Course Information

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).
In-person direct teaching

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 19 fields of study the course is directly associated with, display

Course objectives

After completing this course, the student should handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Learning outcomes

After completing this course, the student will be able to handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerization reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, ultrasound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick's laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

recommended literature
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
• MASEL, Richard I. Chemical kinetics and catalysis. New York: John Wiley & Sons, 2001, xiii, 952. ISBN 0471241970. info
• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info

Teaching methods

Lectures. Class discussion, individual projects, literature reading.

Assessment methods

Final assessment - oral examination. The condition logon to the exam is successful presentation on the topic of kinetics and catalysis in the seminar C6330. The successful evaluation should demonstrate knowledge of at least 50% of the lectures.

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Mon 19. 2. to Sun 26. 5. Mon 14:00–15:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 19 fields of study the course is directly associated with, display

Course objectives

After completing this course, the student should handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Learning outcomes

After completing this course, the student will be able to handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerization reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, ultrasound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick's laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

recommended literature
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
• MASEL, Richard I. Chemical kinetics and catalysis. New York: John Wiley & Sons, 2001, xiii, 952. ISBN 0471241970. info
• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info

Teaching methods

Lectures. Class discussion, individual projects, literature reading.

Assessment methods

Final assessment - oral examination. The condition logon to the exam is successful presentation on the topic of kinetics and catalysis in the seminar C6330. The successful evaluation should demonstrate knowledge of at least 50% of the lectures.

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Tue 10:00–11:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 19 fields of study the course is directly associated with, display

Course objectives

After completing this course, the student should handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Learning outcomes

After completing this course, the student will be able to handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerization reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, ultrasound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick's laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

recommended literature
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
• MASEL, Richard I. Chemical kinetics and catalysis. New York: John Wiley & Sons, 2001, xiii, 952. ISBN 0471241970. info
• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info

Teaching methods

Lectures. Class discussion, individual projects, literature reading.

Assessment methods

Final assessment - oral examination. The condition logon to the exam is successful presentation on the topic of kinetics and catalysis in the seminar C6330. The successful evaluation should demonstrate knowledge of at least 50% of the lectures.

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Mon 12:00–13:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 19 fields of study the course is directly associated with, display

Course objectives

After completing this course, the student should handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Learning outcomes

After completing this course, the student will be able to handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerization reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, ultrasound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick's laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

recommended literature
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
• MASEL, Richard I. Chemical kinetics and catalysis. New York: John Wiley & Sons, 2001, xiii, 952. ISBN 0471241970. info
• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info

Teaching methods

Lectures. Class discussion, individual projects, literature reading.

Assessment methods

Final assessment - oral examination. The condition logon to the exam is successful presentation on the topic of kinetics and catalysis in the seminar C6330. The successful evaluation should demonstrate knowledge of at least 50% of the lectures.

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Mon 1. 3. to Fri 14. 5. Tue 13:00–14:50 online_CH2

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 19 fields of study the course is directly associated with, display

Course objectives

After completing this course, the student should handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Learning outcomes

After completing this course, the student will be able to handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerization reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, ultrasound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick's laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

recommended literature
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
• MASEL, Richard I. Chemical kinetics and catalysis. New York: John Wiley & Sons, 2001, xiii, 952. ISBN 0471241970. info
• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info

Teaching methods

Lectures. Class discussion, individual projects, literature reading.

Assessment methods

Final assessment - oral examination. The condition logon to the exam is successful presentation on the topic of kinetics and catalysis in the seminar C6330. The successful evaluation should demonstrate knowledge of at least 50% of the lectures.

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Tue 11:00–12:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 19 fields of study the course is directly associated with, display

Course objectives

After completing this course, the student should handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Learning outcomes

After completing this course, the student will be able to handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerization reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, ultrasound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick's laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

recommended literature
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
• MASEL, Richard I. Chemical kinetics and catalysis. New York: John Wiley & Sons, 2001, xiii, 952. ISBN 0471241970. info
• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info

Teaching methods

Lectures. Class discussion, individual projects, literature reading.

Assessment methods

Final assessment - oral examination. The condition logon to the exam is successful presentation on the topic of kinetics and catalysis in the seminar C6330. The successful evaluation should demonstrate knowledge of at least 50% of the lectures.

