
H18
O 414.8(0.3) 584.1(0.2) 2.4(0.2) 521(12) 262
Dibutyl phthalate C16
H22
O4
611(9) 797(9) 1.6(0.3) 954(18) 112
m-Dichlorobenzene C6
H4
Cl2
445(2) 685.7(0.4) 4.2(0.2) 366(22) 119
1,4-Dichlorobenzene C6
H4
Cl2
447.0(0.2) 669(5) 3.54(0.07) 364(22) 263
Dichlorodiethylsilane C4
H10
Cl2
Si 403(2) 595.7(0.6) 3.06(0.03) 455(4) 264
Dichlorodifluoromethane CCl2
F2
243.3(0.1) 384.9(0.2) 4.12(0.01) 218(36) 191, 216, 265
Dichlorodimethylsilane C2
H6
Cl2
Si 343.6(0.5) 520.3(0.6) 3.49(0.03) 350(5) 266
1,1-Dichloroethane C2
H4
Cl2
329.4(0.7) 523.4(0.1) 5.1(0.5) 248(12) 267
1,2-Dichloroethane C2
H4
Cl2
356.5(0.1) 561.5(0.4) 5.4(0.1) 225(8) 33, 34, 268, 269
cis-1,2-Dichloroethene C2
H2
Cl2
333(2) 535.8(0.4) 5.4(0.3) 220(15) 34
trans-1,2-Dichloroethene C2
H2
Cl2
320.79(0.08) 515.5(0.2) 5.3(0.2) 216(14) 33, 34
1,1-Dichloro-1-fluoroethane C2
H3
Cl2
F 305.20(0.09) 477.3(0.1) 4.20(0.02) 253.7(0.6) 178, 270
Dichlorofluoromethane CHCl2
F 282.1 451.6(0.4) 5.20(0.01) 196(1) 271
1,2-Dichlorohexafluoropropane C3
Cl2
F6
307(2) 451.8(0.1) 2.63(0.07) 365(48) 272
Dichloromethane CH2
Cl2
312.9(0.3) 508.0(0.2) 6.35(0.05) 177(13) 273
1,2-Dichloropropane C3
H6
Cl2
369.6 578(2) 4.63(0.06) 292(6) 119, 232
1,3-Dichloropropane C3
H6
Cl2
393.9(0.3) 615(3) 4.7(0.5) 299(16) 119
1,1-Dichloro-1,2,2,2-tetrafluoroethane C2
Cl2
F4
276(1) 418.6(0.8) 3.31(0.03) 294(8) 179
1,2-Dichloro-1,1,2,2-tetrafluoroethane C2
Cl2
F4
276.8(0.5) 418.74(0.06) 3.25(0.02) 295(3) 191, 274
1,2-Dichloro-1,1,2-trifluoroethane C2
HCl2
F3
303.1(0.1) 461.6(0.1) 3.77(0.08) 283.2(0.5) 178
2,2-Dichloro-1,1,1-trifluoroethane C2
HCl2
F3
300.9(0.6) 456.8(0.2) 3.67(0.01) 278(2) 182, 275–280
Didecyl phthalate C28
H46
O4
736(4) 870(10) 0.94(0.05) 1807(27) 112
1,1-Diethoxyethane C6
H14
O2
375(2) 539.7(0.4) 3.22(0.08) 426(12) 166
1,2-Diethoxyethane C6
H14
O2
393.8(0.7) 542(3) 2.14(0.02) 432(11) 162
Diethoxymethane C5
H12
O2
359(2) 532(1) 3.4(0.5) 370(10) 162
Diethylamine C4
H11
N 328.5(0.1) 499.5(0.4) 3.75(0.02) 304(32) 38, 117, 133, 281, 282
p-Diethylbenzene C10
H14
457(1) 657.90(0.03) 2.80(0.08) 494(12) 79, 86
Diethylene glycol C4
H10
O3
518.6(0.2) 753(4) 4.8(0.2) 325(19) 283
Diethylene glycol diethyl ether C8
H18
O3
458(4) 612(10) 2.4(0.7) 587(18) 162
Diethylene glycol dimethyl ether C6
H14
O3
435(2) 617(4) 3.0(0.6) 450(16) 162
Diethylene glycol monobutyl ether C8
H18
O3
505(4) 692(3) 2.8(0.6) 546(26) 41
Diethylene glycol monobutyl ether acetate C10
H20
O4
521(2) 694(2) 2.15(0.05) 627(20) 55
Diethylene glycol monoethyl ether C6
H14
O3
475(3) 670(4) 3.2(0.1) 427(23) 49
Diethylene glycol monoethyl ether acetate C8
H16
O4
491(1) 670(12) 2.50(0.06) 524(18) 49, 55
Diethylene glycol monomethyl ether C5
H12
O3
467(2) 672(2) 3.7(0.2) 378(25) 49
Diethylene glycol monopropyl ether C7
H16
O3
488.0(0.4) 680(2) 3.05(0.07) 495(18) 41, 104
6-62	 Critical Constants of Organic Compounds
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
Diethyl ether C4
H10
O 307.5(0.5) 466.8(0.3) 3.64(0.01) 280(5) 19, 77, 95, 155, 196,
284–301
Diethyl oxalate C6
H10
O4
459(1) 618(2) 2.14(0.02) 464(37) 101
Diethyl phthalate C12
H14
O4
571(2) 776(9) 2.2(0.2) 687(15) 112
Diethyl succinate C8
H14
O4
490(1) 663(30) 2.26(0.02) 567(44) 101, 302
Diethyl sulfide C4
H10
S 365.2(0.2) 557.5(1) 4.0(0.1) 322(8) 32, 303, 304
m-Difluorobenzene C6
H4
F2
356.1(0.5) 548.4(0.4) 4.20(0.01) 289(21) 119
o-Difluorobenzene C6
H4
F2
367.0(0.5) 566.0(0.4) 4.28(0.01) 290(21) 119
p-Difluorobenzene C6
H4
F2
362.0(0.3) 556.9(0.4) 4.28(0.07) 297(22) 119
1,1-Difluoroethane C2
H4
F2
249.1 386.4(0.1) 4.52(0.01) 178(2) 178, 180, 185, 305–307
1,1-Difluoroethene C2
H2
F2
187.6(0.8) 302.9(0.6) 4.48(0.05) 155(4) 179, 215
2,2-Difluoroethylbis(trifluoromethyl)amine C4
H3
F8
N 324.5 460.20(0.09) 2.64(0.01) 375(1) 308
Difluoromethane CH2
F2
221.50(0.07) 351.28(0.03) 5.79(0.01) 121(4) 306, 309–316
3-Difluoromethoxy-1,1,1,2,2-pentafluoropropane C4
H3
F7
O 319.09 455.1(0.1) 2.77(0.02) 363(1) 113
2-(Difluoromethoxy)-1,1,1-trifluoroethane C3
H3
F5
O 302.3(0.2) 444.9(0.3) 3.43(0.01) 291(19) 113
2,4-Difluorotoluene C7
H6
F2
390 581.4(0.4) 3.7(0.4) 340(21) 119
2,5-Difluorotoluene C7
H6
F2
391 587.8(0.4) 3.8(0.5) 341(21) 119
2,6-Difluorotoluene C7
H6
F2
385 581.8(0.4) 3.7(0.4) 341(21) 119
3,4-Difluorotoluene C7
H6
F2
385 598.5(0.5) 3.8(0.6) 342(22) 119
Diheptyl phthalate C22
H34
O4
633 830(9) 1.24(0.08) 1153(22) 112
Dihexyl phthalate C20
H30
O4
652(5) 817(9) 1.3(0.1) 1061(22) 112
3,4-Dihydro-2H-pyran C5
H8
O 358.6(0.2) 561(2) 4.63(0.08) 268(34) 75
Diisobutylamine C8
H19
N 412.8 584.4(0.2) 3.20(0.06) 518(22) 168
Diisopropylamine C6
H15
N 357(3) 523.1(0.2) 3.02(0.02) 407(18) 168
1,4-Diisopropylbenzene C12
H18
483.4(0.2) 675(1) 2.30(0.04) 610(65) 317
Diisopropyl ether C6
H14
O 341.5(0.2) 500.2(0.7) 2.85(0.04) 386(5) 25, 290, 318, 319
1,2-Dimethoxyethane C4
H10
O2
358.1(0.1) 539(4) 3.91(0.05) 305(9) 162, 166, 175, 290
Dimethoxymethane C3
H8
O2
315.4(0.2) 488(11) 4.0(0.2) 259(10) 75, 162, 320
1,2-Dimethoxypropane C5
H12
O2
369 543(1) 3.4(0.6) 356(12) 162
2,2-Dimethoxypropane C5
H12
O2
350.5(0.7) 510(3) 4(1) 360(13) 162
Dimethyl adipate C8
H14
O4
504(3) 692(14) 2.5(0.5) 561(13) 321
Dimethylamine C2
H7
N 280.4(0.4) 437.5(0.4) 5.34(0.05) 188(13) 193, 322, 323
N,N-Dimethylaniline C8
H11
N 466(1) 687.7(0.6) 3.63(0.09) 407(15) 39, 40
2,2-Dimethylbutane C6
H14
322.8(0.2) 489.1(0.5) 3.10(0.01) 363.74(0.02) 86, 324–328
2,3-Dimethylbutane C6
H14
331.1(0.3) 500.2(0.3) 3.13(0.01) 358(1) 19, 86, 252, 324–330
3,3-Dimethyl-2-butanone C6
H12
O 379.2(0.2) 570.9(0.3) 3.67(0.03) 383(6) 164, 165
2,3-Dimethyl-1-butene C6
H12
328.74(0.04) 497.7(0.9) 3.31(0.01) 346(9) 170
3,3-Dimethyl-1-butene C6
H12
346.34(0.06) 477.4(0.9) 3.18(0.02) 348(10) 170
2,3-Dimethyl-2-butene C6
H12
314.39(0.04) 521.0(0.9) 3.4(0.1) 344(7) 170
Dimethyl carbonate C3
H6
O3
363.26(0.09) 557(1) 4.8(0.2) 251(51) 331, 332
cis-1,3-Dimethylcyclohexane C8
H16
397.5(0.6) 587.7(0.5) 2.88(0.01) 429(10) 64
cis-1,4-Dimethylcyclohexane C8
H16
392.4(0.5) 603.2(0.3) 3.44(0.02) 434(7) 164, 165
trans-1,4-Dimethylcyclohexane C8
H16
397.4(0.7) 588(2) 3.04(0.01) 439(18) 74
Dimethyl disulfide C2
H6
S2
382.87(0.08) 608(4) 5.1(0.1) 266(8) 54
Dimethyl ether C2
H6
O 248.3(0.2) 400.1(0.8) 5.31(0.03) 171(3) 125, 174, 186, 333–343
N,N-Dimethylformamide C3
H7
NO 426.0(0.5) 649.6(0.8) 4.4(0.1) 262(9) 11, 344
Dimethyl glutarate C7
H12
O4
489(4) 682(14) 2.8(0.4) 488(14) 321
2,2-Dimethylheptane C9
H20
406(1) 576.7(0.5) 2.35(0.07) 546(12) 345
2,2-Dimethylhexane C8
H18
379.9(0.4) 549.9(0.4) 2.53(0.03) 481(10) 346
