Course Information

C7280 Electrode Kinetics

Faculty of Science
Autumn 2024

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).
In-person direct teaching

Teacher(s)

prof. RNDr. Jan Hrbáč, Ph.D. (lecturer)
RNDr. Romana Sokolová, Ph.D. (lecturer), prof. RNDr. Jan Hrbáč, Ph.D. (deputy)

Guaranteed by

prof. RNDr. Jan Hrbáč, Ph.D.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Goal of the topic lecture Electrode kinetics is to inform students of chemistry about: (a) kinetics of electrode processes on a charged interfaces, (b) different types of electro-active systems in equilibrium and out of equilibrium conditions, (c) the influence of experimental conditions on the rate constant of electrode reactions, and (d) quantification of electrochemical data with aim to calculate kinetic parameters.

Learning outcomes

Student will be able to:

-describe electrode-electrolyte interphase, equilibrium in electrochemical systems;

-present the theory of electron transfer in electrochemical reactions as well as the phenomena preceding and succeeding the electron transfer event;

- to describe transport phenomena involved during electrode transformations;

orientatate itself in experimental techniques of the electrode phenomena

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytes during current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Fick's laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reaction (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemically modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

Study Materials
The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2023

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jan Hrbáč, Ph.D. (lecturer)
RNDr. Romana Sokolová, Ph.D. (lecturer), prof. RNDr. Jan Hrbáč, Ph.D. (deputy)
prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Learning outcomes

Student will be able to:

-describe electrode-electrolyte interphase, equilibrium in electrochemical systems;

-present the theory of electron transfer in electrochemical reactions as well as the phenomena preceding and succeeding the electron transfer event;

- to describe transport phenomena involved during electrode transformations;

orientatate itself in experimental techniques of the electrode phenomena

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytes during current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Fick's laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reaction (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemically modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2022

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jan Hrbáč, Ph.D. (lecturer)
RNDr. Romana Sokolová, Ph.D. (lecturer), prof. RNDr. Jan Hrbáč, Ph.D. (deputy)
prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Learning outcomes

Student will be able to:

-describe electrode-electrolyte interphase, equilibrium in electrochemical systems;

-present the theory of electron transfer in electrochemical reactions as well as the phenomena preceding and succeeding the electron transfer event;

- to describe transport phenomena involved during electrode transformations;

orientatate itself in experimental techniques of the electrode phenomena

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytes during current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Fick's laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reaction (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemically modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

Study Materials
The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

C7280 Electrode Kinetics

Faculty of Science
autumn 2021

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jan Hrbáč, Ph.D. (lecturer)
RNDr. Romana Sokolová, Ph.D. (lecturer), prof. RNDr. Jan Hrbáč, Ph.D. (deputy)
prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Learning outcomes

Student will be able to:

-describe electrode-electrolyte interphase, equilibrium in electrochemical systems;

-present the theory of electron transfer in electrochemical reactions as well as the phenomena preceding and succeeding the electron transfer event;

- to describe transport phenomena involved during electrode transformations;

orientatate itself in experimental techniques of the electrode phenomena

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytes during current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Fick's laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reaction (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemically modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

Study Materials
The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2020

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jan Hrbáč, Ph.D. (lecturer)
RNDr. Romana Sokolová, Ph.D. (lecturer), prof. RNDr. Jan Hrbáč, Ph.D. (deputy)
prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Learning outcomes

Student will be able to:

-describe electrode-electrolyte interphase, equilibrium in electrochemical systems;

-present the theory of electron transfer in electrochemical reactions as well as the phenomena preceding and succeeding the electron transfer event;

- to describe transport phenomena involved during electrode transformations;

orientatate itself in experimental techniques of the electrode phenomena

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytes during current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Fick's laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reaction (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemically modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

Study Materials
The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2019

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jan Hrbáč, Ph.D. (lecturer)
RNDr. Romana Sokolová, Ph.D. (lecturer), prof. RNDr. Jan Hrbáč, Ph.D. (deputy)
prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Learning outcomes

Student will be able to:

-describe electrode-electrolyte interphase, equilibrium in electrochemical systems;

-present the theory of electron transfer in electrochemical reactions as well as the phenomena preceding and succeeding the electron transfer event;

- to describe transport phenomena involved during electrode transformations;

orientatate itself in experimental techniques of the electrode phenomena

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytes during current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Fick's laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reaction (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemically modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

Study Materials
The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2018

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jan Hrbáč, Ph.D. (lecturer)
RNDr. Romana Sokolová, Ph.D. (lecturer), prof. RNDr. Jan Hrbáč, Ph.D. (deputy)
prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Learning outcomes

The student will gain a deeper knowledge in the field of kinetics of electrode processes.

