PřF:C6350 Stereochemistry of org. comp.

C6350 Stereochemistry of organic compounds

Faculty of Science
Spring 2000

Extent and Intensity

2/1/0. 5 credit(s). Type of Completion: zk (examination).

Teacher(s)

prof. RNDr. Jaroslav Jonas, CSc. (lecturer)

Guaranteed by

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

there are 16 fields of study the course is directly associated with, display

Syllabus

Chemistry in space - based upon symmetry, based upon constitution. Inner coordinates of molecular structure - configuration and conformation. Symmetry, asymmetry, dissymmetry, and chirality - molecular and local symmetry. Stereogenicity. Isomerism and topicity in static molecular structures and in dynamic molecular structures. Timescale of experiments. Stereoisomerism of acyclic and cyclic structures. Stereoelectronic effects, especially the anomeric effect. Stereodifferentiating reactions. Principles of stereochemical methodology. Stereochemistry of penta- and hexacoordinated compounds as compared to stereochemistry of carbon compounds. Topological stereochemistry.