C5350 Analytical Chemistry III

Faculty of Science
Autumn 2009
Extent and Intensity
2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).
Teacher(s)
prof. RNDr. Přemysl Lubal, Ph.D. (lecturer)
prof. Mgr. Jan Preisler, Ph.D. (lecturer)
Guaranteed by
prof. RNDr. Viktor Kanický, DrSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Timetable
Wed 14:00–15:50 AK1
Prerequisites
C4050 Analytical Chemistry II
The requirement is passing of subjects Analytical chemistry I (C3100), Analytical chemistry II (C4050) and Laboratory courses of analytical chemistry (C3120 a C4190).
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
Course objectives
During the course consisting of closed lectures students will learn advanced analytical techniques. The course is an upgrade to basic courses Analytical chemistry I a Analytical chemistry II. The new trends in analytical chemistry (development of instrumentation, methodology) are presented in lecture. In addition, the interdisciplinary character of present-day analytical chemistry is stressed. The lecture is documented by numerous examples taken from literature or practice. On the base of acquired knowledge student is able to understand basic principles of modern analytical chemistry. Utilizing informations from the course, he can also analyse problems and propose solutions.
Syllabus
  • 1. Kinetic methods of chemical analysis. Theory - knowledge of basic terms and their use in analytical chemistry. Instrumentation and their use for analysis.
  • 2. Modern chemometric methods v analytical chemistry. Application of chemometric alghoritms and computers in analytical chemistry. Examples of optimization of analytical methods. Soft-modeling methods.
  • 3. Chemical analysis in mixed and non-aqueous solutions. Titration in mixed and non-aqueous milieus, two-phase titration. Application of tenzides in analytical chemistry.
  • 4. Analytical methods using radioisotopes. Basic terms. Methods. Description of methods and their use in practice. Activation analysis.
  • 5-6. Modern trends in chemical analysis (use of computers in "multi-array" data collection and their treatment, joining of analytical techniques - "hyphenated" techniques, miniaturisation, automation).
  • 7-8. Advanced optical methods and their use in analytical chemistry. Laser analytical spectroscopy - Properties and types of lasers. Analytical interaction of laser beam with matter. Linear methods - examples, optoacoustic, LIF spectroscopy, etc. Nonlinear methods. Special methods - detection of trace amounts, time-resolved spectroscopy, LIDAR far detection.
  • 9. Survey of instrumental methods suitable for organic analysis (Raman, IR, NMR spectroscopy, MS spectrometry, polarimetry, spectropolarimetry a CD spectrometry, refractometry a interferometry) and examples of use.
  • 10. Modern separation methods. Preconcentration of samples - Solid Phase Extraction (SPE). Membrane separation - ultrafiltration , dialysis, elektrodialysis, reverse osmosis. Methods with supercritical state of matter - extraction, chromatography. FFF methods.
  • 11-12. Surface analysis. Laser ablation. Techniques with photon probe (PES, XPS, UPS, LAMMS, etc.). Techniques with electron probe (EPXMA, SEM, kombinovaná AEM, AES, etc). Techniques with ion probe (RBS, ISS, SIMS, etc.). Techniques with pole probe (FIM, etc.). Microscopy with scanning probe (STM, AFM, etc.). Analytical X-ray spectrometry and their use in structural analysis.
Literature
  • Analytická příručka. Díl I [Zýka, 1988]. Edited by Jaroslav Zýka. 4. upr. vyd. Praha: SNTL - Nakladatelství technické literatury, 1988, 678 s. info
  • Analytická příručka. Edited by Jaroslav Zýka. 4., upr. vyd. Praha: SNTL - Nakladatelství technické literatury, 1988, 831 s. info
  • Sommer L., Základy analytické chemie II, VUTium Brno 2000.
  • HARRIS, Daniel C. Quantitative chemical analysis. 7th ed. New York: W. H. Freeman and Company, 2007, 1 sv. ISBN 0716776944. info
  • Analytical chemistry : a modern approach to analytical science. Edited by Jean-Michel Mermet - Matthias Otto - M. Valcárcel Cases. 2nd ed. Weinheim: Wiley-VCH, 2004, xxviii, 11. ISBN 3527305904. info
  • SCHWEDT, Georg. The essential guide to analytical chemistry. Translated by Brooks Haderlie. 2nd ed. Chichester: John Wiley & Sons, 1997, xii, 248. ISBN 0471974129. info
  • Aktuální publikace pro dané odvtví (Talanta, Analytica Chimica Acta, Fresenius Journal of Analytical Chemistry, Analytical Chemistry, aj.)
Teaching methods
lectures
Assessment methods
Knowledge obtained during lectures will be tested by final combined examinanition (written and oral).
Language of instruction
Czech
Further comments (probably available only in Czech)
Study Materials
The course can also be completed outside the examination period.
The course is taught annually.
Listed among pre-requisites of other courses
The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.
  • Enrolment Statistics (Autumn 2009, recent)
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