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Wed 8:00–9:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 19 fields of study the course is directly associated with, display

Course objectives

After completing this course, the student should handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Learning outcomes

Students will be able to solve problems of chemical kinetics, will be able to independently plan kinetic experiments, evaluate acquired data and process them into suitable outputs. Students will be able to use simulation SW for kinetics of chemical reactions.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerization reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, ultrasound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick's laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

recommended literature
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
• MASEL, Richard I. Chemical kinetics and catalysis. New York: John Wiley & Sons, 2001, xiii, 952. ISBN 0471241970. info
• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info

Teaching methods

Lectures. Class discussion, individual projects, literature reading.

Assessment methods

Final assessment - oral examination. The condition logon to the exam is successful presentation on the topic of kinetics and catalysis in the seminar C6330. The successful evaluation should demonstrate knowledge of at least 50% of the lectures.

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Mon 20. 2. to Mon 22. 5. Wed 13:00–14:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 19 fields of study the course is directly associated with, display

Course objectives

After completing this course, the student should handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerization reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, ultrasound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick's laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

recommended literature
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
• MASEL, Richard I. Chemical kinetics and catalysis. New York: John Wiley & Sons, 2001, xiii, 952. ISBN 0471241970. info
• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info

Teaching methods

Lectures. Class discussion, individual projects, literature reading.

Assessment methods

Final assessment - oral examination. The condition logon to the exam is successful presentation on the topic of kinetics and catalysis in the seminar C6330. The successful evaluation should demonstrate knowledge of at least 50% of the lectures.

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
Information on completion of the course: Podmínkou ke ykoušce je získání zápočtu ze semináře.
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Wed 16:00–17:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 19 fields of study the course is directly associated with, display

Course objectives

After completing this course, the student should handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerization reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, ultrasound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick's laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

recommended literature
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
• MASEL, Richard I. Chemical kinetics and catalysis. New York: John Wiley & Sons, 2001, xiii, 952. ISBN 0471241970. info
• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info

Teaching methods

Lectures. Class discussion, individual projects, literature reading.

Assessment methods

Final assessment - oral examination. The condition logon to the exam is successful presentation on the topic of kinetics and catalysis in the seminar C6330. The successful evaluation should demonstrate knowledge of at least 50% of the lectures.

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Tue 10:00–11:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

After completing this course, the student should handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerization reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, ultrasound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick's laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

recommended literature
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
• MASEL, Richard I. Chemical kinetics and catalysis. New York: John Wiley & Sons, 2001, xiii, 952. ISBN 0471241970. info
• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info

Teaching methods

Lectures. Class discussion, individual projects, literature reading.

Assessment methods

Final assessment - oral examination. The condition logon to the exam is successful presentation on the topic of kinetics and catalysis in the seminar C6330. The successful evaluation should demonstrate knowledge of at least 50% of the lectures.

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Wed 12:00–13:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

After completing this course, the student should handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerization reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, ultrasound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick's laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

recommended literature
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
• MASEL, Richard I. Chemical kinetics and catalysis. New York: John Wiley & Sons, 2001, xiii, 952. ISBN 0471241970. info
• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info

Teaching methods

Lectures. Class discussion, individual projects, literature reading.

Assessment methods

Final assessment - oral examination. The condition logon to the exam is successful presentation on the topic of kinetics and catalysis in the seminar C6330. The successful evaluation should demonstrate knowledge of at least 50% of the lectures.

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Mon 14:00–15:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Reaction thermodynamic (Arrhenius equation, collision and transition state theory). Solid state diffusion. Electrode kinetics.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerising reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, super-sound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick`s laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

recommended literature
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
• MASEL, Richard I. Chemical kinetics and catalysis. New York: John Wiley & Sons, 2001, xiii, 952. ISBN 0471241970. info
• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info

Teaching methods

Lectures.

Assessment methods

The student listen the lectures. The oral exam is preferred

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Wed 16:00–17:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Reaction thermodynamic (Arrhenius equation, collision and transition state theory). Solid state diffusion. Electrode kinetics.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerising reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, super-sound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick`s laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info

Teaching methods

Lectures.

