PdF:CH2BP_2W8S Organic Chemistry Seminar 1 - Course Information
CH2BP_2W8S Organic Chemistry Seminar 1
Faculty of EducationSpring 2008
- Extent and Intensity
- 0/1/0. 1 credit(s). Type of Completion: z (credit).
- Teacher(s)
- Mgr. Jiří Šibor, Ph.D. (seminar tutor)
- Guaranteed by
- Mgr. Jiří Šibor, Ph.D.
Department of Physics, Chemistry and Vocational Education – Faculty of Education
Contact Person: Helena Pelcová - Timetable
- Thu 7:00–7:45 učebna 3, Thu 7:55–8:40 učebna 3
- Course Enrolment Limitations
- The course is also offered to the students of the fields other than those the course is directly associated with.
- fields of study / plans the course is directly associated with
- Lower Secondary School Teacher Training in Chemistry (programme PdF, B-SPE)
- Lower Secondary School Teacher Training in Chemistry (programme PdF, M-ZS4)
- Lower Secondary School Teacher Training in Chemistry (programme PdF, M-ZS5)
- Course objectives
- The subject of organic chemistry. Nomenclature of organic chemistry. Principles of organic chemistry. General criteria of chemical reaction. Spectral properties of organic compounds. Alkanes and cycloal-kanes. Optical activity and symmetry of molecules. Alkenes. Dienes and polyenes. Isoprenoides. Ste-roids. Pericyclic reactions. Alkynes. Aromatic compounds.
- Syllabus
- The subject of organic chemistry. Nomenclature of organic chemistry. Name of compounds for-mation. Chemical bonds and bonding in organic molecules. Hybridization of the carbon atom, bon-ding energy, bond length, polarity of the chemical bond. Inductive and mesomeric effects, conjugation. Steric effects. General criteria of chemical reaction - reaction kinetics, reaction profiles and mecha-nism. Activation energy and enthalpy of the reaction. Chemical. Acidity and basicity. Arrhenius, Brøn-sted and Lewis explanation, acids and bases, pKa and pH. Spectral properties of organic com-pounds. Electronic spectra. Infrared spectroscopy, Nuclear magmetic resonance, mass spectroscopy. Alkanes and cycloalkanes. Chain isomerie, conformation analysis of alkanes and cycloalkanes. Fu-sed cyclic systems. Newmann projection. cis-trans- Isomerism of cycloalkanes. Radical reactions as typical reactions of this system. Summary of radical reactions. Optical activity and symmetry of molecules. Chiral molecules, conditions of chirality. Methods of space objects presentation. Enantio-mers, optical activity, specific rotation and its measurement, optical purity, racemic mixture. Molecules with more than one stereocenter. Cahn, Ingold, Prelog rules. Alkenes, stereochemistry of double bond, cis-trans and E-Z nomenclature. Addition reactions, their summary with attention to the stereo-chemistry and mechanism. Polymerizations. Dienes and polyenes (cumulated, isolated, conjugated). Reactions of conjugated dienes, conditions and mechanism of 1,2- and 1,4-addition. Isoprenoides (monoterpenes, sesquiterpenes, di-, tri- and tetraterpenes, carotenes). Steroids. Pericyclic reacti-ons - electrocyclic reactions, cycloaddition reactions, the rules of their realization, sigmatropic rear-rangements. Alkynes and their structure. Properties of the triple bond, addition reactions (electrophilic and nucleophilic additions), acidity of the hydrogen atoms bound on sp- carbon. Aromatic com-pounds.The phenomenon of aromaticity and its properties. Nonbenzoid aromates (polycyclic aroma-tes, annulenes, aromatic ions.} Mechanism of aromatic electrophilic substitution. Summary of electro-philic reactions, formation of electrophilic reagents. Effect of substituents on the reactivity and orien-tation. Hammet equation, sigma and rho constants. Ipso substitution. Nucleophilic substitution on the aromatic ring (SN1, SN2, elimination-addition mechanism). Conditions for addition reactions and reacti-ons of oxidation. Substitution a other reactions on fused aromatic compounds.
- Literature
- ŠIBOR, Jiří. Cvičebnice organické chemie (Excercises of Organic Chemistry). 1. vydání. Brno: Masarykova univerzita v Brně, 2004, 123 pp. ISBN 80-210-3326-6. info
- Assessment methods (in Czech)
- Seminář. Písemný test - splnění 60 %.
- Language of instruction
- Czech
- Further Comments
- The course is taught annually.
- Enrolment Statistics (Spring 2008, recent)
- Permalink: https://is.muni.cz/course/ped/spring2008/CH2BP_2W8S