2,3-Dimethylhexane C8
H18
388.8(0.5) 563.5(0.4) 2.63(0.02) 466(16) 346
2,4-Dimethylhexane C8
H18
382.5(0.4) 553(3) 2.55(0.02) 480(39) 330, 346
2,5-Dimethylhexane C8
H18
382.2(0.7) 550.0(0.3) 2.49(0.02) 485(20) 19, 346
3,3-Dimethylhexane C8
H18
385.0(0.6) 562.0(0.4) 2.65(0.02) 450(17) 346
3,4-Dimethylhexane C8
H18
390.8(0.4) 568.8(0.4) 2.69(0.02) 467(21) 346
Dimethyl malonate C5
H8
O4
454.2(0.6) 647(1) 3.5(0.1) 368(13) 317, 321
2,7-Dimethylnaphthalene C12
H12
535.5(0.3) 775(2) 3.02(0.03) 515(45) 347
Dimethyl octanedioate C10
H18
O4
532(8) 723(14) 2.3(0.3) 672(14) 321
Dimethyl oxalate C4
H6
O4
436.5(0.5) 632(14) 4.0(0.3) 315(12) 321, 348
2,2-Dimethyloxirane C4
H8
O 324(2) 500(4) 4.4(0.1) 327(31) 54
2,2-Dimethylpentane C7
H16
352.3(0.3) 520.6(0.6) 2.77(0.04) 409(12) 346, 349
2,3-Dimethylpentane C7
H16
362.9(0.6) 537.5(0.6) 2.92(0.08) 394(23) 346, 349, 350
Critical Constants of Organic Compounds	 6-63
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
2,4-Dimethylpentane C7
H16
353.5(0.5) 520.0(0.7) 2.74(0.06) 415(19) 346, 349
3,3-Dimethylpentane C7
H16
359.1(0.6) 536.4(0.4) 2.94(0.02) 413(24) 346
2,3-Dimethyl-1-pentene C7
H14
357(1) 534(4) 2.9(0.8) 400(11) 170
4,4-Dimethyl-1-pentene C7
H14
345.6(0.2) 516(4) 2.91(0.01) 406(11) 170
Dimethyl phthalate C10
H10
O4
555.8(0.2) 772(9) 2.76(0.08) 557(17) 112
Dimethyl pimelate C9
H16
O4
518(2) 711(14) 2.4(0.1) 608(14) 321
2,3-Dimethylpyridine C7
H9
N 434.2(0.4) 655.5(0.3) 4.03(0.01) 337(28) 86, 351
2,4-Dimethylpyridine C7
H9
N 431.5(0.3) 647.1(0.9) 3.83(0.02) 363(34) 90, 352
2,5-Dimethylpyridine C7
H9
N 430.15(0.05) 644.2(0.3) 4.11(0.04) 371(45) 86
2,6-Dimethylpyridine C7
H9
N 417.1(0.1) 623.8(0.2) 3.80(0.04) 353(43) 90
3,4-Dimethylpyridine C7
H9
N 452.2(0.3) 683.8(0.4) 4.06(0.01) 353(13) 86, 351, 352
3,5-Dimethylpyridine C7
H9
N 445.0(0.1) 667.3(0.3) 3.84(0.02) 369(12) 86, 351
2,6-Dimethylquinoline C11
H11
N 541.2(0.4) 786(2) 3.27(0.02) 505(24) 529
Dimethyl sebacate C12
H22
O4
562(3) 742(14) 2.1(0.2) 695(14) 321
Dimethyl succinate C6
H10
O4
470(1) 662(14) 3.5(0.2) 426(16) 321
Dimethyl sulfide C2
H6
S 310.47(0.05) 503.0(0.3) 5.40(0.06) 201(9) 52, 117, 304
Dimethyl sulfoxide C2
H6
OS 465.0(0.9) 707(1) 4.6(0.7) 228(7) 23
1,3-Dimethyl-1,1,3,3-tetraphenyldisiloxane C26
H26
OSi2
701(2) 893(9) 1.38(0.1) 1300(89) 353
1,3-Dimethyltricyclo[3.3.1.13,7
]decane C12
H20
476.53 708(2) 2.86(0.01) 595(115) 141
Dinonyl phthalate C26
H42
O4
686 858(9) 1.0(0.3) 1652(26) 112
Dioctyl phthalate C24
H38
O4
688(4) 840(9) 1.1(0.1) 1510(22) 112
1,4-Dioxane C4
H8
O2
374.3(0.3) 587.3(0.1) 5.2(0.2) 251(5) 34, 290, 354
Dipentyl phthalate C18
H26
O4
614(40) 811(9) 1.4(0.7) 957(21) 112
Diphenyl ether C12
H10
O 531.1(0.1) 766.9(0.8) 3.10(0.04) 526(23) 25, 355
Diphenylmethane C13
H12
537.3(0.3) 776(9) 3.02(0.07) 546(144) 39, 302, 356, 357
1,3-Diphenyltetramethyldisiloxane C16
H22
OSi2
750(8) 353
Dipropylamine C6
H15
N 380.6(0.9) 555.8(0.1) 3.6(0.1) 414(15) 168
Dipropylene glycol C6
H14
O3
504(2) 705(4) 3.4(0.1) 444(18) 54
Dipropyl ether C6
H14
O 363.2(0.3) 531(2) 2.92(0.05) 402(8) 25, 52
Dipropyl phthalate C14
H18
O4
592(2) 784(9) 1.9(0.1) 816(20) 112
Diundecyl phthalate C30
H50
O4
711(25) 886(10) 0.89(0.1) 1590(25) 112
Docosane C22
H46
642(5) 786(6) 1.0(0.1) 1434(50) 62, 358, 359
Docosanoic acid C22
H44
O2
693(3) 837(8) 1.11(0.08) 1485(29) 360
1-Docosanol C22
H46
O 680(12) 827(8) 1.0(0.6) 1243(20) 361
1,2,2,3,3,4,4,5,5,6,6,7-Dodecafluoro-1-heptanol C7
H4
F12
O 444.7(0.7) 589(5) 2.0(0.2) 620(34) 362
Dodecane C12
H26
489.4(0.2) 658.8(0.9) 1.80(0.09) 747(18) 34, 86, 118, 243, 244,
363, 364
1,12-Dodecanediamine C12
H28
N2
572(13) 767(8) 2.0(0.3) 765(37) 140
Dodecanedioic acid C12
H22
O4
621(10) 859(13) 2.1(0.2) 730(19) 253
1-Dodecanethiol C12
H26
S 550(3) 734(4) 1.81(0.1) 726(25) 99
Dodecanoic acid C12
H24
O2
572(1) 743(7) 1.9(0.2) 787(19) 360
1-Dodecanol C12
H26
O 537.2(0.3) 719.4(0.6) 2.02(0.05) 805(15) 149
2-Dodecanone C12
H24
O 520(6) 702(4) 1.9(0.9) 742(20) 256
3-Dodecanone C12
H24
O 523(3) 701(2) 1.9(0.2) 680(19) 256
4-Dodecanone C12
H24
O 528(5) 697(2) 1.9(0.4) 672(19) 256
5-Dodecanone C12
H24
O 521(4) 695(5) 1.9(0.4) 678(19) 256
6-Dodecanone C12
H24
O 522(4) 694(2) 1.9(0.3) 677(19) 256
1-Dodecene C12
H24
486.5(0.9) 657.6(0.6) 1.88(0.01) 710(15) 257
Eicosane C20
H42
617.2(0.9) 768(6) 1.08(0.05) 1325(48) 358, 359
Eicosanoic acid C20
H40
O2
673(6) 820(8) 1.2(0.1) 1346(27) 360
1-Eicosanol C20
H42
O 629 808(8) 1.1(0.2) 1130(18) 361
1-Eicosene C20
H40
620(15) 772(15) 1.1(0.3) 1213(36) 365
Ethane C2
H6
184.5(0.4) 305.36(0.04) 4.88(0.01) 146(3) 44, 48, 92, 131, 132, 134,
214, 215, 229, 246,
366–393
1,2-Ethanediamine C2
H8
N2
390.0(0.5) 613.1(0.3) 6.71(0.04) 204(13) 49
1,2-Ethanediol C2
H6
O2
470.6(0.1) 719(5) 8.1(0.4) 180(11) 11, 32, 41, 394
1,1-Ethanediol, diacetate C6
H10
O4
441(3) 618(4) 2.9(0.1) 457(13) 54
Ethanethiol C2
H6
S 308.1(0.1) 498.7(0.3) 5.53(0.08) 208(10) 304
6-64	 Critical Constants of Organic Compounds
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
Ethanol C2
H6
O 351.39(0.09) 515(1) 6.25(0.04) 169(4) 19, 25, 34, 80, 85, 128,
148–150, 152, 222,
395–409
Ethoxybenzene C8
H10
O 443.0(0.2) 647(2) 3.45(0.05) 407(16) 39, 40
2-Ethoxyethyl acetate C6
H12
O3
429.8(0.4) 609(2) 3.07(0.03) 443(38) 141, 144, 163
2-Ethoxy-2-methylbutane C7
H16
O 374.6(0.4) 546(2) 2.83(0.09) 448(29) 410
1-Ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane C6
H5
F9
O 350.04 482.0(0.1) 1.98(0.01) 518(2) 113
Ethyl acetate C4
H8
O2
350.2(0.2) 523.27(0.07) 3.88(0.02) 288(19) 19, 23, 400,
411–413
Ethylamine C2
H7
N 289.8(0.2) 456.5(0.9) 5.6(0.1) 183(22) 193, 414
Ethylbenzene C8
H10
409.3(0.4) 617.1(0.1) 3.61(0.01) 365(61) 68, 78, 79, 86, 88, 172,
345
Ethyl benzoate C9
H10
O2
485.6(0.2) 700(14) 3.01(0.05) 470(12) 169
Ethyl butanoate C6
H12
O2
394.2(0.4) 566.1(0.1) 3.2(0.3) 421(30) 415, 416
Ethyl trans-2-butenoate C6
H10
O2
413(5) 599(10) 3(2) 382(7) 21
Ethylcyclohexane C8
H16
404.9(0.4) 606.9(0.4) 3.27(0.04) 431(12) 170, 171
Ethylcyclopentane C7
H14
376.6(0.6) 569.48(0.05) 3.40(0.07) 377(3) 236
Ethyl 2,2-dimethylpropanoate C7
H14
O2
391.4(0.4) 566(2) 2.88(0.02) 461(8) 417
Ethylene C2
H4
169.3(0.3) 282.35(0.03) 5.06(0.01) 130.9(0.2) 61, 246, 371, 418–436
Ethyl 3-ethoxypropanoate C7
H14
O3
441(2) 621(3) 2.7(0.1) 478(19) 11, 41
Ethyl formate C3
H6
O2
327.2(0.1) 508.5(0.5) 4.78(0.03) 223(47) 413, 415
Ethyl heptanoate C9
H18
O2
461(2) 634(1) 2.3(0.2) 587(8) 162
3-Ethylhexane C8
H18
391.6(0.5) 565.5(0.4) 2.61(0.02) 450(15) 346
Ethyl hexanoate C8
H16
O2
438(1) 615(1) 2.6(0.2) 528(8) 162