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytes during current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Fick's laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reaction (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemically modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
autumn 2017

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jan Hrbáč, Ph.D. (lecturer)
RNDr. Romana Sokolová, Ph.D. (lecturer), prof. RNDr. Jan Hrbáč, Ph.D. (deputy)
prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Learning outcomes

The student will gain a deeper knowledge in the field of kinetics of electrode processes.

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytes during current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Fick's laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reaction (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemically modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

Study Materials
The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2016

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jan Hrbáč, Ph.D. (lecturer)
prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytes during current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Fick's laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reaction (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemically modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

Study Materials
The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2015

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Jan Hrbáč, Ph.D. (lecturer)
prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 9 fields of study the course is directly associated with, display

Course objectives

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytes during current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Fick's laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reaction (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemically modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

Study Materials
The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2014

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytes during current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Fick's laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reaction (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemically modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

Study Materials
The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2013

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytes during current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Fick's laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reaction (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemically modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2012

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytesduring current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Ficks laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reactio (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemical modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

Study Materials
The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2011

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytesduring current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Ficks laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reactio (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemical modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2010

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Fri 7:00–8:50 C12/311

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytesduring current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Ficks laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reactio (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemical modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2009

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytesduring current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Ficks laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reactio (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemical modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2008

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Goal of the topic lecture Electrode kinetics is to inform students of chemistry about: (a) kinetics of electrode processes on a charged interfaces, (b) different types of electro-active systems in equilibrium and out of equilibrium conditions, (c)the influence of experimental conditions on the rate constant of electrode reactions, and (d) quantification of electrochemical data with aim to calculate kinetic parameters.

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytesduring current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Ficks laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reactio (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemical modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Assessment methods

Oral examination can be completed by a proving test

Language of instruction

Czech

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2007

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Goal of the topic lecture Electrode kinetics is to inform students of chemistry about: (a) kinetics of electrode processes on a charged interfaces, (b) different types of electro-active systems in equilibrium and out of equilibrium conditions, (c)the influence of experimental conditions on the rate constant of electrode reactions, and (d) quantification of electrochemical data with aim to calculate kinetic parameters.

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytesduring current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Ficks laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reactio (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemical modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Assessment methods (in Czech)

Povinně volitelný předmět pro studenty odborné chemie. Dvouhodinová jednosemestrální pednáška. Zkouška je ústní, může být doplněná testem.

Language of instruction

Czech

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2006

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Goal of the topic lecture Electrode kinetics is to inform students of chemistry about: (a) kinetics of electrode processes on a charged interfaces, (b) different types of electro-active systems in equilibrium and out of equilibrium conditions, (c)the influence of experimental conditions on the rate constant of electrode reactions, and (d) quantification of electrochemical data with aim to calculate kinetic parameters.

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytesduring current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Ficks laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reactio (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemical modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Assessment methods (in Czech)

Povinně volitelný předmět pro studenty odborné chemie. Dvouhodinová jednosemestrální pednáška. Zkouška je ústní, může být doplněná testem.

Language of instruction

Czech

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2005

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Goal of the topic lecture Electrode kinetics is to inform students of chemistry about: (a) kinetics of electrode processes on a charged interfaces, (b) different types of electro-active systems in equilibrium and out of equilibrium conditions, (c)the influence of experimental conditions on the rate constant of electrode reactions, and (d) quantification of electrochemical data with aim to calculate kinetic parameters.

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytesduring current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Ficks laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reactio (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemical modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Assessment methods (in Czech)

Povinně volitelný předmět pro studenty odborné chemie. Dvouhodinová jednosemestrální pednáška. Zkouška je ústní, může být doplněná testem.

Language of instruction

Czech

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2004

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Electrode kinetics (dynamics) for physical chemistry students describes the equilibria at electrodes and in galvanic cells, transport of mass to electrodes, systems with convective diffusion, hydrodynamic electrodes and characteristic numbers, non-stationary methods (voltammetry, pulse polarography modes), impedance spectroscopy ordered ionic layers, multisteps mechanism examples, applications.