Assessment methods

The student listen the lectures. The oral exam is preferred

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Fri 8:00–9:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Reaction thermodynamic (Arrhenius equation, collision and transition state theory). Solid state diffusion. Electrode kinetics.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerising reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, super-sound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick`s laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info

Teaching methods

Lectures.

Assessment methods

The student listen the lectures. The oral exam is preferred

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Mon 15:00–16:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Reaction thermodynamic (Arrhenius equation, collision and transition state theory). Solid state diffusion. Electrode kinetics.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerising reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, super-sound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick`s laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info

Teaching methods

Lectures.

Assessment methods

The student listen the lectures. The oral exam is preferred

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Mon 8:00–9:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Reaction thermodynamic (Arrhenius equation, collision and transition state theory). Solid state diffusion. Electrode kinetics.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerising reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, super-sound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick`s laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info

Assessment methods

The student listen the lectures. The oral exam is preferred

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Miroslav Holík, CSc. (lecturer)
prof. RNDr. Jiří Sopoušek, CSc. (lecturer)
prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Miroslav Holík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Tue 9:00–10:50 C12/311

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Reaction thermodynamic (Arrhenius equation, collision and transition state theory). Solid state diffusion. Electrode kinetics.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerising reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, super-sound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick`s laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Miroslav Holík, CSc. (lecturer)
prof. RNDr. Jiří Sopoušek, CSc. (lecturer)
prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Miroslav Holík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Thu 7:00–8:50 02004

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Reaction thermodynamic (Arrhenius equation, collision and transition state theory). Solid state diffusion. Electrode kinetics.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerising reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, super-sound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick`s laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Miroslav Holík, CSc. (lecturer)
prof. RNDr. Jiří Sopoušek, CSc. (lecturer)
prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Miroslav Holík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Reaction thermodynamic (Arrhenius equation, collision and transition state theory). Solid state diffusion. Electrode kinetics.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerising reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, super-sound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick`s laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Miroslav Holík, CSc. (lecturer)
doc. RNDr. Pavel Janderka, CSc. (lecturer)
prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Miroslav Holík, CSc.
Chemistry Section – Faculty of Science

Timetable

Wed 16:00–17:50 Cpm,02016

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Relaxation and dynamic NMR spectroscopy. Reaction thermodynamic (Arrhenius equation, collision and transition state theory).

Syllabus (in Czech)

• 1. Základní pojmy chemické kinetiky: rychlost reakce, rozsah reakce,rychlostní rovnice, řád reakce, elementární reakce, molekularita. Metody k určení řádu reakce 1: počátečních rychlostí, zlomkových časů, poločas reakce, střední doba života. 2. Metody k určení řádu reakce 2: derivační a integrační rychlostní rovnice pro reakce 1. a 2. řádu, nelineární rovnice, metoda izolační. 3. Reakce vratné: dynamická rovnováha, rovnovážná konstanta, reakce unimolekulární a bimolekulární, rychlostní rovnice lineární a exponenciální. 4. Reakce souběžné (paralelní): rozvětvené, konkurenční, nezávislé. Reakce následné, ustálený stav, předrovnováha. 5. Reakce katalyzované 1: homogenní katalýza, acidobazická katalýza,autokatalýza, enzymová katalýza, rovnice Michalisova-Mentenové, nestacionární kinetika. 6. Reakce katalyzované 2: integrovaná rovnice Michaelisova-Mentenové, složité enzymové reakce (Clelandova symbolika, Kingova-Altmanova metoda), inhibice. 7. Reakce katalyzované 3: heterogenní katalýza, chemisorpce a pokrytí povrchu, adsorpční izotermy (Langmuirova, BET, Freundlichova, Temkinova), uni a bimolekulární reakce na povrchu, inhibice produktem. 8. Reakce řetězové: iniciace, propagace, terminace, reakce radikálové, reakce větvené, polymerace, hoření, exploze. 9. Reakce oscilující: oscilátory (Lotka-Volterra, Brusselátor, Oregonátor), limitní cyklus, rekurentní rovnice Metody relaxační: teplotní, tlakový skok, ultrazvuk, mikrovlny. 10. Dynamická NMR spektroskopie (pravděpodobnostní matice výměny). 11. Závislost rychlostní konstanty na teplotě 1: Arrheniova rovnice, srážková teorie, pravděpodobnostní faktor, Lindemannova teorie unimolekulárních reakcí. 12. Závislost rychlostní konstanty na teplotě 2: plochy potenciální energie aktivovaný komplex, Eyringova rovnice, reakční termodynamika. 13. Lineární vztahy Gibbsovy energie: korelační analýza, rovnice Hammettova a Taftova. Kvantitativní vztahy mezi strukturou a biologickou aktivitou (QSAR).

