Course Information

C6190 Advanced laboratory course of inorganic chemistry.

Extent and Intensity

0/0/6. 6 credit(s) (plus extra credits for completion). Type of Completion: z (credit).
In-person direct teaching

Teacher(s)

Mgr. Jaroslav Dorošenko, Ph.D. (seminar tutor)
Mgr. Martin Kejík, Ph.D. (seminar tutor)
Mgr. Zdeněk Moravec, Ph.D. (seminar tutor)
doc. Mgr. Marek Nečas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
Mgr. Martin Sojka, Ph.D. (seminar tutor)
Mgr. Aleš Stýskalík, Ph.D. (seminar tutor)

Guaranteed by

prof. RNDr. Jiří Pinkas, Ph.D.
Department of Chemistry – Chemistry Section – Faculty of Science
Contact Person: prof. RNDr. Jiří Pinkas, Ph.D.
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C2200 Chemical synthesis - lab.
Succesful completion of Inorganic Chemistry I-II courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CHE)

Course objectives

The course covers a set of selected experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Learning outcomes

After completing this course, students will be able to:
- identify suitable syntetic methods for laboratory synthesis of selected inorganic compounds;
- extract from literature necessary procedures, starting materials and caveats of the selected syntetic method;
- prepare laboratory instruments and starting materials for the synthesis of selected inorganic compound;
- safely carry out syntetic reactions, isolate products, establish yields, identify possible sideproducts;
- unequivocally characterize desired product by available instrumental methods;

Syllabus

• Úloha 1. Příprava trimethylsilylesteru kyseliny fosforečné
  Úloha 2. Příprava tetraacetoxysilanu
  Úloha 3. Příprava cyklického aluminofosfátu
  Úloha 4. Příprava silikofosfátového xerogelu
  Úloha 5. Příprava bis(difenylfosfino)ferrocenu (dppf)
  Úloha 6. Příprava komplexů dppf
  Charakterizace produktů:
  1H, 13C, 29Si, 31P NMR, 29Si CP MAS NMR, DIP MS, IR-ATR, XRF, TG/DSC

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5
• GIROLAMI, Gregory S., Thomas B. RAUCHFUSS and Robert J. ANGELICI. Synthesis and technique in inorganic chemistry :a laboratory manual. 3rd ed. Sausalito, Calif.: University Science Books, 1998, xiii, 272. ISBN 0-935702-48-2. info
• SHRIVER, D. F. The manipulation of air-sensitive compounds. New York: McGraw-Hill Book Company, 1969, xiii, 299. info

Teaching methods

Laboratory course, literature search, practical execution of synthetic experiments

Assessment methods

Laboratory course with mandatory attendance, students have to perform all synthetic experiments and submit for evaluation laboratory protocols and prepared products. Their results are graded.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

Extent and Intensity

0/0/6. 6 credit(s) (plus extra credits for completion). Type of Completion: z (credit).

Teacher(s)

Mgr. Jaroslav Dorošenko, Ph.D. (seminar tutor)
Mgr. Martin Kejík, Ph.D. (seminar tutor)
Mgr. Zdeněk Moravec, Ph.D. (seminar tutor)
doc. Mgr. Marek Nečas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
Mgr. Martin Sojka, Ph.D. (seminar tutor)
Mgr. Aleš Stýskalík, Ph.D. (seminar tutor)

Guaranteed by

prof. RNDr. Jiří Pinkas, Ph.D.
Department of Chemistry – Chemistry Section – Faculty of Science
Contact Person: prof. RNDr. Jiří Pinkas, Ph.D.
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable of Seminar Groups

C6190/01: No timetable has been entered into IS. M. Nečas

Prerequisites

C2200 Chemical synthesis - lab.
Succesful completion of Inorganic Chemistry I-II courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CHE)

Course objectives

The course covers a set of selected experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Learning outcomes

After completing this course, students will be able to:
- identify suitable syntetic methods for laboratory synthesis of selected inorganic compounds;
- extract from literature necessary procedures, starting materials and caveats of the selected syntetic method;
- prepare laboratory instruments and starting materials for the synthesis of selected inorganic compound;
- safely carry out syntetic reactions, isolate products, establish yields, identify possible sideproducts;
- unequivocally characterize desired product by available instrumental methods;

Syllabus

• Úloha 1. Příprava trimethylsilylesteru kyseliny fosforečné
  Úloha 2. Příprava tetraacetoxysilanu
  Úloha 3. Příprava cyklického aluminofosfátu
  Úloha 4. Příprava silikofosfátového xerogelu
  Úloha 5. Příprava bis(difenylfosfino)ferrocenu (dppf)
  Úloha 6. Příprava komplexů dppf
  Charakterizace produktů:
  1H, 13C, 29Si, 31P NMR, 29Si CP MAS NMR, DIP MS, IR-ATR, XRF, TG/DSC