Syllabus (in Czech)

1. Rovnovážná elektrochemie. Potenciál a napětí,referentní elektroda, typy elektrod, elektrolýza a Faradayovy zákony. Nernstova rovnice. Rychlost přenosu elektronu. Vliv potenciálu na aktivaci reakcí elektroredukce a elektrooxidace.Přepětí, Butlerova a Volmerova rovnice. Vliv potenciálu na Fermiho hladinu elektronů v kovu. Hraniční orbitaly v redoxních reakcích. 2. Marcusova theorie reakcí přenosu elektronu. Reakce inner sphere a outer sphere. Fyzikální model přenosu elektronu. Kvadratická závislost aktivační energie na standardní energii kroku přenosu elektronu. Rychlostní konstanta a transmisní koeficient. Adiabatické a neadiabatické reakce ET. 3. Roztoky elektrolytů při průchodu proudu. Tok složky = tok migrace + tok difuze + tok konvekce. Elektrický proud jako tok nabitých složek. Platnost Ohmova zákona. 4. Transport látek k elektrodě. Rychlost elektrochemického procesu. Řídící krok, transport látky jako nejvýhodnější řídící krok. Limitní proud konvektivní difuze. Analyticky řešitelné theorie proudění: podélně obtékaná plotna, válcový kanál, kapková elektroda. Theorie podobnosti, pí- theorém. Čísla: Sherwoodovo, Reynoldsovo, Schmidtovo. Rotující disková elektroda. Difuzní vrstva a hydrodynamická vrstva. 5. Voltametrie a cyklická voltametrie, inverzní voltametrie, pulzní polarografie. Vkládané napětí v čase, proudonapěťová křivka.Randlesova - Ševčíkova rovnice. Kriteria reverzibility děje.Dvoustupňové děje v inverzní voltametrii. Mikrofáze a makrofáze. DPP a NPP, Cottrellova rovnice pro limitní proud v NPP. Proudová funkce a šířka píku v DPP, ovlivněná amplitudou pulzu. 6. Rychlost a vratnost elektrodových dějů. Rychlost produkce entropie. Nulové přepětí nebo proud limitující k nule jako podmínky vratnosti elektrodových dějů. Relace mezi rychlostí ET a rychlostí transportu látky ovlivňující vratnost.Nernstova rovnice jako kriterium vratnosti. Kinetický parametr v DC polarografii, cyklické voltametrii a pro rotující diskovou elektrodu. Stupňovitost elektrodových dějů. 7. Základy nových polarografických metod. Sinusoidální AC, polarografie čtvercové vlny (square wave), pulzní diferenční polarografie. Nabíjecí proud. Maximální proud. Kinetický parametr, šířka píku. 8. AC impedanční spektroskopie. Impedance, složky in phase a out of phase, závislost na frekvenci. Sériový a paralelní obvod RC. Randlesův obvod. Warburgova impedance. Transmisní linie. 9. Struktura mezifází elektroda - roztok. Elektrická dvojvrstva Helmholtzův model. Difuzní vrstav Gouy- Chapmanova. Sternova kombinace obou modelů. Grahamova specifická adsorpce. Elektrokapilární maximum. Měření diferenciální kapacity. 10. Heterogenní reakce provázející elektrodový děj. Elektrosyntéza. Voltametrie adsorbovaných látek. Polymerní pokrytí na modifikovaných elektrodách. Monovrstva kovu, underpotential deposition. 11. Spektroelektrochemie a charakterizace povrchů. Fotoelektrochemie, fotoproud. Charakterizace povrchu ve vakuu (ex situ): LEED (low energy electron diffraction), APS (Augerova fotoelektronová spektroskopie), XPS(X-ray photoelectron spectroscopy). Skenovací tunelová mikroskopie jako zobrazení v atomové škále. Skenovací elektrochemická spektroskopie- podstata. Spektroskopická detekce elektrogenerovaných látek v roztoku- UV-VIS, IR. 12. Reaktivní částice v organické elůektrosyntéze. Elektrofory katodických reakcí. Uhlovodíky, organické halogenidy, nitrolátky, karbonylové sloučeniny, oniové sloučeniny. Elektrofory anodických oxidací. Uhlovodíky, karbonové kyseliny, aminy, kyslíkaté sloučeniny, sirné sloučeniny. Elektrodové reakce klasifikované podle typů: reduktivní tvorba vazeb (coupling), dimerace, adice. Oxidativní coupling, štěpení, anodická substituce.