Literature

• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Miroslav Holík, CSc. (lecturer)

Guaranteed by

prof. RNDr. Miroslav Holík, CSc.
Chemistry Section – Faculty of Science

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Relaxation and dynamic NMR spectroscopy. Reaction thermodynamic (Arrhenius equation, collision and transition state theory).

Syllabus (in Czech)

• 1. Základní pojmy chemické kinetiky: rychlost reakce, rozsah reakce,rychlostní rovnice, řád reakce, elementární reakce, molekularita. Metody k určení řádu reakce 1: počátečních rychlostí, zlomkových časů, poločas reakce, střední doba života. 2. Metody k určení řádu reakce 2: derivační a integrační rychlostní rovnice pro reakce 1. a 2. řádu, nelineární rovnice, metoda izolační. 3. Reakce vratné: dynamická rovnováha, rovnovážná konstanta, reakce unimolekulární a bimolekulární, rychlostní rovnice lineární a exponenciální. 4. Reakce souběžné (paralelní): rozvětvené, konkurenční, nezávislé. Reakce následné, ustálený stav, předrovnováha. 5. Reakce katalyzované 1: homogenní katalýza, acidobazická katalýza,autokatalýza, enzymová katalýza, rovnice Michalisova-Mentenové, nestacionární kinetika. 6. Reakce katalyzované 2: integrovaná rovnice Michaelisova-Mentenové, složité enzymové reakce (Clelandova symbolika, Kingova-Altmanova metoda), inhibice. 7. Reakce katalyzované 3: heterogenní katalýza, chemisorpce a pokrytí povrchu, adsorpční izotermy (Langmuirova, BET, Freundlichova, Temkinova), uni a bimolekulární reakce na povrchu, inhibice produktem. 8. Reakce řetězové: iniciace, propagace, terminace, reakce radikálové, reakce větvené, polymerace, hoření, exploze. 9. Reakce oscilující: oscilátory (Lotka-Volterra, Brusselátor, Oregonátor), limitní cyklus, rekurentní rovnice Metody relaxační: teplotní, tlakový skok, ultrazvuk, mikrovlny. 10. Dynamická NMR spektroskopie (pravděpodobnostní matice výměny). 11. Závislost rychlostní konstanty na teplotě 1: Arrheniova rovnice, srážková teorie, pravděpodobnostní faktor, Lindemannova teorie unimolekulárních reakcí. 12. Závislost rychlostní konstanty na teplotě 2: plochy potenciální energie aktivovaný komplex, Eyringova rovnice, reakční termodynamika. 13. Lineární vztahy Gibbsovy energie: korelační analýza, rovnice Hammettova a Taftova. Kvantitativní vztahy mezi strukturou a biologickou aktivitou (QSAR).

Literature

• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Miroslav Holík, CSc. (lecturer)

Guaranteed by

prof. RNDr. Miroslav Holík, CSc.
Chemistry Section – Faculty of Science

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Relaxation and dynamic NMR spectroscopy. Reaction thermodynamic (Arrhenius equation, collision and transition state theory).

Syllabus (in Czech)

