LECTURE 11
step 1
step 2
step 3
step 4
step 5
step 6
118 -
119 -
120 -
121 -
122 -
123 -
i-1-r
8.0   7.9   7.8    8.0   7.9   7.8    8.0   7.9   7.8    8.0   7.9   7.8    8.0   7.9   7.8    8.0   7.9 7.8
S^HWppm   e^HWppm   6 CH) I ppm   6 ^H) / ppm   6 ^H) / ppm   6 ^H) / ppm
step 1
step 2
step 3
step 4
step 5
step 6
118 -
119 -
120 -
121 -
122 -
123 -
T
T
T
T
T
T
i-1-r
8.0   7.9   7.8    8.0   7.9   7.8    8.0   7.9   7.8    8.0   7.9   7.8    8.0   7.9   7.8    8.0   7.9 7.8
S^HJ/ppm   e^HWppm   6 OH) / ppm   6 OH) / ppm   6 OH) / ppm   6 OH) / ppm
step 1
step 2
step 3
step 4
step 5
step 6
118 -
119 -
120 -
121 -
122 -
123 -
i-1-r
8.0   7.9   7.8    8.0   7.9   7.8    8.0   7.9   7.8    8.0   7.9   7.8    8.0   7.9   7.8    8.0   7.9 7.8
S^HWppm   e^HWppm   6 CH) I ppm   6 ^H) / ppm   6 ^H) / ppm   6 ^H) / ppm
A)
step 1 step 2 step 3 step 4 step 5 step 6
o.   120 -
t-1-r
t-1-r
t-1-r
l-1-r
t-1-r
B)
t-1-r
8.0 7.9 7.8 8.0 7.9 7.8 8.0 7.9 7.8 8.0 7.9 7.8 8.0 7.9 7.8 8.0 7.9 7.8 e^HJ/ppm   e^HJ/ppm   6 ?H) I ppm   6 ?H) I ppm   6 ?H) I ppm   6 ?H) I ppm
step 1 step 2 step 3 step 4 step 5 step 6
o.   120 -
t-1-r
1.0   7.9 7.!
t-1-r
1.0   7.9 7.1
t-1-r
1.0   7.9 7.!
t-1-r
1.0   7.9 7.1
t-r
1.0   7.9 7.!
t-1-r
1.0   7.9 7.!
6(^1/ppm   6 ^H) /ppm   6 ^H) I ppm   6 ^H) I ppm   6 ^H) / ppm   6 ^H) I ppm
C)
step 1
step 2
step 3
step 4
step 5
1.   120 -
t-1-r
1.0   7.9 7.!
t-1-r
1.0   7.9 7.1
t-1-r
1.0   7.9 7.!
i-1-r
1.0   7.9 7.1
t-1-r
1.0   7.9 7.!
step 6
t-1-r
1.0   7.9 7.!
6(^1/ppm   6 ^H) /ppm   6      I ppm   6      I ppm   6 ^H) / ppm   6      I ppm
A)
saturation
B) spectra with selective saturation
11 A All   111 1
C) reference spectra
D) difference
5 OH) / ppm
1
H
13
Cl
15
N