Literature

N.S. Hush, Ed.: Reactions of Molecules at Electrodes, Wiley, 1971.
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
Elektrochimija organičeskich sojedinenij. Edited by Manuel M. Baizer. Moskva: Mir, 1976, 731 s. info

Assessment methods (in Czech)

Povinně volitelný předmět pro studenty odborné chemie. Dvouhodinová jednosemestrální přednáška. Zkouška je ústní, doplněná případně testem.

Language of instruction

Czech

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2003

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Syllabus (in Czech)

1. Rovnovážná elektrochemie. Potenciál a napětí,referentní elektroda, typy elektrod, elektrolýza a Faradayovy zákony. Nernstova rovnice. Rychlost přenosu elektronu. Vliv potenciálu na aktivaci reakcí elektroredukce a elektrooxidace.Přepětí, Butlerova a Volmerova rovnice. Vliv potenciálu na Fermiho hladinu elektronů v kovu. Hraniční orbitaly v redoxních reakcích. 2. Marcusova theorie reakcí přenosu elektronu. Reakce inner sphere a outer sphere. Fyzikální model přenosu elektronu. Kvadratická závislost aktivační energie na standardní energii kroku přenosu elektronu. Rychlostní konstanta a transmisní koeficient. Adiabatické a neadiabatické reakce ET. 3. Roztoky elektrolytů při průchodu proudu. Tok složky = tok migrace + tok difuze + tok konvekce. Elektrický proud jako tok nabitých složek. Platnost Ohmova zákona. 4. Transport látek k elektrodě. Rychlost elektrochemického procesu. Řídící krok, transport látky jako nejvýhodnější řídící krok. Limitní proud konvektivní difuze. Analyticky řešitelné theorie proudění: podélně obtékaná plotna, válcový kanál, kapková elektroda. Theorie podobnosti, pí- theorém. Čísla: Sherwoodovo, Reynoldsovo, Schmidtovo. Rotující disková elektroda. Difuzní vrstva a hydrodynamická vrstva. 5. Voltametrie a cyklická voltametrie, inverzní voltametrie, pulzní polarografie. Vkládané napětí v čase, proudonapěťová křivka.Randlesova - Ševčíkova rovnice. Kriteria reverzibility děje.Dvoustupňové děje v inverzní voltametrii. Mikrofáze a makrofáze. DPP a NPP, Cottrellova rovnice pro limitní proud v NPP. Proudová funkce a šířka píku v DPP, ovlivněná amplitudou pulzu. 6. Rychlost a vratnost elektrodových dějů. Rychlost produkce entropie. Nulové přepětí nebo proud limitující k nule jako podmínky vratnosti elektrodových dějů. Relace mezi rychlostí ET a rychlostí transportu látky ovlivňující vratnost.Nernstova rovnice jako kriterium vratnosti. Kinetický parametr v DC polarografii, cyklické voltametrii a pro rotující diskovou elektrodu. Stupňovitost elektrodových dějů. 7. Základy nových polarografických metod. Sinusoidální AC, polarografie čtvercové vlny (square wave), pulzní diferenční polarografie. Nabíjecí proud. Maximální proud. Kinetický parametr, šířka píku. 8. AC impedanční spektroskopie. Impedance, složky in phase a out of phase, závislost na frekvenci. Sériový a paralelní obvod RC. Randlesův obvod. Warburgova impedance. Transmisní linie. 9. Struktura mezifází elektroda - roztok. Elektrická dvojvrstva Helmholtzův model. Difuzní vrstav Gouy- Chapmanova. Sternova kombinace obou modelů. Grahamova specifická adsorpce. Elektrokapilární maximum. Měření diferenciální kapacity. 10. Heterogenní reakce provázející elektrodový děj. Elektrosyntéza. Voltametrie adsorbovaných látek. Polymerní pokrytí na modifikovaných elektrodách. Monovrstva kovu, underpotential deposition. 11. Spektroelektrochemie a charakterizace povrchů. Fotoelektrochemie, fotoproud. Charakterizace povrchu ve vakuu (ex situ): LEED (low energy electron diffraction), APS (Augerova fotoelektronová spektroskopie), XPS(X-ray photoelectron spectroscopy). Skenovací tunelová mikroskopie jako zobrazení v atomové škále. Skenovací elektrochemická spektroskopie- podstata. Spektroskopická detekce elektrogenerovaných látek v roztoku- UV-VIS, IR. 12. Reaktivní částice v organické elůektrosyntéze. Elektrofory katodických reakcí. Uhlovodíky, organické halogenidy, nitrolátky, karbonylové sloučeniny, oniové sloučeniny. Elektrofory anodických oxidací. Uhlovodíky, karbonové kyseliny, aminy, kyslíkaté sloučeniny, sirné sloučeniny. Elektrodové reakce klasifikované podle typů: reduktivní tvorba vazeb (coupling), dimerace, adice. Oxidativní coupling, štěpení, anodická substituce.