• 1. Základní pojmy chemické kinetiky: rychlost reakce, rozsah reakce,rychlostní rovnice, řád reakce, elementární reakce, molekularita. Metody k určení řádu reakce 1: počátečních rychlostí, zlomkových časů, poločas reakce, střední doba života. 2. Metody k určení řádu reakce 2: derivační a integrační rychlostní rovnice pro reakce 1. a 2. řádu, nelineární rovnice, metoda izolační. 3. Reakce vratné: dynamická rovnováha, rovnovážná konstanta, reakce unimolekulární a bimolekulární, rychlostní rovnice lineární a exponenciální. 4. Reakce souběžné (paralelní): rozvětvené, konkurenční, nezávislé. Reakce následné, ustálený stav, předrovnováha. 5. Reakce katalyzované 1: homogenní katalýza, acidobazická katalýza,autokatalýza, enzymová katalýza, rovnice Michalisova-Mentenové, nestacionární kinetika. 6. Reakce katalyzované 2: integrovaná rovnice Michaelisova-Mentenové, složité enzymové reakce (Clelandova symbolika, Kingova-Altmanova metoda), inhibice. 7. Reakce katalyzované 3: heterogenní katalýza, chemisorpce a pokrytí povrchu, adsorpční izotermy (Langmuirova, BET, Freundlichova, Temkinova), uni a bimolekulární reakce na povrchu, inhibice produktem. 8. Reakce řetězové: iniciace, propagace, terminace, reakce radikálové, reakce větvené, polymerace, hoření, exploze. 9. Reakce oscilující: oscilátory (Lotka-Volterra, Brusselátor, Oregonátor), limitní cyklus, rekurentní rovnice Metody relaxační: teplotní, tlakový skok, ultrazvuk, mikrovlny. 10. Dynamická NMR spektroskopie (pravděpodobnostní matice výměny). 11. Závislost rychlostní konstanty na teplotě 1: Arrheniova rovnice, srážková teorie, pravděpodobnostní faktor, Lindemannova teorie unimolekulárních reakcí. 12. Závislost rychlostní konstanty na teplotě 2: plochy potenciální energie aktivovaný komplex, Eyringova rovnice, reakční termodynamika. 13. Lineární vztahy Gibbsovy energie: korelační analýza, rovnice Hammettova a Taftova. Kvantitativní vztahy mezi strukturou a biologickou aktivitou (QSAR).

Literature

• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 3 credit(s). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Miroslav Holík, CSc. (lecturer)

Guaranteed by

prof. RNDr. Miroslav Holík, CSc.
Chemistry Section – Faculty of Science

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Relaxation and dynamic NMR spectroscopy. Reaction thermodynamic (Arrhenius equation, collision and transition state theory).

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 3 credit(s). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Miroslav Holík, CSc. (lecturer)

Guaranteed by

prof. RNDr. Miroslav Holík, CSc.
Chemistry Section – Faculty of Science

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Relaxation and dynamic NMR spectroscopy. Reaction thermodynamic (Arrhenius equation, collision and transition state theory).

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/1/0. 5 credit(s). Type of Completion: zk (examination).

Teacher(s)

prof. RNDr. Miroslav Holík, CSc. (lecturer)

Guaranteed by

prof. RNDr. Miroslav Holík, CSc.
Chemistry Section – Faculty of Science

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

• Physical Chemistry (programme PřF, M-CH)
• Physical Chemistry (programme PřF, N-CH)
• Macromolecular Chemistry (programme PřF, M-CH)
• Macromolecular Chemistry (programme PřF, N-CH)

Syllabus

• Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Relaxation and dynamic NMR spectroscopy. Reaction thermodynamic (Arrhenius equation, collision and transition state theory).

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

The course is not taught in Spring 2019

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 19 fields of study the course is directly associated with, display

Course objectives

After completing this course, the student should handle problem of solving chemical kinetics and catalysis. Students should be able to independently plan kinetic experiments, analyzed the data and process them into suitable outputs. At the same student gains knowledge about how it works software for simulation of kinetics and how to use them for the purpose of describing the kinetics of chemical reactions.

Learning outcomes

Students will be able to solve problems of chemical kinetics, will be able to independently plan kinetic experiments, evaluate acquired data and process them into suitable outputs. Students will be able to use simulation SW for kinetics of chemical reactions.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerization reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, ultrasound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick's laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

recommended literature
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info
• MASEL, Richard I. Chemical kinetics and catalysis. New York: John Wiley & Sons, 2001, xiii, 952. ISBN 0471241970. info
• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info

Teaching methods

Lectures. Class discussion, individual projects, literature reading.

Assessment methods

Final assessment - oral examination. The condition logon to the exam is successful presentation on the topic of kinetics and catalysis in the seminar C6330. The successful evaluation should demonstrate knowledge of at least 50% of the lectures.

