C8845 Theoretical Aspects of Analytical Chemistry

Faculty of Science
autumn 2017
Extent and Intensity
2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium), graded credit.
Teacher(s)
prof. RNDr. Přemysl Lubal, Ph.D. (lecturer)
Guaranteed by
prof. RNDr. Přemysl Lubal, Ph.D.
Department of Chemistry – Chemistry Section – Faculty of Science
Contact Person: prof. RNDr. Přemysl Lubal, Ph.D.
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science
Prerequisites
Prerequisities are basic courses Physical chemistry I (C3140), Physical chemistry II (C4020), Analytical chemistry I (C3100), Analytical chemistry II (C4050).
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
Course objectives
The course is focused on basic aspects of analytical important chemical reactions in solution from thermodynamic as well as kinetic point of view. The main task is to demonstrate to students the theoretical background used in analytical chemistry in order to be able to solve and optimize the newly developed analytical method for wide application in reserch and practice.
Syllabus
  • 1. Introduction to subject.
  • Theoretical background for moedelling of chemical processes in solutions.
  • 2. Description of chemical processes in solution (acidobasic, preciptiation, complexing and redox equlibria). Influence of experimental conditions on thermodynamic data (temperature, ionic strength, pressure, etc.)
  • 3. Equilibria - interphase liquid - gas, solution-solid phase. Equilibria in polyelectrolyte solution. Metal ions in solutions.
  • 4-5. Experimental methods for determination of equlibrium constants and their evaluation (graphical and computer analysis).
  • 6. Application of thermodynamic data for modelling. Demonstration of thermodynamic databases. Methods for calculation of equilibrium concentrations - software demosntration for calculation. Application analytical chemistry - optimalization of analytical methods.
  • 7. Demonstration of chemical processes in solution from chemical point of view. Influence of experimental conditions on kinetic data (temperature, ionic strength, pressure, etc.)
  • 8. Experimental methods for determination of rate constants and their evaluation (graphical and computer analysis).
  • 9. Application of kinetic dat for modelling. Methods for calculation of equilibrium concentrations - software demosntration for calculation. Application analytical chemistry.
Literature
  • ŠŮCHA, Ladislav and Stanislav KOTRLÝ. Teoretické základy analytické chemie. Vyd. 1. Praha: SNTL - Nakladatelství technické literatury, 1971, 328 s. URL info
  • KOTRLÝ, Stanislav and Ladislav ŠŮCHA. Chemické rovnováhy v analytické chemii : tabulky a diagramy. Vyd. l. Praha: SNTL - Nakladatelství technické literatury, 1988, 386 s. info
  • STUMM, Werner and James J. MORGAN. Aquatic chemistry : chemical equilibria and rates in natural waters. New York: John Wiley & Sons, 1995, xvi, 1022. ISBN 0-471-51184-6-. info
  • Grenthe, I., Puigdomenech, I. (Eds.), Modelling in Aquatic Chemistry, OECD NEA Paris 1997.
  • PITTER, Pavel. Hydrochemie [Pitter, 1999]. 3. přeprac. vyd. Praha: Vydavatelství VŠCHT, 1999, 568 s. ISBN 80-03-00525-62. info
Teaching methods
Lectures
Assessment methods
combination of lecture with example demonstration on PC oral exam
Language of instruction
Czech
Further Comments
Study Materials
The course can also be completed outside the examination period.
The course is taught annually.
The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 2010 - only for the accreditation, Autumn 2002, Autumn 2003, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.
  • Enrolment Statistics (autumn 2017, recent)
  • Permalink: https://is.muni.cz/course/sci/autumn2017/C8845