Literature

N.S. Hush, Ed.: Reactions of Molecules at Electrodes, Wiley, 1971.
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
Elektrochimija organičeskich sojedinenij. Edited by Manuel M. Baizer. Moskva: Mir, 1976, 731 s. info

Assessment methods (in Czech)

Povinně volitelný předmět pro studenty odborné chemie. Dvouhodinová jednosemestrální přednáška. Zkouška je ústní, doplněná případně testem.

Language of instruction

Czech

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2002

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

doc. RNDr. Marie Studničková, CSc. (lecturer)

Guaranteed by

doc. RNDr. Marie Studničková, CSc.
Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Syllabus (in Czech)

1. Rovnovážná elektrochemie. Potenciál a napětí,referentní elektroda, typy elektrod, elektrolýza a Faradayovy zákony. Nernstova rovnice. Rychlost přenosu elektronu. Vliv potenciálu na aktivaci reakcí elektroredukce a elektrooxidace.Přepětí, Butlerova a Volmerova rovnice. Vliv potenciálu na Fermiho hladinu elektronů v kovu. Hraniční orbitaly v redoxních reakcích. 2. Marcusova theorie reakcí přenosu elektronu. Reakce inner sphere a outer sphere. Fyzikální model přenosu elektronu. Kvadratická závislost aktivační energie na standardní energii kroku přenosu elektronu. Rychlostní konstanta a transmisní koeficient. Adiabatické a neadiabatické reakce ET. 3. Roztoky elektrolytů při průchodu proudu. Tok složky = tok migrace + tok difuze + tok konvekce. Elektrický proud jako tok nabitých složek. Platnost Ohmova zákona. 4. Transport látek k elektrodě. Rychlost elektrochemického procesu. Řídící krok, transport látky jako nejvýhodnější řídící krok. Limitní proud konvektivní difuze. Analyticky řešitelné theorie proudění: podélně obtékaná plotna, válcový kanál, kapková elektroda. Theorie podobnosti, pí- theorém. Čísla: Sherwoodovo, Reynoldsovo, Schmidtovo. Rotující disková elektroda. Difuzní vrstva a hydrodynamická vrstva. 5. Voltametrie a cyklická voltametrie, inverzní voltametrie, pulzní polarografie. Vkládané napětí v čase, proudonapěťová křivka.Randlesova - Ševčíkova rovnice. Kriteria reverzibility děje.Dvoustupňové děje v inverzní voltametrii. Mikrofáze a makrofáze. DPP a NPP, Cottrellova rovnice pro limitní proud v NPP. Proudová funkce a šířka píku v DPP, ovlivněná amplitudou pulzu. 6. Rychlost a vratnost elektrodových dějů. Rychlost produkce entropie. Nulové přepětí nebo proud limitující k nule jako podmínky vratnosti elektrodových dějů. Relace mezi rychlostí ET a rychlostí transportu látky ovlivňující vratnost.Nernstova rovnice jako kriterium vratnosti. Kinetický parametr v DC polarografii, cyklické voltametrii a pro rotující diskovou elektrodu. Stupňovitost elektrodových dějů. 7. Základy nových polarografických metod. Sinusoidální AC, polarografie čtvercové vlny (square wave), pulzní diferenční polarografie. Nabíjecí proud. Maximální proud. Kinetický parametr, šířka píku. 8. AC impedanční spektroskopie. Impedance, složky in phase a out of phase, závislost na frekvenci. Sériový a paralelní obvod RC. Randlesův obvod. Warburgova impedance. Transmisní linie. 9. Struktura mezifází elektroda - roztok. Elektrická dvojvrstva Helmholtzův model. Difuzní vrstav Gouy- Chapmanova. Sternova kombinace obou modelů. Grahamova specifická adsorpce. Elektrokapilární maximum. Měření diferenciální kapacity. 10. Heterogenní reakce provázející elektrodový děj. Elektrosyntéza. Voltametrie adsorbovaných látek. Polymerní pokrytí na modifikovaných elektrodách. Monovrstva kovu, underpotential deposition. 11. Spektroelektrochemie a charakterizace povrchů. Fotoelektrochemie, fotoproud. Charakterizace povrchu ve vakuu (ex situ): LEED (low energy electron diffraction), APS (Augerova fotoelektronová spektroskopie), XPS(X-ray photoelectron spectroscopy). Skenovací tunelová mikroskopie jako zobrazení v atomové škále. Skenovací elektrochemická spektroskopie- podstata. Spektroskopická detekce elektrogenerovaných látek v roztoku- UV-VIS, IR. 12. Reaktivní částice v organické elůektrosyntéze. Elektrofory katodických reakcí. Uhlovodíky, organické halogenidy, nitrolátky, karbonylové sloučeniny, oniové sloučeniny. Elektrofory anodických oxidací. Uhlovodíky, karbonové kyseliny, aminy, kyslíkaté sloučeniny, sirné sloučeniny. Elektrodové reakce klasifikované podle typů: reduktivní tvorba vazeb (coupling), dimerace, adice. Oxidativní coupling, štěpení, anodická substituce.