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5
• GIROLAMI, Gregory S., Thomas B. RAUCHFUSS and Robert J. ANGELICI. Synthesis and technique in inorganic chemistry :a laboratory manual. 3rd ed. Sausalito, Calif.: University Science Books, 1998, xiii, 272. ISBN 0-935702-48-2. info
• SHRIVER, D. F. The manipulation of air-sensitive compounds. New York: McGraw-Hill Book Company, 1969, xiii, 299. info

Teaching methods

Laboratory course, literature search, practical execution of synthetic experiments

Assessment methods

Laboratory course with mandatory attendance, students have to perform all synthetic experiments and submit for evaluation laboratory protocols and prepared products. Their results are graded.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

Extent and Intensity

0/0/6. 6 credit(s) (plus extra credits for completion). Type of Completion: z (credit).

Teacher(s)

Mgr. Jaroslav Dorošenko, Ph.D. (seminar tutor)
Mgr. Martin Kejík, Ph.D. (seminar tutor)
Mgr. Zdeněk Moravec, Ph.D. (seminar tutor)
doc. Mgr. Marek Nečas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
Mgr. Martin Sojka, Ph.D. (seminar tutor)
Mgr. Aleš Stýskalík, Ph.D. (seminar tutor)

Guaranteed by

prof. RNDr. Jiří Pinkas, Ph.D.
Department of Chemistry – Chemistry Section – Faculty of Science
Contact Person: prof. RNDr. Jiří Pinkas, Ph.D.
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Tue 8:00–13:50 Kontaktujte učitele

Prerequisites

Succesful completion of Inorganic Chemistry I-II courses.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CHE)

Course objectives

The course covers a set of selected experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Learning outcomes

After completing this course, students will be able to:
- identify suitable syntetic methods for laboratory synthesis of selected inorganic compounds;
- extract from literature necessary procedures, starting materials and caveats of the selected syntetic method;
- prepare laboratory instruments and starting materials for the synthesis of selected inorganic compound;
- safely carry out syntetic reactions, isolate products, establish yields, identify possible sideproducts;
- unequivocally characterize desired product by available instrumental methods;

Syllabus

• Úloha 1. Příprava trimethylsilylesteru kyseliny fosforečné
  Úloha 2. Příprava tetraacetoxysilanu
  Úloha 3. Příprava cyklického aluminofosfátu
  Úloha 4. Příprava silikofosfátového xerogelu
  Úloha 5. Příprava bis(difenylfosfino)ferrocenu (dppf)
  Úloha 6. Příprava komplexů dppf
  Charakterizace produktů:
  1H, 13C, 29Si, 31P NMR, 29Si CP MAS NMR, DIP MS, IR-ATR, XRF, TG/DSC

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5
• GIROLAMI, Gregory S., Thomas B. RAUCHFUSS and Robert J. ANGELICI. Synthesis and technique in inorganic chemistry :a laboratory manual. 3rd ed. Sausalito, Calif.: University Science Books, 1998, xiii, 272. ISBN 0-935702-48-2. info
• SHRIVER, D. F. The manipulation of air-sensitive compounds. New York: McGraw-Hill Book Company, 1969, xiii, 299. info

Teaching methods

Laboratory course, literature search, practical execution of synthetic experiments

Assessment methods

Laboratory course with mandatory attendance, students have to perform all synthetic experiments and submit for evaluation laboratory protocols and prepared products. Their results are graded.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

Study Materials
The course is taught annually.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Timetable

Wed 7:00–12:50 Kontaktujte učitele

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

doc. RNDr. Josef Novosad, CSc.
Chemistry Section – Faculty of Science

Timetable

Mon 7:00–12:50 Kontaktujte učitele

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Milan Alberti, CSc. (seminar tutor)
RNDr. Miloš Černík, CSc. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

doc. RNDr. Josef Novosad, CSc.
Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Milan Alberti, CSc. (seminar tutor)
RNDr. Miloš Černík, CSc. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

Extent and Intensity

0/6/0. 7 credit(s). Type of Completion: graded credit.

Teacher(s)

RNDr. Milan Alberti, CSc. (seminar tutor)
RNDr. Miloš Černík, CSc. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Chemistry Section – Faculty of Science

Prerequisites (in Czech)

C5380 Special Laboratory Techniques

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

Extent and Intensity

0/6/0. 7 credit(s). Type of Completion: graded credit.