2-Ethylhexanoic acid C8
H16
O2
500.6(0.1) 674(1) 2.75(0.06) 543(8) 144, 163
2-Ethyl-1-hexanol C8
H18
O 459.3(0.2) 640.2(0.3) 3.0(0.2) 508(29) 437
2-Ethylhexyl acetate C10
H20
O2
473(1) 642(2) 2.02(0.01) 644(10) 410
Ethyl 3-methylbutanoate C7
H14
O2
408(3) 584(6) 3(1) 463(9) 147, 162
Ethyl methyl ether C3
H8
O 279(2) 437.8(0.2) 4.39(0.06) 219(5) 174, 304, 438
3-Ethyl-2-methylpentane C8
H18
388.8(0.6) 567.1(0.4) 2.70(0.02) 442(22) 346
3-Ethyl-3-methylpentane C8
H18
391.3(0.9) 576.5(0.4) 2.77(0.01) 463(13) 346
Ethyl 2-methylpropanoate C6
H12
O2
384(2) 554(4) 3.1(0.3) 421(76) 415
Ethyl methyl sulfide C3
H8
S 339.8(0.3) 533(10) 4.62(0.03) 260(6) 303
Ethyl nonanoate C11
H22
O2
497(5) 664(1) 2.0(0.4) 715(8) 162
Ethyl octanoate C10
H20
O2
479(1) 652(12) 2(2) 657(8) 147, 162
3-Ethylpentane C7
H16
366.5(0.4) 540.7(0.4) 2.90(0.03) 412(14) 346, 349
Ethyl pentanoate C7
H14
O2
415(3) 593(1) 2.8(0.4) 466(10) 162
2-Ethylphenol C8
H10
O 477.6(0.1) 703(1) 3.7(0.3) 388(15) 218
3-Ethylphenol C8
H10
O 491.5(0.1) 716(1) 3.8(0.3) 393(15) 218
4-Ethylphenol C8
H10
O 491.12(0.06) 716(1) 3.1(0.6) 395(15) 218
Ethyl propanoate C5
H10
O2
372.0(0.2) 547(1) 3.37(0.05) 343(23) 19, 64, 162, 413, 415
Ethyl propyl ether C5
H12
O 336(3) 500.2(0.4) 3.37(0.01) 343(44) 25, 304
S-Ethyl thioacetate C4
H8
OS 387(3) 590.5(0.2) 4.1(0.1) 320(10) 49
4-Ethyltoluene C9
H12
435.1(0.6) 640.2(0.5) 3.23(0.04) 446(12) 439, 440
Ethyl vinyl ether C4
H8
O 309(2) 475(2) 4.06(0.04) 262(8) 290
Fluorobenzene C6
H5
F 357.8(0.3) 560.10(0.07) 4.55(0.01) 272(9) 86, 441
Fluoroethane C2
H5
F 235.4(0.3) 375.2(0.2) 5.02(0.01) 164(3) 206, 442, 443
Fluoromethane CH3
F 194.8 317.42(0.01) 5.88(0.01) 112.41(0.01) 444, 445
2-Fluorotoluene C7
H7
F 387(2) 591.2(0.4) 3.9(0.3) 323(47) 119
3-Fluorotoluene C7
H7
F 389(2) 591.8(0.4) 3.9(0.3) 332(17) 119
4-Fluorotoluene C7
H7
F 389.8(0.4) 592.1(0.8) 3.85(0.01) 332(17) 119
Formic acid CH2
O2
374 588(10) 115.88(0.08) 146
Furan C4
H4
O 304.4(0.2) 490.2(0.2) 5.43(0.08) 218(3) 241, 290
Glycerol C3
H8
O3
562(3) 850(9) 7.6(0.8) 251(15) 394
Heneicosane C21
H44
632(6) 778(8) 1.0(0.1) 1366(48) 359
Heptadecane C17
H36
576(2) 736(1) 1.33(0.07) 1081(28) 359
Heptadecanoic acid C17
H34
O2
635(4) 792(8) 1.4(0.1) 1130(24) 360
1-Heptadecanol C17
H36
O 597 780(8) 1.4(0.1) 1097(18) 361
1-Heptadecene C17
H34
574(3) 734(7) 1.34(0.08) 1053(35) 365
2,2,3,3,5,5,6-Heptafluoro-1,4-dioxane C4
HF7
O2
312.5(0.1) 453(1) 2.86(0.06) 359(4) 110
1,1,1,2,2,3,3-Heptafluoropentan-4-one C5
H3
F7
O 337.4 476.55(0.08) 2.57(0.01) 394.2(0.7) 308
Critical Constants of Organic Compounds	 6-65
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
1,1,1,2,3,3,3-Heptafluoropropane C3
HF7
257.65 375.0(0.1) 2.93(0.01) 299(7) 446–449
1,1,1,2,4,4,4-Heptafluoro-2-
trifluoromethoxybutane
C5
H2
F10
O 322.73(0.09) 447(1) 2.15(0.06) 465(5) 110
1,1,1,2,2,3,3-Heptafluoro-3-(trifluoromethoxy)
propane
C4
F10
O 280.0(0.4) 391.7(0.7) 1.89(0.05) 431(31) 450
2,2,4,4,6,8,8-Heptamethylnonane C16
H34
519(1) 692(4) 1.53(0.01) 957(27) 451
1,1,1,3,5,5,5-Heptamethyltrisiloxane C7
H22
O2
Si3
416(1) 553.4(0.6) 1.48(0.02) 828(3) 452
Heptanal C7
H14
O 426(3) 616.8(0.4) 3.2(0.2) 434(7) 242
2-Heptanamine C7
H17
N 414(4) 598(2) 2.9(0.3) 455(18) 170
Heptane C7
H16
371.53(0.07) 540.1(0.2) 2.74(0.01) 428(15) 34, 36, 62, 75, 78, 86,
131, 133–135, 157,
243, 244, 254, 286,
324, 346, 359, 394,
432, 453–463
Heptanedioic acid C7
H12
O4
615.1 842(13) 3.3(0.2) 463(15) 253
Heptanoic acid C7
H14
O2
495(2) 678(2) 3.0(0.3) 476(5) 145, 146, 464
1-Heptanol C7
H16
O 451(1) 632.4(0.6) 3.1(0.2) 430(9) 149, 254, 465
2-Heptanol C7
H16
O 432 608.4(0.6) 3.0(0.1) 442(2) 149, 465
3-Heptanol C7
H16
O 436(2) 605.4(0.3) 3.1(0.4) 451(3) 465
4-Heptanol C7
H16
O 434(2) 602.6(0.3) 3.1(0.6) 455(4) 465
2-Heptanone C7
H14
O 424.1(0.3) 611.4(0.2) 2.98(0.04) 436(4) 25, 172, 466
3-Heptanone C7
H14
O 419(2) 606.6(0.2) 3.0(0.1) 433(5) 466
4-Heptanone C7
H14
O 417(1) 602.0(0.2) 3.0(0.3) 434(5) 466
1-Heptene C7
H14
370(2) 537.3(0.3) 2.85(0.02) 409(2) 51, 52, 86, 124, 257, 467
cis-2-Heptene C7
H14
371(2) 548.5(0.6) 3.0(0.3) 410(7) 170
trans-2-Heptene C7
H14
369(2) 542.8(0.4) 3.0(0.2) 410(7) 170
trans-3-Heptene C7
H14
367(1) 538.6(0.7) 3.0(0.2) 411(7) 170
Heptylbenzene C13
H20
515(4) 708(7) 2.1(0.2) 680(16) 258
Heptyl orthosilicate C28
H60
O4
Si 778(16) 57
Hexacosane C26
H54
688(11) 816(8) 0.8(0.2) 1740(59) 358
Hexadecane C16
H34
560.0(0.7) 722.2(0.8) 1.4(0.2) 1009(53) 34, 244, 245
Hexadecanoic acid C16
H32
O2
624(6) 785(8) 1.5(0.2) 1059(23) 360
1-Hexadecanol C16
H34
O 598(2) 770(8) 1.47(0.1) 1019(17) 361
1-Hexadecene C16
H32
558(1) 718(7) 1.4(0.2) 986(33) 365
Hexaethyldisiloxane C12
H30
OSi2
525(7) 692.9(0.1) 1.7(0.7) 955(2) 34
Hexafluoroacetylacetone C5
H2
F6
O2
342(2) 485.1(0.5) 2.9(0.2) 313(49) 468
Hexafluorobenzene C6
F6
353.3(0.2) 516.4(0.5) 3.28(0.01) 337(4) 74, 198, 286, 469–473
2,2,4,4,5,5-Hexafluoro-1,3-dioxolane C3
F6
O2
251.0(0.2) 368.1(0.7) 2.72(0.04) 293(30) 116
Hexafluoroethane C2
F6
195.0(0.1) 292.9(0.2) 3.03(0.01) 223(3) 172, 474–477
1,1,1,3,3,3-Hexafluoro-2-methoxy-2-
(trifluoromethyl)propane
C5
H3
F9
O 327(1) 463(1) 2.37(0.07) 448(5) 110
1,1,1,2,3,3-Hexafluoro-3-(2,2,3,3,3-
pentafluoropropoxy)propane
C6
H3
F11
O 360.64 486.48(0.07) 1.95(0.01) 529(2) 113
1,1,1,2,3,3-Hexafluoropropane C3
H2
F6
277.65 412.40(0.06) 3.42(0.01) 270(5) 203, 447, 448, 478, 479
1,1,1,3,3,3-Hexafluoropropane C3
H2
F6
271.8(0.2) 398.07(0.06) 3.18(0.01) 262(18) 203
1,1,1,2,3,3-Hexafluoro-3-(2,2,3,3-
tetrafluoropropoxy)propane
C6
H4
F10
O 379.07 516.2(0.3) 2.2(0.2) 543(34) 113
1,1,1,2,3,3-Hexafluoro-3-(2,2,2-trifluoroethoxy)
propane
C5
H3
F9
O 345.87 475.74(0.09) 2.23(0.02) 455(2) 113
Hexamethylbenzene C12
H18
541(3) 758(2) 2.6(0.4) 581(15) 25
1,1,1,5,5,5-Hexamethyl-3,3-bis[(trimethylsilyl)
oxy]trisiloxane
C12
H36
O4
Si5
494.6(0.2) 622.6(0.2) 1.03(0.02) 1323(90) 34
Hexamethyldisiloxane C6
H18
OSi2
373.6(0.3) 518.7(0.6) 1.95(0.02) 629(15) 480
2,6,10,15,19,23-Hexamethyltetracosane C30
H62
693(6) 796(2) 0.60(0.04) 2060(70) 481
Hexanal C6
H12
O 402.8(0.4) 592(3) 3.4(0.2) 378(7) 163, 242
Hexane C6
H14
341.87(0.06) 507.5(0.1) 3.03(0.01) 366.0(0.8) 19, 29, 33, 34, 38, 52, 77,
78, 84, 86, 96, 106,
124, 131, 133, 134,
243, 244, 254, 281,
286, 318, 324–328,
401, 456, 458, 470,
482–488
1,6-Hexanediamine C6
H16
N2
470(2) 685(7) 3.6(0.5) 446(17) 140
6-66	 Critical Constants of Organic Compounds
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
1,6-Hexanedioic acid C6
H10
O4
610.5 841(13) 3.8(0.3) 449(17) 253
1,6-Hexanediol C6
