PřF:C8510 Org. React. Mechanisms-sem.

C8510 Organic Reaction Mechanisms - seminar

Faculty of Science
Spring 2003

Extent and Intensity

0/1/0. 1 credit(s) (fasci plus compl plus > 4). Type of Completion: z (credit).

Teacher(s)

prof. RNDr. Petr Klán, Ph.D. (lecturer)

Guaranteed by

Prerequisites

NOW( C8500 Organic Reaction Mechanisms )
organic chemistry; physical chemistry

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

Course objectives

Problem set discussions based on the lecture C8500.

Syllabus

1. Art of writing the reaction mechanism. 2. How chemistry studies the reaction mechanisms. 3. Reactive intermediates. Radicals, carbebes, nitrenes etc. 4. Pericylic reactions. Selection rules. 5. Nucleophilic aliphatic and aromatic substitution. 6. Eliminations. 7. Electrophilic aromatic substitution. 8. Additions to C=C bond. 9. Reactions of carbonyl compounds 10. Rearrangements. 11. Free radical reactions. 12. Oxidation and reductions. 13. Transient metal catalysis. 14. Photochemical reactions.

Literature

A: Jurášek: Fyzikálne princípy a mechanizmy organických reakcií. Veda, Bratislava 1989.
O. Červinka: Mechanismy organických reakcí. SNTL/ALFA, Praha 1981.

Language of instruction

Czech

Further Comments

The course is taught annually.
The course is taught: every week.

Listed among pre-requisites of other courses