Literature

N.S. Hush, Ed.: Reactions of Molecules at Electrodes, Wiley, 1971.
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
Elektrochimija organičeskich sojedinenij. Edited by Manuel M. Baizer. Moskva: Mir, 1976, 731 s. info

Assessment methods (in Czech)

Povinně volitelný předmět pro studenty odborné chemie. Dvouhodinová jednosemestrální přednáška. Zkouška je ústní, doplněná případně testem.

Language of instruction

Czech

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2001

Extent and Intensity

2/0/0. 3 credit(s). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

doc. RNDr. Marie Studničková, CSc. (lecturer)

Guaranteed by

doc. RNDr. Marie Studničková, CSc.
Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Syllabus (in Czech)

1. Rovnovážná elektrochemie. Potenciál a napětí,referentní elektroda, typy elektrod, elektrolýza a Faradayovy zákony. Nernstova rovnice. Rychlost přenosu elektronu. Vliv potenciálu na aktivaci reakcí elektroredukce a elektrooxidace.Přepětí, Butlerova a Volmerova rovnice. Vliv potenciálu na Fermiho hladinu elektronů v kovu. Hraniční orbitaly v redoxních reakcích. 2. Marcusova theorie reakcí přenosu elektronu. Reakce inner sphere a outer sphere. Fyzikální model přenosu elektronu. Kvadratická závislost aktivační energie na standardní energii kroku přenosu elektronu. Rychlostní konstanta a transmisní koeficient. Adiabatické a neadiabatické reakce ET. 3. Roztoky elektrolytů při průchodu proudu. Tok složky = tok migrace + tok difuze + tok konvekce. Elektrický proud jako tok nabitých složek. Platnost Ohmova zákona. 4. Transport látek k elektrodě. Rychlost elektrochemického procesu. Řídící krok, transport látky jako nejvýhodnější řídící krok. Limitní proud konvektivní difuze. Analyticky řešitelné theorie proudění: podélně obtékaná plotna, válcový kanál, kapková elektroda. Theorie podobnosti, pí- theorém. Čísla: Sherwoodovo, Reynoldsovo, Schmidtovo. Rotující disková elektroda. Difuzní vrstva a hydrodynamická vrstva. 5. Voltametrie a cyklická voltametrie, inverzní voltametrie, pulzní polarografie. Vkládané napětí v čase, proudonapěťová křivka.Randlesova - Ševčíkova rovnice. Kriteria reverzibility děje.Dvoustupňové děje v inverzní voltametrii. Mikrofáze a makrofáze. DPP a NPP, Cottrellova rovnice pro limitní proud v NPP. Proudová funkce a šířka píku v DPP, ovlivněná amplitudou pulzu. 6. Rychlost a vratnost elektrodových dějů. Rychlost produkce entropie. Nulové přepětí nebo proud limitující k nule jako podmínky vratnosti elektrodových dějů. Relace mezi rychlostí ET a rychlostí transportu látky ovlivňující vratnost.Nernstova rovnice jako kriterium vratnosti. Kinetický parametr v DC polarografii, cyklické voltametrii a pro rotující diskovou elektrodu. Stupňovitost elektrodových dějů. 7. Základy nových polarografických metod. Sinusoidální AC, polarografie čtvercové vlny (square wave), pulzní diferenční polarografie. Nabíjecí proud. Maximální proud. Kinetický parametr, šířka píku. 8. AC impedanční spektroskopie. Impedance, složky in phase a out of phase, závislost na frekvenci. Sériový a paralelní obvod RC. Randlesův obvod. Warburgova impedance. Transmisní linie. 9. Struktura mezifází elektroda - roztok. Elektrická dvojvrstva Helmholtzův model. Difuzní vrstav Gouy- Chapmanova. Sternova kombinace obou modelů. Grahamova specifická adsorpce. Elektrokapilární maximum. Měření diferenciální kapacity. 10. Heterogenní reakce provázející elektrodový děj. Elektrosyntéza. Voltametrie adsorbovaných látek. Polymerní pokrytí na modifikovaných elektrodách. Monovrstva kovu, underpotential deposition. 11. Spektroelektrochemie a charakterizace povrchů. Fotoelektrochemie, fotoproud. Charakterizace povrchu ve vakuu (ex situ): LEED (low energy electron diffraction), APS (Augerova fotoelektronová spektroskopie), XPS(X-ray photoelectron spectroscopy). Skenovací tunelová mikroskopie jako zobrazení v atomové škále. Skenovací elektrochemická spektroskopie- podstata. Spektroskopická detekce elektrogenerovaných látek v roztoku- UV-VIS, IR. 12. Reaktivní částice v organické elůektrosyntéze. Elektrofory katodických reakcí. Uhlovodíky, organické halogenidy, nitrolátky, karbonylové sloučeniny, oniové sloučeniny. Elektrofory anodických oxidací. Uhlovodíky, karbonové kyseliny, aminy, kyslíkaté sloučeniny, sirné sloučeniny. Elektrodové reakce klasifikované podle typů: reduktivní tvorba vazeb (coupling), dimerace, adice. Oxidativní coupling, štěpení, anodická substituce.