H14
O2
481 741(10) 4.1(0.1) 404(13) 489
Hexanenitrile C6
H11
N 436.6(0.3) 633.8(0.2) 2.99(0.06) 378(8) 35
Hexanoic acid C6
H12
O2
478.0(0.6) 661(7) 413(15) 145, 146, 360, 464
1-Hexanol C6
H14
O 430.0(0.7) 611.0(0.4) 3.40(0.09) 381(30) 34, 149, 151, 152, 254,
255, 456
2-Hexanol C6
H14
O 413 585.9(0.5) 3.3(0.3) 406(8) 149, 255, 437
3-Hexanol C6
H14
O 416(2) 582.4(0.4) 3.3(0.1) 378(14) 64, 254, 255
2-Hexanone C6
H12
O 400.8(0.1) 586.7(0.5) 3.31(0.04) 377(4) 25, 172, 466
3-Hexanone C6
H12
O 396.6(0.3) 583.1(0.5) 3.32(0.01) 378(4) 25, 466
Hexatriacontane C36
H74
777(7) 872(9) 0.47(0.07) 2711(2) 358
1-Hexene C6
H12
336.5(0.1) 504.1(0.9) 3.20(0.03) 381(9) 86, 201, 202, 252, 257,
490
cis-2-Hexene C6
H12
342.0(0.5) 513.4(0.9) 3.34(0.06) 347(7) 170
trans-2-Hexene C6
H12
341.00(0.09) 509.0(0.7) 3.16(0.01) 353(7) 170
cis-3-Hexene C6
H12
339.5(0.5) 510(1) 3.29(0.01) 351(7) 170
trans-3-Hexene C6
H12
340.21(0.09) 507(2) 3.18(0.01) 352(7) 170
5-Hexen-2-one C6
H10
O 402.2(0.5) 593.5(0.6) 3.51(0.04) 359(10) 51
Hexyl acetate C8
H16
O2
444.2(0.7) 618(1) 2.5(0.1) 526(8) 162
Hexylamine C6
H15
N 405(1) 592.3(0.7) 3.4(0.3) 402(15) 170
Hexylbenzene C12
H18
499(2) 695(7) 2.4(0.2) 620(14) 258
Hexyl benzoate C13
H18
O2
550(26) 748(14) 2.0(0.3) 658(14) 169
Indan C9
H10
451.0(0.4) 684.8(0.4) 3.95(0.03) 385(22) 25
Isobutanal C4
H8
O 337.2(0.2) 543.6(0.6) 5.12(0.08) 283(10) 164, 165
Isobutane C4
H10
261.4(0.5) 407.84(0.07) 3.64(0.02) 256(7) 125, 132, 491, 492
Isobutene C4
H8
266.1(0.2) 418.0(0.3) 4.00(0.04) 240(3) 123, 158, 493, 494
Isobutyl acetate C6
H12
O2
390.0(0.6) 562(2) 2.97(0.06) 369(37) 166, 201, 202, 415
Isobutylbenzene C10
H14
445.8(0.4) 650(3) 3.0(0.2) 493(15) 96
Isobutyl butanoate C8
H16
O2
430(1) 611(6) 2.5(0.3) 524(9) 147
Isobutylcyclohexane C10
H20
444.5 642.1(0.6) 2.61(0.07) 550(14) 170
Isobutyl formate C5
H10
O2
371.5(0.3) 551(4) 3.9(0.4) 359(25) 415
Isobutyl isobutanoate C8
H16
O2
421(3) 602(6) 2.5(0.8) 530(9) 147
Isobutyl 3-methylbutanoate C9
H18
O2
442(3) 621(6) 2.3(0.7) 581(9) 147
Isobutyl propanoate C7
H14
O2
409(2) 586(8) 3(1) 462(9) 162, 167
Isopentane C5
H12
300.98(0.06) 460.37(0.09) 3.35(0.06) 313(17) 19, 86, 96, 127, 495
Isopentyl acetate C7
H14
O2
414.8(0.7) 586.1(0.4) 2.76(0.07) 464(9) 166
Isopentyl butanoate C9
H18
O2
458.0(0.3) 619(6) 3(1) 595(10) 147
Isopentyl nitrite C5
H11
NO2
372(3) 626(16) 5.07(0.04) 386.2(0.1) 52
Isopentyl propanoate C8
H16
O2
446(4) 611(6) 2.5(0.9) 523(9) 147
Isopropyl acetate C5
H10
O2
361.8(0.2) 531.1(0.6) 3.31(0.04) 343(4) 64, 166, 172, 411, 490
Isopropylamine C3
H9
N 304.9(0.2) 472.2(0.9) 4.55(0.07) 231(5) 75, 170
Isopropylbenzene C9
H12
425.5(0.2) 631(1) 3.2(0.1) 423(5) 79, 90, 96, 172
Isopropylcyclohexane C9
H18
427.5(0.4) 632.2(0.4) 3.1(0.2) 484(14) 170
Isopropyl formate C4
H8
O2
341(2) 534.6(0.5) 3.95(0.03) 294(11) 164, 165
1-Isopropyl-4-methylbenzene C10
H14
450(2) 654(8) 2.8(0.1) 495(16) 96, 147
(1S,2R,5S)-2-Isopropyl-5-methylcyclohexanol C10
H20
O 489(3) 694(5) 2.7(0.6) 539(14) 302
Isopropyl methyl ether C4
H10
O 303.9(0.5) 464.4(0.2) 3.76(0.01) 287(11) 25
Isoquinoline C9
H7
N 516.3(0.6) 803(8) 5.07(0.03) 380(17) 218
d-Limonene C10
H16
450.8(0.5) 653(2) 2.81(0.02) 498(11) 496
Mesityl oxide C6
H10
O 402.8(0.4) 605(2) 3.85(0.02) 353(27) 497
Methane CH4
111.6(0.2) 190.56(0.02) 4.60(0.01) 99(3) 132, 134, 498–508
Methane-d4
CD4
189.2(0.6) 98(3) 507
Methanethiol CH4
S 279.1(0.1) 469.9(0.3) 7.24(0.09) 148(4) 304
Methanol CH4
O 337.6(0.7) 512.7(0.6) 8.01(0.03) 117(4) 19, 38, 67, 80, 85, 87,
131, 148, 152, 155,
196, 405, 458, 482,
509–516
1-Methoxy-2,4-dimethylbenzene C9
H12
O 465 682(4) 3.2(0.7) 451(18) 162
2-Methoxy-1,4-dimethylbenzene C9
H12
O 467 677(1) 3.2(0.7) 451(15) 162
2-Methoxyethanol C3
H8
O2
397.4(0.1) 598(1) 5.28(0.08) 263(6) 49
2-Methoxyethyl acetate C5
H10
O3
415(3) 603(3) 3.6(0.5) 368(15) 162
Critical Constants of Organic Compounds	 6-67
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
4-Methoxy-1,1,1,2,2,3,3-heptafluorobutane C5
H5
F7
O 344.13 481.5(0.2) 2.38(0.01) 431(2) 113
1-Methoxy-1,1,2,2,3,3-hexafluoropropane C4
H4
F6
O 341.02 487.0(0.3) 2.9(0.1) 370(25) 113
2-Methoxy-2-methylbutane C6
H14
O 359.5(0.1) 536(2) 3.23(0.09) 372(19) 172, 410, 517
5-Methoxy-1,1,2,2,3,3,4,4-octafluoropentane C6
H6
F8
O 395.83 546.1(0.3) 2.40(0.07) 493(30) 113
1-Methoxy-2-propanol C4
H10
O2
393.1(0.6) 579.8(0.3) 4.11(0.04) 304(12) 49
2-Methoxypropene C4
H8
O 308.8(0.3) 478.5(0.6) 4.2(0.3) 257(13) 518
Methyl acetate C3
H6
O2
329.8(0.2) 506.7(0.4) 4.73(0.07) 227(22) 19, 411–413
Methylamine CH5
N 266.8(0.3) 430.6(0.6) 7.61(0.09) 139(1) 130, 193, 322, 323
N-Methylaniline C7
H9
N 470(1) 702(5) 5.2(0.6) 347(16) 117
2-Methylaniline C7
H9
N 473.1(0.4) 710(1) 3.6(0.1) 377(52) 519
3-Methylaniline C7
H9
N 476.4(0.5) 709(10) 4.6(0.5) 346(17) 106
4-Methylaniline C7
H9
N 474(1) 667(10) 3.3(0.7) 334(16) 106
2-Methylanisole C8
H10
O 446(2) 662(1) 3.6(0.3) 397(18) 162
3-Methylanisole C8
H10
O 450(2) 665(1) 3.6(0.3) 449(22) 162
4-Methylanisole C8
H10
O 448(2) 667(1) 3.6(0.4) 396(15) 162
α-Methylbenzenemethanol C8
H10
O 478(4) 699(5) 3.8(0.7) 399(16) 32
Methyl benzoate C8
H8
O2
472(2) 702(1) 3.8(0.1) 408(11) 517
2-Methylbutanal C5
H10
O 363(2) 531.6(0.1) 4.04(0.03) 318(10) 124
Methyl butanoate C5
H10
O2
375.0(0.1) 554.4(0.1) 3.49(0.08) 341(20) 19, 413, 416
3-Methylbutanoic acid C5
H10
O2
449.6(0.2) 629(1) 3.4(0.2) 355(10) 146
2-Methyl-1-butanol C5
H12
O 402.1(0.4) 575.4(0.5) 3.9(0.1) 342(8) 254
2-Methyl-2-butanol C5
H12
O 375.6 544(1) 3.71(0.05) 326(9) 147, 254
3-Methyl-1-butanol C5
H12
O 403.9(0.3) 579(2) 3.9(0.3) 335(7) 21, 91, 222, 254, 511,
520
3-Methyl-2-butanol C5
H12
O 386.8(0.4) 556.1(0.5) 3.9(0.4) 336(9) 254
3-Methyl-2-butanone C5
H10
O 367.3(0.2) 553.1(0.3) 3.83(0.1) 321(33) 157, 166
2-Methyl-2-butene C5
H10
311.6(0.4) 470(1) 3.4(0.1) 299(7) 521
3-Methyl-1-butene C5
H10
293.2(0.2) 452.7(0.5) 3.51(0.04) 305(8) 490
Methyl tert-butyl ether C5
H12
O 328.2(0.1) 497.0(0.6) 3.41(0.05) 335(10) 25, 440
Methylcyclohexane C7
H14
374.0(0.1) 572.3(0.2) 3.48(0.09) 368(3) 34, 74, 78, 86, 88, 171,
235, 236
Methylcyclopentane C6
H12
344.9(0.2) 532.78(0.05) 3.79(0.05) 322(2) 78, 235, 236
2-Methylcyclopentanone C6
H10
O 413(3) 631(2) 4.0(0.6) 328(17) 162
2-Methyl-N,N-dimethylaniline C9
H13
N 458(2) 668.0(0.7) 3.12(0.08) 466(15) 39, 40
Methyl dodecanoate C13
H26
O2
540(2) 712(5) 1.4(0.4) 842(9) 218
1,1’-Methylenebis[(1-methylethyl)benzene] C19
H24
592(36) 795(8) 1.6(0.1) 871(30) 394
Methyl formate C2
H4
O2
304.8(0.3) 487.16(0.1) 6.01(0.01) 172(6) 19, 412, 413
