PřF:C7291 Applied Thermodynamics I - Course Information
C7291 Applied Thermodynamics I
Faculty of ScienceAutumn 2011 - acreditation
The information about the term Autumn 2011 - acreditation is not made public
- Extent and Intensity
- 2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).
- Teacher(s)
- doc. RNDr. Michal Roth, CSc. (lecturer)
prof. RNDr. Jan Vřešťál, DrSc. (lecturer) - Guaranteed by
- doc. RNDr. Michal Roth, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Contact Person: prof. RNDr. Jan Vřešťál, DrSc. - Course Enrolment Limitations
- The course is also offered to the students of the fields other than those the course is directly associated with.
- fields of study / plans the course is directly associated with
- Physical Chemistry (programme PřF, N-CH)
- Macromolecular Chemistry (programme PřF, D-CH) (2)
- Course objectives
- Main objectives can be summarized as follows: Classical thermodynamics of phase equilibria. Thermodynamics properties from volumetric data. Intermolecular forces and the theory of corresponding states. Fugacities in gas mixtures. The virial equation of state. Solubility of solids and liquids in compressed gases. Fugacities in liquid mixtures, excess functions. Fundamental relations of excess functions. Activity and activity coefficients. Normalisation of activity coefficients. Activity coefficients from excess functions.
- Syllabus
- Applied thermodynamics I 1. Problem of phase equilibria. Possibility and methods of application of thermodynamics to its solution.
- 2. Clasical thermodynamics of phase equlibria. Equilibrium in heterogeneous closed system. Gibbs-Duhem equation. Gibbs phase rule. Chemical potential. Fugacity a activity.
- 3. Thermodynamic properties from the volumetric data. Thermodynamic properties with independent variables T and P. Thermodynamic properties with independent variables T a V. Fugacity of pure liquid or pure solid. Phase equilibria from volumetric data.
- 4. Intermolecular forces and theorem of corresponding states. Potential functions. Electrostatic forces. Forces between non-polar molecules. Specific interactions. Molecular base of the theorem of corresponding states. Corresponding states in complex systems.
- 5. Fugacity in gasseous mixtures. Virial equation of state and its extension to mixtures. Virial coefficients from potential functions. Virial coefficients from the theorem of corresponding states. Fugacity at high densities. Solubility of solids and liquids in compressed gases.
- 6. Fugacity in liquid mixtures: excess thermodynamic functions. Ideal solution. Principle relations for excess functions. Activity and activity coefficient. Normalization of activity coefficients. Activity coefficients from the excess functions. Application of Gibbs-Duhem equation. Wohl equation for excess Gibbs energy.
- Teaching methods
- Lectures
- Assessment methods
- Oral exam
- Language of instruction
- Czech
- Further Comments
- The course can also be completed outside the examination period.
The course is taught annually.
The course is taught: every week.
- Enrolment Statistics (Autumn 2011 - acreditation, recent)
- Permalink: https://is.muni.cz/course/sci/autumn2011-acreditation/C7291