C8371 Chemical Reactivity

Faculty of Science
Spring 2000
Extent and Intensity
2/0/0. 3 credit(s). Type of Completion: k (colloquium).
Teacher(s)
doc. RNDr. Pavel Kubáček, CSc. (lecturer)
Guaranteed by
doc. RNDr. Pavel Kubáček, CSc.
Chemistry Section – Faculty of Science
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
Syllabus
  • Potential energy hypersurfaces. The qualitative description of reactivity by means of orbital interactions. The perturbation MO theory. Frontier orbitals. Charge and orbital controlled reactions. The concept of conservation of orbital symmetry. Correlation diagrams in bonding and reactivity problems. Thermal and photochemical pericyclic reactions. Four-centre transition states in inorganic and organic reactions. Orbital interactions through space and through bonds. The isolobal analogy.
Literature
  • LOWE, John P. Quantum chemistry. 2nd ed. San Diego: Academic Press, 1993, xx, 711. ISBN 0124575552. info
  • FLEMING, Ian. Hraniční orbitaly a reakce v organické chemii. Translated by Josef Panchartek. 1. vyd. Praha: Státní nakladatelství technické literatury, 1983, 254 s. info
  • HAVLAS, Zdeněk and Rudolf ZAHRADNÍK. Řešené úlohy z chemické reaktivity : kvalitativní a kvantitativní využití metod kvantové chemie. 1. vyd. Praha: Academia, 1987, 193 s. info
  • ZAHRADNÍK, Rudolf and Rudolf POLÁK. Základy kvantové chemie. Vyd. 1. Praha: Státní nakladatelství technické literatury, 1976, 437 s. URL info
Language of instruction
Czech
Further comments (probably available only in Czech)
The course is taught annually.
The course is taught: every week.
General note: v a.r.2000/01.

  • Enrolment Statistics (recent)
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