2-Methylfuran C5
H6
O 337.0(0.2) 528(3) 4.77(0.08) 252(3) 290
2-Methylheptane C8
H18
390.8(0.9) 559.6(0.1) 2.50(0.02) 487(12) 86, 346, 522
3-Methylheptane C8
H18
392.0(0.6) 563.7(0.4) 2.54(0.02) 463(12) 346
4-Methylheptane C8
H18
390.8(0.5) 561.7(0.4) 2.54(0.02) 480(14) 346
Methyl heptanoate C8
H16
O2
442.8(0.4) 628(2) 2.6(0.4) 521(8) 162
4-Methyl-3-heptanol C8
H18
O 430(2) 623.5(0.7) 2.8(0.4) 505(13) 437
5-Methyl-3-heptanol C8
H18
O 427(2) 621.2(0.3) 2.8(0.3) 493(13) 437
2-Methyl-3-heptanone C8
H16
O 431 615(1) 2.7(0.3) 487(11) 162
5-Methyl-3-heptanone C8
H16
O 432(4) 619(4) 2.7(0.7) 484(11) 162
2-Methyl-1-heptene C8
H16
392(2) 567.5(0.9) 2.6(0.2) 466(10) 170
2-Methyl-2-heptene C8
H16
395(2) 569(1) 2.6(0.4) 465(11) 170
2-Methylhexane C7
H16
363.1(0.8) 530.4(0.1) 2.73(0.03) 420(15) 86, 346, 349, 522
3-Methylhexane C7
H16
365.0(0.1) 535.4(0.5) 2.82(0.06) 405(19) 346, 349
2-Methyl-3-hexanone C7
H14
O 407(3) 593(1) 2.9(0.4) 428(13) 162
5-Methyl-2-hexanone C7
H14
O 412(2) 604(1) 2.9(0.3) 434(13) 162
2-Methyl-1-hexene C7
H14
365(2) 542(1) 2.9(0.3) 407(8) 170
5-Methyl-1-hexene C7
H14
358(1) 528.7(0.4) 2.9(0.2) 410(9) 170
N-Methylhexylamine C7
H17
N 418(8) 592(1) 2.8(0.8) 458(20) 170
Methyl isobutanoate C5
H10
O2
365(1) 540.7(0.5) 3.43(0.01) 341(42) 19, 413
Methyl methacrylate C5
H8
O2
373.8(0.2) 540.3(0.6) 2.97(0.06) 320(6) 51
1-Methylnaphthalene C11
H10
517.5(0.9) 771(5) 3.56(0.07) 479(22) 86, 218, 523
2-Methylnaphthalene C11
H10
514.2(0.3) 761(3) 3.37(0.06) 464(20) 218
2-Methyloctane C9
H20
416(1) 582.8(0.2) 2.30(0.02) 547(17) 345, 522
Methyloxirane C3
H6
O 308 488.11(0.08) 5.44(0.02) 197(42) 290, 524
6-68	 Critical Constants of Organic Compounds
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
Methyl pentafluoroethyl ether C3
H3
F5
O 278.8(0.9) 406.81(0.05) 2.89(0.01) 301(5) 176, 448, 525
2-Methylpentane C6
H14
333.36(0.09) 497.9(0.2) 3.03(0.01) 371(2) 86, 127, 252, 325–328,
487, 522
3-Methylpentane C6
H14
336.4(0.5) 504.6(0.2) 3.12(0.01) 368.7(0.3) 252, 324–328, 526
Methyl pentanoate C6
H12
O2
400.51(0.06) 588.9(0.3) 3.20(0.05) 398(6) 164, 165
2-Methyl-1-pentanol C6
H14
O 430(6) 604.4(0.5) 3.4(0.2) 410(8) 254
2-Methyl-2-pentanol C6
H14
O 394(1) 559.5(0.7) 3.6(0.4) 410(11) 437
2-Methyl-3-pentanol C6
H14
O 401.0(0.2) 576(1) 3.5(0.1) 380(9) 254
3-Methyl-3-pentanol C6
H14
O 402(4) 575.6(0.6) 3.5(0.2) 376(10) 254
4-Methyl-1-pentanol C6
H14
O 424(2) 603.5(0.7) 3.4(0.4) 406(7) 437
4-Methyl-2-pentanol C6
H14
O 405.1(0.5) 574.4(0.5) 4(2) 389(9) 437
4-Methyl-2-pentanone C6
H12
O 388.8(0.2) 575.4(1) 3.4(0.1) 378(12) 166, 527
2-Methyl-2-pentene C6
H12
340.4(0.5) 509.3(0.5) 3.26(0.01) 348(7) 170
4-Methyl-1-pentene C6
H12
327(2) 493.1(0.5) 3.18(0.07) 348(77) 170, 497
4-Methyl-cis-2-pentene C6
H12
329.5(0.1) 496.3(0.7) 3.24(0.01) 350(7) 170
Methyl pentyl ether C6
H14
O 372(3) 546.5(0.2) 3.04(0.1) 395(14) 173, 174
2-Methyl-1,3-propanediol C4
H10
O2
494(4) 708(2) 5.4(0.4) 300(12) 55
Methyl propanoate C4
H8
O2
351.8(0.2) 530.57(0.1) 4.0(0.2) 280(98) 19, 412, 413, 415
2-Methylpropanoic acid C4
H8
O2
427.5(0.2) 605(2) 3.7(0.3) 296(10) 146
2-Methyl-1-propanol C4
H10
O 380.99(0.07) 548(2) 4.30(0.04) 274(17) 25, 91, 148, 153, 155
2-Methyl-2-propanol C4
H10
O 355.4(0.1) 506.2(0.1) 3.98(0.07) 283(4) 153
Methyl propyl ether C4
H10
O 312(1) 476.2(0.2) 3.80(0.01) 281(7) 25
2-Methylpyridine C6
H7
N 402.5(0.2) 622(1) 4.62(0.04) 306(119) 75, 528
3-Methylpyridine C6
H7
N 417.2(0.1) 644.8(0.6) 4.63(0.03) 302(30) 90, 528
4-Methylpyridine C6
H7
N 418.4(0.1) 645.8(0.5) 4.68(0.04) 316(67) 75, 90
N-Methyl-2-pyrrolidinone C5
H9
NO 477.3(0.3) 721.7(0.4) 4.5(0.4) 330(12) 144, 242
2-Methylquinoline C10
H9
N 520.5(0.4) 778(2) 3.91(0.02) 447(49) 530
8-Methylquinoline C10
H9
N 520.5(0.7) 787(2) 4.22(0.02) 426(124) 530
Methyl salicylate C8
H8
O3
495.8(0.5) 709(30) 4.4(0.7) 436(17) 302
2-Methyltetrahydrofuran C5
H10
O 353(1) 537(2) 3.74(0.06) 292(4) 290
(Methylthio)benzene C7
H8
S 467.4(0.2) 706(4) 4.1(0.1) 374(13) 99
Methyl trifluoromethyl ether C2
H3
F3
O 247.9(0.7) 377.92(0.06) 3.64(0.03) 219(2) 447, 525
Methyltris(trimethylsiloxy)silane C10
H30
O3
Si4
464.3(0.2) 597.4(0.2) 1.23(0.02) 1089(74) 34
4-Morpholinecarboxaldehyde C5
H9
NO2
511(1) 779(4) 5.0(0.4) 326(14) 54
Naphthalene C10
H8
491.1(0.1) 748.3(0.4) 4.06(0.04) 408(21) 79, 82, 86, 241, 251, 355,
451, 531
Neopentane C5
H12
282.65(0.06) 433.71(0.01) 3.20(0.01) 311.6(0.7) 532
Nitromethane CH3
NO2
374.3(0.1) 588(3) 6.0(0.2) 175(2) 533, 534
Nonadecane C19
H40
603(3) 756(5) 1.16(0.07) 1216(43) 358, 359
1-Nonadecene C19
H38
604(17) 755(8) 1.2(0.2) 1196(36) 365
1,1,1,2,2,3,3,4,4-Nonafluorohexan-5-one C6
H3
F9
O 360.47 498.97(0.08) 2.20(0.02) 504(2) 308
Nonanal C9
H18
O 468(3) 658(2) 2.7(0.1) 546(10) 242
Nonane C9
H20
424.0(0.2) 594.2(0.5) 2.29(0.05) 547(23) 34, 36, 78, 86, 131,
243–245, 247, 249,
251, 454, 456, 535, 536
1,9-Nonanediamine C9
H22
N2
531.8 726(7) 2.6(0.3) 600(23) 140
Nonanedioic acid C9
H16
O4
630.2 844(13) 2.7(0.2) 586(17) 253
Nonanoic acid C9
H18
O2
529(1) 712(3) 2.3(0.8) 592(16) 146
1-Nonanol C9
H20
O 486.8(0.4) 670.6(0.5) 2.54(0.07) 555(75) 149, 152, 254, 255
2-Nonanol C9
H20
O 466.7 649(1) 2.53(0.1) 575(11) 149, 255
3-Nonanol C9
H20
O 468 648.0(0.3) 2.5(0.3) 577(12) 255
4-Nonanol C9
H20
O 465.7 645.1(0.3) 2.5(0.3) 577(12) 255
2-Nonanone C9
H18
O 467(1) 652.1(0.7) 2.5(0.1) 560(8) 49, 466
3-Nonanone C9
H18
O 460(4) 648(4) 2.4(0.6) 560(7) 466
4-Nonanone C9
H18
O 461(4) 643.7(0.3) 2.4(0.3) 560(7) 466
5-Nonanone C9
H18
O 461.5(0.3) 641.4(0.3) 2.35(0.02) 560(7) 466
1-Nonene C9
H18
420.0(0.6) 594(1) 2.38(0.01) 529(2) 257
Octacosane C28
H58
705(6) 824(8) 0.8(0.1) 1916(65) 358
Octadecane C18
H38
589(2) 748(1) 1.3(0.1) 1167(41) 244
1-Octadecanol C18
H38
O 624(2) 790(8) 1.28(0.1) 1157(18) 361
1-Octadecene C18
H36
588.7(1) 748(8) 1.3(0.1) 1119(34) 365
Critical Constants of Organic Compounds	 6-69
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
1,1,1,2,2,3,3,4-Octafluorobutane C4
H2
F8
300.62(0.02) 432.0(0.1) 2.80(0.02) 360(22) 537
1,2,2,3,3,4,4,5-Octafluoro-1-pentanol C5
H4
F8
O 413.1(0.3) 571(1) 2.9(0.1) 440(24) 362
Octafluorotetrahydrofuran C4
F8
O 272.3(0.5) 399.6(0.7) 2.68(0.09) 350(30) 450
Octamethylcyclotetrasiloxane C8
H24
O4
Si4
448.5(0.9) 585.8(0.9) 1.33(0.01) 1006(67) 114, 538
Octamethyltrisiloxane C8
H24
O2
Si3
425.6(0.8) 564.1(0.2) 1.42(0.01) 882(16) 539
Octanal C8
H16
O 447(3) 639.3(0.3) 3.0(0.3) 489(7) 163, 242
Octane C8
H18
398.8(0.1) 568.7(0.1) 2.48(0.01) 490(22) 11, 19, 33, 34, 36, 78, 83,
86, 91, 96, 131, 133,
134, 243–245, 247,
