C2442 Inorganic Chemistry II

Faculty of Science
Spring 2007
Extent and Intensity
2/0/0. 2 credit(s) (fasci plus compl plus > 4). Type of Completion: zk (examination).
Teacher(s)
doc. RNDr. Jiří Toužín, CSc. (lecturer)
Guaranteed by
doc. RNDr. Jiří Toužín, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Timetable
Wed 10:00–11:50 02004
Prerequisites
Examination from C 1441, knowledge of chemistry on secondary school level
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
there are 10 fields of study the course is directly associated with, display
Course objectives
The second part of the lecture covers the chemistry of noble gases subgroups of gallium, germanium, arsenic and selenium, d- and f-blocks elements. General information on function of metals in biological systems and nomenclature of coordination compounds, their structure and bonding are included.
Syllabus
  • 1. Noble gases, clathrates, fluorides, oxides and xenon oxoacids

    2. Gallium, indium, thallium, their hydrides, oxides, halogenides and hydroxides, complex and organometallic compounds

    3. Germanium, tin, lead, their hydrides, oxides, halogenides and hydroxides, complex and organometallic compounds

    4. Arsenic, antimony, bismuth, their hydrides, oxides, sulfides and halogenidy in oxidation states III and V, oxo- a thioacids of arsenic and antimony, their salts and derivatives, Bi(III) salts, bismuthates, complex and organometallic compounds

    5. Selenium, tellurium, polonium, hydrogen chalkogenides, chalkogenides, oxides and halogenides, oxoacids, their salts and derivatives, complex compounds

    6. Scandium, yttrium, lanthanum, lanthanoides, their compounds, actinium a actinoides, oxides and halogenides, aktinoyl cations, complex and organometallic compounds, lanthanoid contraction

    7. Titanium, zirconium, hafnium, their oxides and halogenides in oxidation states II-IV, complex and organometallic compounds

    8. Vanadium, niobium, tantalum, their oxides and halogenides in oxidation states II-V, polyvanadates, niobates and tantalates, isopolyanions, peroxocompounds of vanadium, complex a organometallic compounds

    9. Chromium, molybdenum, tungsten, their oxides and halogenides in oxidation states II-VI, chromates, molybdates and tungstates, iso- a heteropolyanions, peroxocompounds of chromium, complex and organometallic compounds

    10. Manganese, technetium, rhenium, their oxides and halogenides in oxidation states II-VII, Mn(II) and Mn(III) salts, manganates, permanganates, complex compounds

    11. Iron, cobalt, nickel, their oxides, sulfides, halogenides and oxoacids salts in oxidation states II and III, ferrate(III), (IV), and (VI), carbonyl-, cyano-, and sandwich complexes

    12. Light and heavy platinum metals, oxides, sulfides and halogenides of ruthenium and osmium in oxidation states IV and VIII, of rhodium and iridium (III) and (IV), platinum and palladium (II) and (IV), complex and organometallic compounds

    13. Coordination compounds, their structure, nomenclature, and bonding problems, isomerism, mechanisms of substitution reactions, trans-effect

    14. Copper, silver, gold, silver and copper compounds in oxidation states I and II, gold compounds in oxidation states I and III, complex and organometallic compounds

    15. Zinc, cadmium, mercury, their compounds in oxidation state II, compounds of Hg(I), complex and organometallic compounds

Literature
  • Chemie prvků. Edited by N.N Greenwood - A. Earnshaw, Translated by F. Jursík. Praha: Informatorium, 1993, 793 s. ISBN 80-85427-38-9. info
  • TOUŽÍN, Jiří. Stručný přehled chemie prvků (Chemistry of the Elements, brief overview). 1.dotisk 1. vyd. Brno: Masarykova univerzita, 2003. ISBN 80-210-2635-9. info
  • Text skript ve formáru pdf: text
  • KLIKORKA, Jiří, Bohumil HÁJEK and Jiří VOTINSKÝ. Obecná a anorganická chemie [Klikorka, 1989] a. 2. nezměn. vyd. Praha: SNTL - Nakladatelství technické literatury, 1989, 592 s. info
  • Prezentace používaná na přednášce prezentace
Assessment methods (in Czech)
Výuka formou přednášky, ústní zkouška.
Language of instruction
Czech
Further Comments
Study Materials
The course is taught annually.
The course is also listed under the following terms Spring 2008 - for the purpose of the accreditation, Spring 2000, Spring 2001, Spring 2002, Spring 2003, Spring 2004, Spring 2005, Spring 2006, Spring 2008, Spring 2009, Spring 2010.
  • Enrolment Statistics (Spring 2007, recent)
  • Permalink: https://is.muni.cz/course/sci/spring2007/C2442