Literature

N.S. Hush, Ed.: Reactions of Molecules at Electrodes, Wiley, 1971.
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
Elektrochimija organičeskich sojedinenij. Edited by Manuel M. Baizer. Moskva: Mir, 1976, 731 s. info

Language of instruction

Czech

Further Comments

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2000

Extent and Intensity: 2/0/0. 3 credit(s). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).
Teacher(s): doc. RNDr. Marie Studničková, CSc. (lecturer)
Guaranteed by: doc. RNDr. Marie Studničková, CSc.
Chemistry Section – Faculty of Science
Course Enrolment Limitations: The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with: there are 8 fields of study the course is directly associated with, display
Course objectives: Electrode kinetics (dynamics) for physical chemistry students describes the equilibria at electrodes and in galvanic cells, transport of mass to electrodes, systems with convective diffusion, hydrodynamic electrodes and characteristic numbers, non-stationary methods (voltammetry, pulse polarography modes), impedance spectroscopy ordered ionic layers, multisteps mechanism examples, applications.
Language of instruction: Czech
Further Comments: The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 1999

Extent and Intensity

2/0/0. 3 credit(s). Type of Completion: zk (examination).

Teacher(s)

doc. RNDr. Marie Studničková, CSc. (lecturer)

Guaranteed by

doc. RNDr. Marie Studničková, CSc.
Chemistry Section – Faculty of Science

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

Physical Chemistry (programme PřF, M-CH)
Physical Chemistry (programme PřF, N-CH)

Syllabus

Electrode kinetics (dynamics) for physical chemistry students describes the equilibria at electrodes and in galvanic cells, transport of mass to electrodes, systems with convective diffusion, hydrodynamic electrodes and characteristic numbers, non-stationary methods (voltammetry, pulse polarography modes), impedance spectroscopy ordered ionic layers, multisteps mechanism examples, applications.

Language of instruction

Czech

Further Comments

The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2011 - acreditation

The information about the term Autumn 2011 - acreditation is not made public

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytesduring current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Ficks laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reactio (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemical modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2010 - only for the accreditation

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytesduring current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Ficks laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reactio (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemical modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Teaching methods

Lecture. Graduates of this course will be equipped with skills for assessment of electrode processes at phase interfaces electrode/solution.

Assessment methods

Oral examination is completed by the proving test.