249, 318, 319, 324,
346, 465, 469, 535,
540, 541
1,8-Octanediamine C8
H20
N2
498.7 712(7) 2.8(0.3) 547(20) 140
Octanedioic acid C8
H14
O4
618.6 843(13) 3.0(0.2) 520(16) 253
Octanenitrile C8
H15
N 475(3) 674.4(0.4) 2.85(0.03) 494(10) 35
Octanoic acid C8
H16
O2
513(1) 694(1) 2.9(0.3) 522(19) 145, 146, 360, 464
1-Octanol C8
H18
O 467.8(0.8) 651(2) 2.80(0.07) 490(47) 25, 149, 152, 254, 255
2-Octanol C8
H18
O 452.5 629.5(0.9) 2.75(0.04) 519(10) 149, 254, 255
3-Octanol C8
H18
O 457(6) 628.4(0.3) 2.8(0.4) 515(10) 255
4-Octanol C8
H18
O 449.5 625.1(0.3) 2.8(0.3) 516(10) 255
2-Octanone C8
H16
O 446(3) 632.7(0.2) 2.7(0.5) 497(6) 466
3-Octanone C8
H16
O 439(4) 627.7(0.2) 2.7(0.3) 497(6) 466
4-Octanone C8
H16
O 439(3) 623.8(0.2) 2.7(0.3) 497(6) 466
1-Octene C8
H16
398.0(0.5) 566.58(0.05) 2.68(0.02) 464(2) 86, 257
trans-2-Octene C8
H16
395.5(0.5) 569.8(0.4) 2.58(0.09) 471(9) 170
trans-4-Octene C8
H16
394.4(0.2) 566(1) 2.55(0.06) 472(9) 170
Octylamine C8
H19
N 451.8(0.2) 641(1) 2.82(0.03) 494(41) 542
Octylbenzene C14
H22
536(2) 725(7) 2.0(0.2) 746(17) 258
Octyl orthosilicate C32
H68
O4
Si 812(16) 57
Oxazole C3
H3
NO 342.6(0.2) 551(4) 6.8(0.2) 185(23) 54
Oxirane C2
H4
O 283.5(0.1) 469(1) 7.2(0.2) 138(4) 543, 544
Paraldehyde C6
H12
O3
397(2) 563(10) 4(3) 410(15) 12
Pentacene C22
H14
1115(47) 806(23) 545
1H-Pentadecafluoroheptane C7
HF15
368(2) 495.8(0.7) 1.7(0.5) 644(38) 546
Pentadecane C15
H32
543.8(0.4) 707(2) 1.54(0.09) 938(36) 243, 244, 245, 247, 249,
363, 547
Pentadecanoic acid C15
H30
O2
612(4) 777(8) 1.6(0.2) 1002(22) 360
1-Pentadecanol C15
H32
O 591(2) 757(8) 1.6(0.2) 961(16) 361
1-Pentadecene C15
H30
541.5(0.4) 705(7) 1.56(0.05) 933(30) 365
Pentafluorobenzene C6
HF5
358(3) 530.93(0.03) 3.53(0.01) 322(22) 472, 548
3,3,4,4,4-Pentafluoro-2-butanone C4
H3
F5
O 314.36(0.04) 453(1) 2.90(0.06) 333(4) 110
Pentafluoroethane C2
HF5
224.65 339.2(0.2) 3.63(0.01) 210(3) 180, 309, 312, 315, 447,
448, 549–554
1,1,1,2,2-Pentafluoropentan-3-one C5
H5
F5
O 335.24 475.5(0.1) 2.64(0.01) 356(1) 308
1,1,1,2,2-Pentafluoropropane C3
H3
F5
255.1(0.3) 380.1(0.4) 3.14(0.02) 273(3) 555
1,1,1,3,3-Pentafluoropropane C3
H3
F5
288.5 427.20(0.07) 3.66(0.02) 262(14) 203
1,1,2,2,3-Pentafluoropropane C3
H3
F5
298.2 447.57(0.06) 3.96(0.02) 258(13) 203
1,1,1,2,2-Pentafluoro-3-(1,1,2,2-
tetrafluoroethoxy)propane
C5
H3
F9
O 343.4 473.0(0.1) 2.24(0.01) 457(2) 113
Pentafluoro(trifluoromethoxy)ethane C3
F8
O 249.5(0.3) 356.8(0.1) 2.4(0.5) 319(5) 442
Pentafluoro(trifluoromethyl)sulfur CF8
S 252.4(0.2) 381.2(0.1) 3.4(0.1) 284(4) 442
Pentanal C5
H10
O 376(2) 567(3) 3.1(0.3) 313(11) 104, 124
Pentane C5
H12
309.21(0.07) 469.7(0.1) 3.37(0.01) 310(1) 19, 34, 36, 52, 64, 77,
84–86, 127, 131, 133,
134, 201, 202, 243,
244, 254, 286, 324,
359, 394, 456, 490,
556–562
Pentanedioic acid C5
H8
O4
546(10) 840(13) 4.3(0.5) 343(13) 253
Pentanenitrile C5
H9
N 413(1) 610.3(0.2) 3.58(0.05) 320(8) 35
Pentanoic acid C5
H10
O2
459.2(0.3) 639(2) 3.6(0.1) 347(15) 11, 41, 145, 146, 464
1-Pentanol C5
H12
O 410.8(0.4) 587.9(0.4) 3.9(0.3) 331(9) 25, 34, 149, 329, 456,
465, 563
6-70	 Critical Constants of Organic Compounds
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
2-Pentanol C5
H12
O 392.2(0.5) 560.4(0.2) 4.2(0.4) 340(3) 149, 254, 465
3-Pentanol C5
H12
O 396(2) 559.6(0.3) 4.9(0.9) 325(2) 465
2-Pentanone C5
H10
O 375.3(0.1) 561.0(0.2) 3.70(0.06) 324(4) 25, 172
3-Pentanone C5
H10
O 375.0(0.1) 561.4(0.2) 3.73(0.07) 319(11) 25
1-Pentene C5
H10
310.0(0.2) 464.74(0.04) 3.55(0.02) 301.0(0.1) 86, 470, 559
cis-2-Pentene C5
H10
303.1(0.3) 474.9(0.4) 3.69(0.02) 301(7) 564
Pentyl acetate C7
H14
O2
422.5(0.3) 600(2) 2.79(0.03) 466(123) 141, 162, 166
Pentylbenzene C11
H16
476(3) 675(7) 2.6(0.3) 559(12) 258
Pentyl benzoate C12
H16
O2
533(3) 736(14) 2.2(0.2) 661(14) 169
Pentyl formate C6
H12
O2
399(3) 576(4) 3.5(0.8) 453(35) 415
Perfluoroacetone C3
F6
O 245.7(0.4) 357.2(0.1) 2.85(0.01) 329(7) 197, 470
Perfluorobutane C4
F10
271.0(0.8) 386.3(0.2) 2.33(0.02) 380(18) 565, 566
Perfluorocyclobutane C4
F8
267.3 388.4(0.1) 2.78(0.01) 316(8) 265, 470, 567, 568
Perfluorocyclohexane C6
F12
325.95 s 457.1(0.5) 2.24(0.03) 424(32) 569
Perfluorocyclohexene C6
F10
324.8(0.1) 461.7(0.7) 2.6(0.1) 434(28) 546
Perfluorodecane C10
F22
408(3) 542.4(0.4) 1.45(0.03) 892(7) 240, 570
Perfluorodimethoxymethane C3
F8
O2
263.1(0.7) 372.4(0.2) 2.34(0.01) 370(30) 116, 571
Perfluoro-2,3-dimethylbutane C6
F14
332.9(0.3) 463.0(0.1) 1.95(0.03) 523(18) 240, 572
Perfluoroethyl ethyl ether C4
H5
F5
O 301(3) 431.23(0.08) 2.53(0.01) 366(3) 176
Perfluoroethyl 2,2,2-trifluoroethyl ether C4
H2
F8
O 301.04 421.68(0.08) 2.33(0.01) 409(3) 176
Perfluoroheptane C7
F16
355.6(0.2) 477(3) 1.63(0.01) 603(14) 232, 566, 570,
573–576
Perfluoro-1-heptene C7
F14
354(4) 478.2(0.7) 1.7(0.3) 555(34) 546
1H-Perfluorohexane C6
HF13
345(4) 471.8(0.7) 2.0(0.3) 504(32) 546
Perfluorohexane C6
F14
330.3(0.2) 451(3) 1.88(0.02) 552(77) 198, 470, 546, 570, 572,
573, 577
Perfluoro-1-hexene C6
F12
330.2 454.3(0.7) 1.9(0.7) 462(31) 546
Perfluoroisobutane C4
F10
273 395.4(0.7) 396(22) 578
Perfluoroisopentane C5
F12
303.26(0.03) 423(19) 2.12(0.02) 465(8) 240
Perfluoroisopropyl methyl ether C4
H3
F7
O 302(1) 433.30(0.08) 2.55(0.01) 369(3) 176
Perfluoromethylcyclohexane C7
F14
349.4(0.2) 486.5(1) 2.02(0.01) 561(4) 325, 326, 327, 566, 569
Perfluoromethylcyclopentane C6
F12
321.58(0.01) 451.43(0.04) 2.17(0.01) 419(37) 579
Perfluoro-2-methylpentane C6
F14
330.8(0.3) 454.6(0.2) 1.87(0.02) 585(10) 572, 580
Perfluoro-3-methylpentane C6
F14
331(9) 450(1) 1.69(0.01) 511(36) 572
Perfluoronaphthalene C10
F8
473(8) 673(1) 2.9(0.6) 464(29) 546
Perfluorononane C9
F20
390(3) 524.0(0.1) 1.56(0.04) 846(48) 570
Perfluorooctane C8
F18
378(2) 502.3(0.1) 1.66(0.02) 738(17) 34, 240, 570, 573
Perfluorooxetane C3
F6
O 244.5(0.6) 361.8(0.5) 3.10(0.02) 274(24) 116, 571
1H-Perfluoropentane C5
HF11
319(2) 443.9(0.7) 2.2(0.3) 413(28) 546
Perfluoropentane C5
F12
302.3(0.2) 421.8(0.1) 2.04(0.02) 463(7) 570, 573
Perfluoropropane C3
F8
236.3(0.3) 345.03(0.08) 2.67(0.01) 301(12) 187, 305, 470, 581
Perfluoropropyl methyl ether C4
H3
F7
O 307(1) 437.7(0.1) 2.48(0.01) 382(3) 176
Perfluorotoluene C7
F8
377.8(0.3) 534.4(0.2) 2.70(0.02) 423(26) 25
Perfluorotributylamine C12
F27
N 451(2) 566(4) 1.24(0.09) 1196(66) 582
Perfluorovaleric acid C5
HF9
O2
415.3(0.3) 545.5(0.2) 2.10(0.05) 496(29) 583
Phenol C6
H6
O 455.0(0.1) 694.3(0.1) 5.5(0.2) 283(10) 218, 584
Phenyl acetate C8
H8
O2
468(1) 686(2) 3.60(0.06) 407(12) 55
4-Phenyl-1-butanol C10
H14
