C2100 Inorganic Chemistry - laboratory course

Faculty of Science
Spring 2003
Extent and Intensity
0/0/7. 7 credit(s). Recommended Type of Completion: graded credit. Other types of completion: z (credit).
Teacher(s)
RNDr. Milan Alberti, CSc. (seminar tutor)
RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
Mgr. Jiří Křivohlávek (seminar tutor)
RNDr. Aleš Mareček, CSc. (seminar tutor)
doc. Mgr. Marek Nečas, Ph.D. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
Guaranteed by
prof. RNDr. Jiří Pinkas, Ph.D.
Chemistry Section – Faculty of Science
Timetable of Seminar Groups
C2100/01: No timetable has been entered into IS. D. Dastych
C2100/02: No timetable has been entered into IS. J. Pinkas
C2100/03: No timetable has been entered into IS. M. Alberti
C2100/04: No timetable has been entered into IS. M. Černík
C2100/05: No timetable has been entered into IS. J. Novosad
C2100/06: No timetable has been entered into IS. M. Nečas
C2100/07: No timetable has been entered into IS. J. Křivohlávek
Prerequisites
Basic knowledge of general and inorganic chemistry. Writing chemical equations, stoichiometric calculations, and calculations of solution concentration and mixing will be used extensively.
Course Enrolment Limitations
The course is only offered to the students of the study fields the course is directly associated with.
fields of study / plans the course is directly associated with
there are 21 fields of study the course is directly associated with, display
Course objectives
Basic laboratory course in inorganic preparative chemistry. Covers syntheses, properties and structures of simple inorganic compounds, such as oxides, halides and other salts, acids and their functional derivatives, and complexes.
Syllabus
  • 1. Introduction, safety rules, laboratory notebook, worked example of experiment calculations. Potassium hydrogen sulfate, alkalimetric titration.

    2. Preparative route selection criteria. Solubility. Potassium oxalate monohydrate, manganometric titration. Iron(II) sulfate.

    3. Copper(II) sulfate, copper(I) iodide. Mohr's salt.

    4. Synthetic routes to oxides. Tin(IV) iodide. Orthoboric acid.

    5. Chromium(III) oxide. Potassium chomate. Purity assessment of Mohr's salt.

    6. Synthetic routes to hydroxides. Hexaaquacobalt(II)chloride. Potassium tris(oxalato)chromate(III).

    7. Hexaaminecobalt(III) chloride. Pentaammine-chlorocobalt(III) chloride. Potassium tetraperoxochromate(V).

    8. Synthetic routes to acids. Metal acetylacetonate complexes. Thin-layer chromatography.

    9. Calcium tungstate. Crystal structures of basic inorganic compounds.

    10. Synthetic routes to salts. Potassium chlorate. Pentaammine-nitrocobalt(III) chloride and pentaammine-nitritocobalt(III) chloride.

    11. Boric oxide, trimethylborate. Amonnium tetrathiomolybdate(VI).

    12. Synthetic routes to halides. Potassium disulfate, potassium methylsulfate. Vacuum sublimation of SnI4.

    13. Bismuth(III) oxide. Bismut. Thermite reaction.

    14. Synthetic routes to coordination compounds. Potassium peroxydisulfate. Iodometric titration.

Literature
  • Laboratorní technika a cvičení z anorganické chemie. 7. přeprac. vyd. Brno: Masarykova univerzita, 1995, 114 s. ISBN 8021010126. info
  • TANAKA, John and Steven L. SUIB. Experimental Methods in Inorganic Chemistry. New Jersey: Prentice Hall, 1999, 393 pp. ISBN 0-13-841909-4. info
  • KLIKORKA, Jiří. Úvod do preparativní anorganické chemie. 3. vyd. Praha: SNTL - Nakladatelství technické literatury, 1974, 373 s. info
Assessment methods (in Czech)
Laboratorní cvičení probíhá každý týden. Každý druhý týden je v úvodní hodině cvičení probráno jedno obecné téma přípravy některé ze základních tříd anorganických sloučenin. V následujícím cvičení jsou znalosti probraného tématu zkontrolovány testem. Připravenost každého posluchače na příslušnou úlohu laboratorního cvičení je kontrolována před zahájením cvičení krátkým písemným testem nebo ústním přezkoušením. Všechny rovnice a výpočty pro danou úlohu musí mít posluchači připraveny v laboratorním deníku před zahájením cvičení. Zameškaná cvičení musí být řádně omluvena a pro získání klasifikovaného zápočtu je nutno je nahradit do konce semestru.
Language of instruction
Czech
Follow-Up Courses
Further comments (probably available only in Czech)
The course is taught annually.
General note: Vyučují učitelé katedry anorganické chemie.
Listed among pre-requisites of other courses
The course is also listed under the following terms Spring 2008 - for the purpose of the accreditation, Spring 2000, Spring 2001, Spring 2002, Spring 2004, Spring 2005, Spring 2006, Spring 2007, Spring 2008, Spring 2009, Spring 2010.
  • Enrolment Statistics (Spring 2003, recent)
  • Permalink: https://is.muni.cz/course/sci/spring2003/C2100