Teacher(s)

RNDr. Milan Alberti, CSc. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Chemistry Section – Faculty of Science

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Pokročilá anorganická chemie - cvičení

Extent and Intensity

0/6/0. 7 credit(s). Type of Completion: graded credit.

Teacher(s)

RNDr. Milan Alberti, CSc. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Chemistry Section – Faculty of Science

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Language of instruction

Czech

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Autumn 2023

Extent and Intensity

0/0/6. 6 credit(s) (plus extra credits for completion). Type of Completion: z (credit).

Teacher(s)

Mgr. Jaroslav Dorošenko, Ph.D. (seminar tutor)
Mgr. Martin Kejík, Ph.D. (seminar tutor)
Mgr. Zdeněk Moravec, Ph.D. (seminar tutor)
doc. Mgr. Marek Nečas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
Mgr. Martin Sojka, Ph.D. (seminar tutor)
Mgr. Aleš Stýskalík, Ph.D. (seminar tutor)

Guaranteed by

prof. RNDr. Jiří Pinkas, Ph.D.
Department of Chemistry – Chemistry Section – Faculty of Science
Contact Person: prof. RNDr. Jiří Pinkas, Ph.D.
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C2200 Chemical synthesis - lab.
Succesful completion of Inorganic Chemistry I-II courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CHE)

Course objectives

The course covers a set of selected experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Learning outcomes

After completing this course, students will be able to:
- identify suitable syntetic methods for laboratory synthesis of selected inorganic compounds;
- extract from literature necessary procedures, starting materials and caveats of the selected syntetic method;
- prepare laboratory instruments and starting materials for the synthesis of selected inorganic compound;
- safely carry out syntetic reactions, isolate products, establish yields, identify possible sideproducts;
- unequivocally characterize desired product by available instrumental methods;

Syllabus

• Úloha 1. Příprava trimethylsilylesteru kyseliny fosforečné
  Úloha 2. Příprava tetraacetoxysilanu
  Úloha 3. Příprava cyklického aluminofosfátu
  Úloha 4. Příprava silikofosfátového xerogelu
  Úloha 5. Příprava bis(difenylfosfino)ferrocenu (dppf)
  Úloha 6. Příprava komplexů dppf
  Charakterizace produktů:
  1H, 13C, 29Si, 31P NMR, 29Si CP MAS NMR, DIP MS, IR-ATR, XRF, TG/DSC

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5
• GIROLAMI, Gregory S., Thomas B. RAUCHFUSS and Robert J. ANGELICI. Synthesis and technique in inorganic chemistry :a laboratory manual. 3rd ed. Sausalito, Calif.: University Science Books, 1998, xiii, 272. ISBN 0-935702-48-2. info
• SHRIVER, D. F. The manipulation of air-sensitive compounds. New York: McGraw-Hill Book Company, 1969, xiii, 299. info

Teaching methods

Laboratory course, literature search, practical execution of synthetic experiments

Assessment methods

Laboratory course with mandatory attendance, students have to perform all synthetic experiments and submit for evaluation laboratory protocols and prepared products. Their results are graded.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Autumn 2022

Extent and Intensity

0/0/6. 6 credit(s) (plus extra credits for completion). Type of Completion: z (credit).

Teacher(s)

Mgr. Jaroslav Dorošenko, Ph.D. (seminar tutor)
Mgr. Martin Kejík, Ph.D. (seminar tutor)
Mgr. Zdeněk Moravec, Ph.D. (seminar tutor)
doc. Mgr. Marek Nečas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
Mgr. Martin Sojka, Ph.D. (seminar tutor)
Mgr. Aleš Stýskalík, Ph.D. (seminar tutor)

Guaranteed by

prof. RNDr. Jiří Pinkas, Ph.D.
Department of Chemistry – Chemistry Section – Faculty of Science
Contact Person: prof. RNDr. Jiří Pinkas, Ph.D.
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C2200 Chemical synthesis - lab.
Succesful completion of Inorganic Chemistry I-II courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CHE)

Course objectives

The course covers a set of selected experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Learning outcomes

After completing this course, students will be able to:
- identify suitable syntetic methods for laboratory synthesis of selected inorganic compounds;
- extract from literature necessary procedures, starting materials and caveats of the selected syntetic method;
- prepare laboratory instruments and starting materials for the synthesis of selected inorganic compound;
- safely carry out syntetic reactions, isolate products, establish yields, identify possible sideproducts;
- unequivocally characterize desired product by available instrumental methods;