O 537(3) 746(14) 3.1(0.2) 493(19) 584
Phenyl isocyanate C7
H5
NO 439.4(0.4) 657(10) 3.6(0.1) 342(15) 54
3-Phenyl-1-propanol C9
H12
O 514(4) 732(14) 3.4(0.5) 450(14) 584
(1S)-(-)-α-Pinene C10
H16
429.1(0.4) 644(2) 3.4(0.2) 472(10) 496
Piperazine C4
H10
N2
421.78(0.05) 660(5) 5.4(0.4) 283(16) 331, 489
Piperidine C5
H11
N 379.34(0.09) 594.14(0.02) 4.7(0.1) 294(10) 39, 218
Propanal C3
H6
O 321.1(0.2) 503.7(0.8) 5.04(0.03) 218(9) 104, 124, 163, 242
Propane C3
H8
231.04(0.09) 369.9(0.1) 4.25(0.01) 199(6) 29, 125, 127, 131–134,
252, 322, 323, 336,
371, 387, 470, 486,
509, 540, 585–596
1,3-Propanediamine C3
H10
N2
412.3(0.7) 632(7) 5.7(0.6) 257(13) 140
1,2-Propanediol C3
H8
O2
460.4(0.2) 676(1) 5.9(0.2) 237(10) 32
1,3-Propanediol C3
H8
O2
487.8(0.3) 718(2) 6.7(0.2) 255(12) 55
Critical Constants of Organic Compounds	 6-71
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
Propanenitrile C3
H5
N 370.4(0.4) 561.3(0.2) 4.26(0.07) 211(7) 35
1-Propanethiol C3
H8
S 340.8(0.1) 536.6(0.6) 4.7(0.1) 286(11) 143, 144
Propanoic acid C3
H6
O2
414.6(0.2) 603(3) 4.5(0.7) 232(12) 39, 145, 146, 493, 597,
598
1-Propanol C3
H8
O 370.19(0.09) 536.8(0.2) 5.1(0.1) 220(22) 19, 34, 80, 148–150,
152, 153, 599, 600
2-Propanol C3
H8
O 355.36(0.09) 508.3(0.2) 4.7(0.1) 226(1) 25, 91, 148, 149, 153,
324, 440, 520, 601, 602
Propene C3
H6
225.5(0.1) 364.9(0.5) 4.59(0.02) 184(11) 67, 123, 172, 181, 427,
603–610
2-Propoxyethanol C5
H12
O2
425(3) 614.7(0.7) 3.65(0.09) 364(13) 11, 41
1-Propoxy-2-propanol C6
H14
O2
423.3(0.7) 605(1) 3.1(0.1) 417(16) 32
Propyl acetate C5
H10
O2
374.1(0.2) 549.69(0.08) 3.37(0.07) 346(24) 19, 411, 413, 415
Propylamine C3
H9
N 320.36(0.08) 499.2(0.4) 4.77(0.06) 230(12) 170, 193
Propylbenzene C9
H12
432.3(0.5) 638.3(0.1) 3.20(0.02) 441(6) 79, 86, 88
Propyl benzoate C10
H12
O2
504(2) 710(14) 2.6(0.3) 530(10) 169
Propyl butanoate C7
H14
O2
417(2) 593(1) 2.72(0.06) 463(10) 162, 166
Propylcyclohexane C9
H18
429.8(0.3) 630.8(0.9) 2.87(0.04) 489(13) 170, 171
Propylene carbonate C4
H6
O3
514.8(0.7) 763(2) 4.1(0.2) 256.5(0.1) 55
1,2-Propylene glycol 1-tert-butyl ether C7
H16
O2
425.2 601(4) 2.7(0.1) 468(15) 99
1,2-Propylene glycol monomethyl ether acetate C6
H12
O3
419.1(0.4) 598(1) 3.1(0.2) 432(16) 41, 144
Propyl formate C4
H8
O2
353.8(0.2) 538.1(0.1) 4.07(0.02) 281(31) 19, 412, 413, 415
Propyl isobutanoate C7
H14
O2
407(4) 582(11) 3(1) 463(9) 162, 167
Propyl 3-methylbutanoate C8
H16
O2
428(3) 609(6) 2.5(0.8) 523(9) 147
Propyl propanoate C6
H12
O2
395.3(0.1) 569(3) 3.1(0.1) 403(6) 162, 166
Propyne C3
H4
250 402(2) 5.63(0.06) 160(10) 605, 611
Pyrazine C4
H4
N2
389.4(0.1) 627(1) 6.49(0.03) 225(16) 612
Pyridine C5
H5
N 388.3(0.1) 619(2) 5.63(0.07) 248(12) 16, 17, 60, 90, 246, 290,
520, 613
Pyrrole C4
H5
N 402.89(0.04) 639.7(0.2) 8.0(0.2) 222(15) 241
Pyrrolidine C4
H9
N 359.8(0.1) 568.6(0.2) 5.69(0.08) 259(3) 241, 290
Quinoline C9
H7
N 510.2(0.5) 782(3) 4.75(0.1) 382(17) 218
Resorcinol C6
H6
O2
553(2) 836(10) 6.3(0.3) 292(10) 489
Stearic acid C18
H36
O2
644(3) 803(8) 1.3(0.2) 1251(27) 360
Styrene C8
H8
418.4(0.6) 635(2) 3.9(0.2) 357(15) 481
Succinic acid C4
H6
O4
507(3) 851(20) 308(21) 253
m-Terphenyl C18
H14
648(1) 883(7) 2.2(0.2) 747(37) 108, 358
o-Terphenyl C18
H14
610(5) 857(6) 2.9(0.1) 737(37) 108
p-Terphenyl C18
H14
649 913(22) 2.5(0.5) 713(37) 108, 614
Tetrabutyl silicate C16
H36
O4
Si 682(14) 57
Tetrachloromethane CCl4
349.8(0.2) 556.5(0.3) 4.57(0.07) 276(9) 19, 27, 469, 615–619
Tetracosane C24
H50
664(5) 800(5) 0.9(0.1) 1585(55) 358, 359
Tetradecamethylcycloheptasiloxane C14
H42
O7
Si7
548.4(0.2) 683.2(0.2) 0.99(0.02) 1634(110) 34
Tetradecane C14
H30
526.6(0.4) 693(1) 1.56(0.08) 870(49) 34, 244
Tetradecanedioic acid C14
H26
O4
639(10) 1.9(0.2) 253
Tetradecanoic acid C14
H28
O2
599(1) 763(8) 1.6(0.2) 921(20) 360
1-Tetradecanol C14
H30
O 569.0(0.4) 743(7) 1.70(0.04) 887(15) 361
2-Tetradecanone C14
H28
O 562(6) 728(9) 1.6(0.5) 896(26) 256
3-Tetradecanone C14
H28
O 552(7) 727(6) 1.6(0.5) 896(26) 256
4-Tetradecanone C14
H28
O 552(7) 725(6) 1.6(0.5) 900(27) 256
7-Tetradecanone C14
H28
O 552(8) 723(8) 1.6(0.6) 904(27) 256
1-Tetradecene C14
H28
524.2(0.4) 691(7) 1.58(0.07) 851(24) 365
Tetradecyl orthosilicate C40
H84
O4
Si 849(16) 57
Tetraethoxysilane C8
H20
O4
Si 441(1) 587(12) 2.0(0.4) 701.3(0.2) 57
Tetraethylene glycol C8
H18
O5
588(7) 800(30) 2.8(0.7) 608(31) 283
Tetraethylsilane C8
H20
Si 426.5(0.7) 606(2) 2.297(0.01) 596.4(0.2) 620
1,2,3,4-Tetrafluorobenzene C6
H2
F4
367.4(0.8) 550.8(0.2) 3.791(0.01) 312(22) 25
1,2,3,5-Tetrafluorobenzene C6
H2
F4
357.4(0.8) 535.2(0.2) 3.75(0.01) 311(22) 25
1,2,4,5-Tetrafluorobenzene C6
H2
F4
363.3(0.3) 543.3(0.2) 3.80(0.01) 309(22) 25
1,1,2,2-Tetrafluoro-2-(2,2-difluoromethoxy)
ethane
C4
H4
F6
O 352.13 501.08(0.08) 3.09(0.02) 356(1) 113
6-72	 Critical Constants of Organic Compounds
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
1,1,1,2-Tetrafluoroethane C2
H2
F4
247.0(0.1) 374.2(0.2) 4.06(0.01) 200(2) 113, 182, 183, 188,
278–280, 305, 313,
315, 447, 448, 478,
621–631
1,1,2,2-Tetrafluoroethane C2
H2
F4
253(1) 391.75(0.08) 4.61(0.01) 192(1) 178, 632
Tetrafluoroethene C2
F4
197(1) 307(1) 3.94(0.05) 183(3) 633, 634
1,2,2,2-Tetrafluoroethyl difluoromethyl ether C3
H2
F6
O 296(2) 428.95(0.08) 3.05(0.01) 315(2) 176
1,1,2,2-Tetrafluoroethyl 1,1,1-trifluoroethyl ether C4
H3
F7
O 329.37 463.89(0.07) 2.71(0.01) 373(1) 113
Tetrafluoromethane CF4
145.2(0.1) 227.54(0.03) 3.73(0.03) 140(1) 506, 635
1,1,2,2-Tetrafluoro-3-methoxypropane C4
H6
F4
O 347.4(0.1) 505.4(0.1) 3.28(0.01) 331(1) 113
1,2,2,3-Tetrafluoro-1-propanol C3
H4
F4
O 386.4(0.4) 554(2) 3.3(0.2) 280(15) 362
1,1,2,2-Tetrafluoro-3-(1,1,2,2-tetrafluoroethoxy)
propane
C5
H4
F8
O 366.32 510.07(0.08) 2.58(0.01) 440(2) 113
1,1,1,2-Tetrafluoro-2-(trifluoromethoxy)ethane C3
HF7
O 264(2) 377.26(0.06) 2.62(0.01) 321(2) 525
3,4,4,4-Tetrafluoro-3-(trifluoromethyl)-2-
butanone
C5
H3
F7
O 328.76(0.05) 468(1) 2.50(0.06) 409(5) 110
4,4,5,5-Tetrafluoro-2-(trifluoromethyl)-1,3-
dioxolane
C4
HF7
O2
304.6(0.1) 435(1) 2.62(0.07) 376(4) 110
Tetrahexoxysilane C24
H52
O4
Si 757(16) 57
Tetrahydrofuran C4
H8
O 339.1(0.1) 540(1) 5.29(0.06) 223(2) 23, 241, 290
1,2,3,4-Tetrahydronaphthalene C10
H12
480.3(0.3) 720(1) 3.6(0.1) 431(40) 144, 242, 636
Tetrahydropyran C5
H10
O 361.1(0.4) 572.0(0.3) 4.8(0.2) 278(18) 75
Tetrahydrothiophene C4
H8
S 394.2(0.2) 632.0(0.2) 5.4(0.6) 276(19) 143, 241
1,2,4,5-Tetraisopropylbenzene C18
H30
532 703(1) 1.65(0.02) 983(83) 317
Tetramethoxysilane C4
H12
O4
Si 393.2(0.7) 558(12) 2.8(0.6) 464(22) 57