Language of instruction

Czech

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.
The course is taught: every week.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

The information about the term spring 2012 - acreditation is not made public

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Reaction thermodynamic (Arrhenius equation, collision and transition state theory). Solid state diffusion. Electrode kinetics.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerising reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, super-sound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick`s laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info

Teaching methods

Lectures.

Assessment methods

The student listen the lectures. The oral exam is preferred

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jiří Sopoušek, CSc. (lecturer)

Guaranteed by

prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Reaction thermodynamic (Arrhenius equation, collision and transition state theory). Solid state diffusion. Electrode kinetics.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerising reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, super-sound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick`s laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info

Teaching methods

Lectures.

Assessment methods

The student listen the lectures. The oral exam is preferred

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

C6320 Chemical Kinetics

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Miroslav Holík, CSc. (lecturer)
prof. RNDr. Jiří Sopoušek, CSc. (lecturer)
prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Miroslav Holík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Passing out the lectures from Physical Chemistry II and III.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Formal kinetics (rate equation, rate constant, order of reaction). Determination of the order of reaction (initial rates, integration, fractional lifetimes, isolation). Reaction mechanism and rate laws (molecularity, elementary reactions). Consecutive, parallel and reversible reactions (steady state approximation, rate determining step).Catalysed reactions (homogeneous, enzymatic, heterogeneous). Chain reactions (polymerisation, branched chain). Reaction thermodynamic (Arrhenius equation, collision and transition state theory). Solid state diffusion. Electrode kinetics.

Syllabus

• 1. Basic definitions: rate of reaction, true rate, rate equation, order of reaction, elementary reaction, molecularity. Determination of reaction order I: initial rare method, time-fraction method, half-life method, mean life-time method. 2. Determination of reaction order II: differential and integral rate equations for 1st and 2nd order reactions, none linear equations, separate method. 3. Reversible reactions: dynamic equilibrium, equilibrium constant, unimolecular and bimolecular reactions, linear and exponential rate equations. 4. Parallel reactions: branched, competitive, independent. Consecutive reactions: steady-state, pre-equilibrium. 5. Catalytic reactions I: Homogeneous catalysis, acid-base catalysis, autocatalysis, enzymatic catalysis, Michalis-Menten equation, and unsteady state kinetics, integral Michaelis-Menten equation, complicated enzymatic reactions (symbolism of Cleland, King-Altman method), inhibition reaction. 6. Catalytic reactions II: heterogeneous catalysts, chemisorption and surface chemisorption, covering a surface, adsorption isotherms (Langmuir, BET, Freundlich, Temkin), uni/bimolecular surface reactions, and product inhibition. 7. Polymer reactions: initiation, propagation, termination, radical reactions, branched reactions, polymerising reaction, burning, explosion. 8. Oscillating reactions: oscillators (Lotka-Volterr, Brusselator, Oregonator), limiting cycle, recurrent equation. Relaxation methods: temperature jump, pressure jump, super-sound, and microwaves. 9. Rate constant temperature dependence I: Arrhenius equation, collision theory, probability factor, Lindemann theory of unimolecular reactions. 10. Rate constant temperature dependence II: surface of potential energy, activated complex, Eyring equation, thermodynamic of reactions. 11. Diffusion. Mass fluxes and diffusion coefficients. 1st and 2nd Fick`s laws. Analytical and numerical solutions of the diffusion equations, boundary constrains. Diffusion in non-ideal systems. 12. Mechanism of electron transfer in homogeneous and heterogeneous media (electrode/solution interface), Marcus theory, overpotential, Butler-Volmer equation, electron transfer coefficient, rate of electrode reaction, heterogeneous rate constant, electrode process coupled with homogeneous chemical reactions (preceding, ECE mechanism, following chemical reaction), evaluation of rate heterogeneous constants by means of common electrochemical methods,

Literature

• TREINDL, Ľudovít. Chemická kinetika. 2. přeprac. vyd. Bratislava: Slovenské pedagogické nakladateľstvo, 1990, 347 s. ISBN 8008003650. info
• ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, xvi, 1014. ISBN 0198501013. info

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.

Listed among pre-requisites of other courses

• C6330 Chemical Kinetics - seminar
  NOW(C6320)  

• Enrolment Statistics (recent)