PřF:C6190 Adv.lab.course inorg.chemistry - Course Information

C6190 Advanced laboratory course of inorganic chemistry.

Extent and Intensity

0/0/6. 6 credit(s) (plus extra credits for completion). Type of Completion: z (credit).

Teacher(s)

Mgr. Jaroslav Dorošenko, Ph.D. (seminar tutor)
Mgr. Martin Kejík, Ph.D. (seminar tutor)
Mgr. Zdeněk Moravec, Ph.D. (seminar tutor)
doc. Mgr. Marek Nečas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
Mgr. Martin Sojka, Ph.D. (seminar tutor)
Mgr. Aleš Stýskalík, Ph.D. (seminar tutor)

Guaranteed by

prof. RNDr. Jiří Pinkas, Ph.D.
Department of Chemistry – Chemistry Section – Faculty of Science
Contact Person: prof. RNDr. Jiří Pinkas, Ph.D.
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Tue 8:00–13:50 Kontaktujte učitele

Prerequisites

Succesful completion of Inorganic Chemistry I-II courses.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CHE)

Course objectives

The course covers a set of selected experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Learning outcomes

After completing this course, students will be able to:
- identify suitable syntetic methods for laboratory synthesis of selected inorganic compounds;
- extract from literature necessary procedures, starting materials and caveats of the selected syntetic method;
- prepare laboratory instruments and starting materials for the synthesis of selected inorganic compound;
- safely carry out syntetic reactions, isolate products, establish yields, identify possible sideproducts;
- unequivocally characterize desired product by available instrumental methods;

Syllabus

• Úloha 1. Příprava trimethylsilylesteru kyseliny fosforečné
  Úloha 2. Příprava tetraacetoxysilanu
  Úloha 3. Příprava cyklického aluminofosfátu
  Úloha 4. Příprava silikofosfátového xerogelu
  Úloha 5. Příprava bis(difenylfosfino)ferrocenu (dppf)
  Úloha 6. Příprava komplexů dppf
  Charakterizace produktů:
  1H, 13C, 29Si, 31P NMR, 29Si CP MAS NMR, DIP MS, IR-ATR, XRF, TG/DSC

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5
• GIROLAMI, Gregory S., Thomas B. RAUCHFUSS and Robert J. ANGELICI. Synthesis and technique in inorganic chemistry :a laboratory manual. 3rd ed. Sausalito, Calif.: University Science Books, 1998, xiii, 272. ISBN 0-935702-48-2. info
• SHRIVER, D. F. The manipulation of air-sensitive compounds. New York: McGraw-Hill Book Company, 1969, xiii, 299. info

Teaching methods

Laboratory course, literature search, practical execution of synthetic experiments

Assessment methods

Laboratory course with mandatory attendance, students have to perform all synthetic experiments and submit for evaluation laboratory protocols and prepared products. Their results are graded.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.
General note: Vyučují učitelé katedry anorganické chemie.

• Enrolment Statistics (Autumn 2019, recent)
  
• Permalink: https://is.muni.cz/course/sci/autumn2019/C6190