1,2,4,5-Tetramethylbenzene C10
H14
470(1) 676(2) 2.9(0.3) 489(11) 39
2,2,3,3-Tetramethylhexane C10
H22
433(2) 623.0(0.5) 2.51(0.06) 574(14) 536
2,2,5,5-Tetramethylhexane C10
H22
410(2) 581.4(0.5) 2.19(0.01) 600(14) 536
2,2,3,3-Tetramethylpentane C9
H20
413.3(0.4) 607.5(0.5) 2.74(0.03) 514(15) 536
2,2,3,4-Tetramethylpentane C9
H20
406.1(0.8) 592.6(0.5) 2.60(0.03) 517(17) 536
2,2,4,4-Tetramethylpentane C9
H20
395(1) 574.6(0.5) 2.49(0.01) 532(16) 536
2,3,3,4-Tetramethylpentane C9
H20
414.6(0.7) 607.5(0.5) 2.72(0.04) 517(17) 536
Tetramethylsilane C4
H12
Si 299.8(0.5) 449(2) 2.82(0.01) 362(7) 637–639
Tetramethylstannane C4
H12
Sn 350(1) 521.77(0.02) 2.98(0.01) 109(109) 640, 641
Tetranonoxysilane C36
H76
O4
Si 830(16) 57
Tetrapropyl silicate C12
H28
O4
Si 649(12) 57
Thiacyclohexane C5
H10
S 414.88(0.04) 684(44) 6.50(0.07) 284(11) 104
Thiobis(trifluoromethane) C2
F6
S 251.3(0.3) 376.8(0.1) 3.2(0.5) 216(19) 442
Thiophene C4
H4
S 357.2(0.1) 579.4(0.2) 5.7(0.2) 230(3) 241, 290
Thymol C10
H14
O 506(3) 698(10) 3(2) 528(21) 302
Toluene C7
H8
383.75(0.07) 591.9(0.2) 4.13(0.02) 314(7) 34, 63, 68, 74, 78, 79, 84,
86, 88, 90, 96, 163,
172, 258, 481, 636,
642–646
Triacontane C30
H62
724(7) 843(8) 0.6(0.1) 2055(69) 358
Tribromomethane CHBr3
422.3(0.5) 682(1) 5.8(0.2) 261(12) 647
Trichloroacetyl chloride C2
Cl4
O 391.3(0.3) 604(2) 4.21(0.03) 331(54) 410
Trichloroethylsilane C2
H5
Cl3
Si 371.8(0.7) 559.9(0.6) 3.34(0.04) 403(5) 266
Trichlorofluoromethane CCl3
F 296.8(0.6) 471.1(0.2) 4.40(0.03) 248.0(0.9) 33, 34, 191, 271, 571
Trichloromethane CHCl3
334.3(0.1) 536.0(0.4) 5.5(0.2) 237(7) 18, 27, 28, 117
Trichloromethylsilane CH3
Cl3
Si 339(2) 517.7(0.3) 3.52(0.03) 329(9) 264, 648
1,3,5-Trichloro-2,4,6-trifluorobenzene C6
Cl3
F3
472(27) 684.7(0.4) 3.3(0.1) 443(27) 25
1,1,2-Trichloro-1,2,2-trifluoroethane C2
Cl3
F3
320.8(0.2) 487.4(0.2) 3.40(0.02) 325(1) 191, 265, 271, 649
Tricosane C23
H48
654(9) 790(8) 0.9(0.1) 1527(53) 359
Tridecane C13
H28
508.5(0.4) 676(1) 1.68(0.04) 824(30) 34, 244, 249
1-Tridecanol C13
H28
O 560(8) 732(7) 1.8(0.2) 828(14) 361
2-Tridecanone C13
H26
O 541(1) 717(6) 1.8(0.2) 820(24) 256
3-Tridecanone C13
H26
O 539(7) 716(5) 1.7(0.5) 823(24) 256
4-Tridecanone C13
H26
O 539(7) 712(6) 1.7(0.5) 823(24) 256
5-Tridecanone C13
H26
O 539(8) 710(8) 1.7(0.7) 826(17) 256
6-Tridecanone C13
H26
O 539(7) 709(5) 1.7(0.5) 826(24) 256
7-Tridecanone C13
H26
O 539(9) 708(5) 1.7(0.5) 830(24) 256
Critical Constants of Organic Compounds	 6-73
Name Mol. Form. Tb
/K Tc
/K Pc
/MPa Vc
/cm3
mol–1
Ref.
1-Tridecene C13
H26
506.0(0.7) 673(7) 1.74(0.05) 770(17) 365
Tridecylbenzene C19
H32
613(4) 790(8) 1.5(0.1) 1079(43) 258
Triethylamine C6
H15
N 361.9(0.2) 535.6(0.3) 3.1(0.3) 392(25) 117, 286
1,3,5-Triethylbenzene C12
H18
489.0(0.9) 679(2) 2.32(0.01) 624(60) 332
Triethylene glycol C6
H14
O4
561.8(0.2) 775(30) 3.3(0.2) 454(25) 283
Trifluoroacetonitrile C2
F3
N 204.3(0.8) 311.1(0.4) 3.61(0.04) 202(4) 470
1,2,3-Trifluorobenzene C6
H3
F3
368 560.3(0.4) 4.1(0.4) 296(20) 119
1,2,4-Trifluorobenzene C6
H3
F3
363 551.1(0.4) 4.1(0.6) 297(20) 119
1,3,5-Trifluorobenzene C6
H3
F3
350.1(0.5) 530.9(0.4) 3.8(0.2) 300(20) 119
1,1,1-Trifluoroethane C2
H3
F3
225.9(0.1) 345.89(0.07) 3.77(0.01) 195(15) 179, 203, 309, 478, 479,
549, 624, 650–653
2,2,2-Trifluoroethanol C2
H3
F3
O 346.9(0.3) 498.57(0.05) 4.81(0.01) 211(12) 654, 655
2,2,2-Trifluoroethyl methyl ether C3
H5
F3
O 304.77 448.98(0.08) 3.51(0.06) 277(3) 176
Trifluoroiodomethane CF3
I 251.3(0.6) 396.44(0.06) 3.95(0.01) 231(3) 656–659
Trifluoromethane CHF3
191.1(0.1) 299.00(0.02) 4.82(0.01) 133(1) 310, 606, 660–664
Trifluoromethyl difluoromethyl ether C2
HF5
O 238.1(0.2) 354.49(0.06) 3.36(0.02) 226(20) 203
Trifluoromethyl 1,1,2,2-tetrafluoroethyl ether C3
HF7
O 270(1) 387.8(0.5) 2.65(0.01) 341(22) 116, 571
3,3,3-Trifluoropropene C3
H3
F3
246(4) 378.6(0.5) 3.61(0.08) 229(14) 440
Trimethylamine C3
H9
N 275.9(0.2) 433.0(0.6) 4.08(0.04) 254(6) 322, 323, 665
1,2,3-Trimethylbenzene C9
H12
449.1(0.4) 664.4(0.1) 3.45(0.03) 423(11) 79
1,2,4-Trimethylbenzene C9
H12
442.5(0.3) 649.1(0.1) 3.3(0.1) 436(12) 79, 86, 96, 251
1,3,5-Trimethylbenzene C9
H12
437.8(0.3) 637.31(0.1) 3.13(0.05) 435(12) 79
3,7,7-Trimethyl-bicyclo[4.1.0]hept-3-ene C10
H16
445(2) 658(2) 2.9(0.5) 487(10) 496
2,2,3-Trimethylbutane C7
H16
353.9(0.1) 531.3(0.5) 2.96(0.03) 401(13) 346, 349
Trimethylchlorosilane C3
H9
ClSi 330.8(0.4) 497.7(0.6) 3.20(0.03) 366(6) 266
1α,3α,5β-1,3,5-Trimethylcyclohexane C9
H18
414(2) 602(2) 2.6(0.3) 494(14) 74
3,3,5-Trimethylheptane C10
H22
430(3) 609.5(0.5) 2.32(0.05) 583(18) 536
2,2,5-Trimethylhexane C9
H20
397(2) 570(2) 2.46(0.03) 547(18) 350
2,2,3-Trimethylpentane C8
H18
382.9(0.4) 563.5(0.4) 2.73(0.02) 442(16) 346
2,2,4-Trimethylpentane C8
H18
372.3(0.2) 543.9(0.4) 2.57(0.02) 475(20) 33, 34, 86, 159, 346, 666,
667
2,3,3-Trimethylpentane C8
H18
387.8(0.3) 573.5(0.4) 2.82(0.03) 454(14) 346
2,3,4-Trimethylpentane C8
H18
386.5(0.3) 566.4(0.4) 2.72(0.02) 462(12) 346
cis-Tri(methylphenyl)trisiloxane C21
H24
O3
Si3
824(8) 353
trans-2,4,6-Trimethyl-2,4,6-
triphenylcyclotrisiloxane
C21
H24
O3
Si3
839(8) 353
Undecafluorocyclohexane C6
HF11
335.2 477.7(0.7) 546
Undecane C11
H24
469.0(0.3) 638.8(0.2) 2.01(0.03) 683(20) 34, 86, 131, 243, 249,
363, 535
Undecanoic acid C11
H22
O2
553 728(7) 2.1(0.2) 741(20) 360
1-Undecanol C11
H24
O 519(2) 703.0(0.6) 2.15(0.07) 707(12) 149
2-Undecanone C11
H22
O 506.2(0.3) 688(2) 2.08(0.01) 692(20) 256
3-Undecanone C11
H22
O 500 685(2) 2.0(0.4) 692(20) 256
4-Undecanone C11
H22
O 501(3) 681(2) 2.0(0.2) 692(20) 256
5-Undecanone C11
H22
O 500 679(2) 2.0(0.2) 692(20) 256
6-Undecanone C11
H22
O 500.5(0.5) 678(2) 2.02(0.01) 692(20) 256
Undecylbenzene C17
H28
585(3) 763(8) 1.6(0.1) 946(35) 258
Vinyl acetate C4
H6
O2
345.8(0.3) 519.2(0.2) 4.17(0.03) 269(7) 156, 440
m-Xylene C8
H10
412.2(0.4) 616.9(0.3) 3.54(0.01) 377(7) 34, 68, 79, 88, 90, 106,
668
o-Xylene C8
H10
417.5(0.4) 630.26(0.1) 3.74(0.01) 372(40) 34, 68, 78, 79, 88, 669
p-Xylene C8
H10
411.4(0.5) 616.17(0.09) 3.55(0.02) 372(35) 34, 68, 74, 79, 88, 90,
669
2,3-Xylenol C8
H10
O 490.03(0.05) 723(1) 4.1(0.3) 397(15) 218
2,4-Xylenol C8
H10
O 484.09(0.03) 708(1) 3.5(0.3) 389(15) 218
2,5-Xylenol C8
H10
O 484.29(0.08) 707(1) 3.9(0.1) 397(15) 25
2,6-Xylenol C8
H10
O 474.18(0.05) 701(1) 3.8(0.1) 396(15) 218
3,4-Xylenol C8
H10
O 500.46(0.05) 730(1) 4.9(0.5) 388(15) 218
3,5-Xylenol C8
H10
O 494.86(0.05) 716(1) 3.8(0.2) 396(15) 218
6-74	 Critical Constants of Organic Compounds
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