Language of instruction

Czech

Follow-Up Courses

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

C7280 Electrode Kinetics

Faculty of Science
Autumn 2007 - for the purpose of the accreditation

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

prof. RNDr. Libuše Trnková, CSc. (lecturer)

Guaranteed by

prof. RNDr. Libuše Trnková, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

Physical Chemistry I and II, especially the part: Kinetics

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 8 fields of study the course is directly associated with, display

Course objectives

Goal of the topic lecture Electrode kinetics is to inform students of chemistry about: (a) kinetics of electrode processes on a charged interfaces, (b) different types of electro-active systems in equilibrium and out of equilibrium conditions, (c)the influence of experimental conditions on the rate constant of electrode reactions, and (d) quantification of electrochemical data with aim to calculate kinetic parameters.

Syllabus

1. Nature of electrode reactions. Fermi energy level. The effect of potential on Fermi level of electrons. Border orbitals in redox reactions. Thermodynamics and kinetics. Methods of electrode reactions study.
2. Equilibrium electrochemistry. Inner and outer potentials, electrochemical and electrode potentials, galvanic cell and its thermodynamics, classification of electrodes, standard electrode potentials.
3. Motion of ions in solutions (diffusion and migration), conductivity and movement, diffusion (liquid) potential, ion-selective electrodes, biomembranes. Solutions of electrolytesduring current pass.
4. Structure of electrode/electrolyte interface. Electric double layer (EDL) and its models (Helmholtz, Gouy- Chapman, Stern, Graham). Specific adsorption. Electrocapillarity maximum. Integral and differential capacity of EDL. EDL on mono-crystalline and poly-crystalline materials. Electrokinetic phenomena, zeta potential, sedimentation potential, electrophoresis, electroosmosis.
5. Mechanism of electron transfer in homogeneous (solutions) and heterogeneous media (electrode/solution), heterogeneous rate constants, exchange current, microscopic interpretation of electron transfer Marcus theory, overvoltage, Butler Volmer equation, charge transfer coefficient.
6. Mass transport. Migration, diffusion, convection. Diffusion, Ficks laws. Limiting diffusion current (planar and spherical diffusion), polarization overpotential, Nernst diffusion layer. Rate determining step (rds).
7. Reversible and irreversible reactions, values of heterogeneous rate constants, Tafel law, effect of EDL and specific adsorption on electrode kinetics, electrode process without and with chemical reactio (preceding, inserted, and following chemical reaction). Consecutive reactions.
8. Hydrodynamic systems: rotating disk electrodes (single and double). Hydrodynamic electrodes in out of stationary techniques. Multiple electron transfer. Investigation of coupled homogeneous reactions
9. Kinetic parameter in individual electrochemical methods. Possible use of potentiostatic and galvanostatic methods for investigation of electrode processes. Criteria of reversibility of electrode processes.
10. Impedance, in phase and out of phase components, serial and parallel circuit of an electrochemical cell. Randles circuit, Warburg impedance. The faradaic impedance for a simple electrode process; calculation of heterogeneous rate constants from impedance data (electrochemical impedance spectrum EIS).
11. Electrode reactions classification according to the type of chemical reactions. Electro-synthesis. Electrodeposition and underpotential deposition. Bockris mechanism of metal electrodeposition. Chemical modified electrodes, polymer electrodes. Corrosion and its kinetics.
12. Non-electrochemical probes of electrodes and electrode processes. The characterization of electrode surfaces. In situ and ex situ spectroscopic techniques, in situ and ex situ microscopic techniques, and other in situ techniques. Photoelectrochemistry. Electrochemiluminescence.

Literature

ATKINS, P. W. Physical chemistry. 6th ed. Oxford: Oxford University Press, 1998, 1014 s. ISBN 0198501013. info
BRETT, Christopher M. A. and Ana Maria Oliviera BRETT. Electroanalysis. Oxford: Oxford University Press, 1998, 88 s. ISBN 0198548168. info
FISHER, A. C. Electrode dynamics. Oxford: Oxford University Press, 1996, 83 s. ISBN 0-19-855690-X. info
BARD, Allen J. and Larry R. FAULKNER. Electrochemical methods : fundamentals and applications. 2nd ed. New York: John Wiley & Sons, 2001, xxi, 833. ISBN 0471043729. info

Assessment methods (in Czech)

Povinně volitelný předmět pro studenty odborné chemie. Dvouhodinová jednosemestrální pednáška. Zkouška je ústní, může být doplněná testem.

Language of instruction

Czech

Further comments (probably available only in Czech)

The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.

The course is also listed under the following terms Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.

Enrolment Statistics (recent)

Course Information

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

C7280 Electrode Kinetics

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