PřF:C8810 Chemistry of transit.elements. - Course Information
C8810 Chemistry of transition elements.
Faculty of ScienceSpring 2003
- Extent and Intensity
- 2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).
- Teacher(s)
- doc. RNDr. Josef Novosad, CSc. (lecturer)
- Guaranteed by
- doc. RNDr. Josef Novosad, CSc.
Chemistry Section – Faculty of Science - Prerequisites
- General Chemistry, Inorganic Chemistry I and II
- Course Enrolment Limitations
- The course is also offered to the students of the fields other than those the course is directly associated with.
- fields of study / plans the course is directly associated with
- there are 23 fields of study the course is directly associated with, display
- Course objectives
- The course covers an introduction to the principles underlying the chemistry of the d- and f-block metals. The main focus will be on the aspects of structure, bonding, chemical thermodynamics and spectroscopy, which underpin studies of the chemistry of these elements.
- Syllabus
- 1. Coordination compounds, ligands and their classification, coordination numbers. 2. Bonding in co rdination compounds, ligand-field theory. 3. Stereochemistry of coordination compounds. 4. Isomerism of coordination compounds, stereochemically nonrigid and fluxional molecules and ions. 5. General periodic trends among transition metals. Group 11- the coinage metals. 6. Group 12 (zinc, cadmium, mercury). 7. Transition metals of group 3-the scandium family and rare earths, the lanthanide contraction. 8. Transition metals of group 4 (titanium, zirkonium, hafnium). 9. Transition metals of group 5 (vanadium, niobium, tantalum). 10. Transition metals of group 6 (chromium, molybdenum, tungsten) and transition metals of group 7 (manganese, technetium, rhenium). 11. Isopoly and heteropolyanions. 12. The iron triad. 13. Platinum metals. 14. Multiply bonded dinuclear complexes. 15. Clusters with metal-metal bonds.
- Literature
- GREENWOOD, N. N. and A. EARNSHAW. Chemistry of the elements (Orig.) : Chemie prvků. Sv. 1 : Chemie prvků. Sv. 2. info
- Cotton F.A., Murillo C., Wilkinson G., Bochmann M., Grimes R.: Advanced Inorganic Chemistry, 6th Ed., Wiley-Interscience, New York 1999.
- Housecroft C. E.: The Heavier d-Block Metals, Oxford Univ. Press, Oxford 1999.
- Jones CH. J.: d- and f-Block Chemistry, Royal Society of Chemistry, Cambridge 2001
- Assessment methods (in Czech)
- Výuka formou přednášky, ústní zkouška.
- Language of instruction
- Czech
- Further Comments
- The course is taught annually.
The course is taught: every week.
- Enrolment Statistics (Spring 2003, recent)
- Permalink: https://is.muni.cz/course/sci/spring2003/C8810