Syllabus

• Úloha 1. Příprava trimethylsilylesteru kyseliny fosforečné
  Úloha 2. Příprava tetraacetoxysilanu
  Úloha 3. Příprava cyklického aluminofosfátu
  Úloha 4. Příprava silikofosfátového xerogelu
  Úloha 5. Příprava bis(difenylfosfino)ferrocenu (dppf)
  Úloha 6. Příprava komplexů dppf
  Charakterizace produktů:
  1H, 13C, 29Si, 31P NMR, 29Si CP MAS NMR, DIP MS, IR-ATR, XRF, TG/DSC

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5
• GIROLAMI, Gregory S., Thomas B. RAUCHFUSS and Robert J. ANGELICI. Synthesis and technique in inorganic chemistry :a laboratory manual. 3rd ed. Sausalito, Calif.: University Science Books, 1998, xiii, 272. ISBN 0-935702-48-2. info
• SHRIVER, D. F. The manipulation of air-sensitive compounds. New York: McGraw-Hill Book Company, 1969, xiii, 299. info

Teaching methods

Laboratory course, literature search, practical execution of synthetic experiments

Assessment methods

Laboratory course with mandatory attendance, students have to perform all synthetic experiments and submit for evaluation laboratory protocols and prepared products. Their results are graded.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in autumn 2021

Extent and Intensity

0/0/6. 6 credit(s) (plus extra credits for completion). Type of Completion: z (credit).

Teacher(s)

Mgr. Jaroslav Dorošenko, Ph.D. (seminar tutor)
Mgr. Martin Kejík, Ph.D. (seminar tutor)
Mgr. Zdeněk Moravec, Ph.D. (seminar tutor)
doc. Mgr. Marek Nečas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
Mgr. Martin Sojka, Ph.D. (seminar tutor)
Mgr. Aleš Stýskalík, Ph.D. (seminar tutor)

Guaranteed by

prof. RNDr. Jiří Pinkas, Ph.D.
Department of Chemistry – Chemistry Section – Faculty of Science
Contact Person: prof. RNDr. Jiří Pinkas, Ph.D.
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C2200 Chemical synthesis - lab.
Succesful completion of Inorganic Chemistry I-II courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CHE)

Course objectives

The course covers a set of selected experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Learning outcomes

After completing this course, students will be able to:
- identify suitable syntetic methods for laboratory synthesis of selected inorganic compounds;
- extract from literature necessary procedures, starting materials and caveats of the selected syntetic method;
- prepare laboratory instruments and starting materials for the synthesis of selected inorganic compound;
- safely carry out syntetic reactions, isolate products, establish yields, identify possible sideproducts;
- unequivocally characterize desired product by available instrumental methods;

Syllabus

• Úloha 1. Příprava trimethylsilylesteru kyseliny fosforečné
  Úloha 2. Příprava tetraacetoxysilanu
  Úloha 3. Příprava cyklického aluminofosfátu
  Úloha 4. Příprava silikofosfátového xerogelu
  Úloha 5. Příprava bis(difenylfosfino)ferrocenu (dppf)
  Úloha 6. Příprava komplexů dppf
  Charakterizace produktů:
  1H, 13C, 29Si, 31P NMR, 29Si CP MAS NMR, DIP MS, IR-ATR, XRF, TG/DSC

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5
• GIROLAMI, Gregory S., Thomas B. RAUCHFUSS and Robert J. ANGELICI. Synthesis and technique in inorganic chemistry :a laboratory manual. 3rd ed. Sausalito, Calif.: University Science Books, 1998, xiii, 272. ISBN 0-935702-48-2. info
• SHRIVER, D. F. The manipulation of air-sensitive compounds. New York: McGraw-Hill Book Company, 1969, xiii, 299. info

Teaching methods

Laboratory course, literature search, practical execution of synthetic experiments

Assessment methods

Laboratory course with mandatory attendance, students have to perform all synthetic experiments and submit for evaluation laboratory protocols and prepared products. Their results are graded.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Spring 2019

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: z (credit).

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in spring 2018

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: z (credit).

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Spring 2017

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Spring 2016

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Spring 2015

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Spring 2014

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Spring 2013

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Spring 2012

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Spring 2011

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Spring 2010

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Spring 2009

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Spring 2008

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course in inorganic chemistry.

The information about the term Autumn 2011 - acreditation is not made public

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Teaching methods

Laboratory course covers advanced laboratory operations and writing laboratory reports.

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in spring 2012 - acreditation

The information about the term spring 2012 - acreditation is not made public

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

C6190 Advanced laboratory course of inorganic chemistry.

The course is not taught in Spring 2011 - only for the accreditation

Extent and Intensity

0/0/6. 6 credit(s) (fasci plus compl plus > 4). Type of Completion: graded credit.

Teacher(s)

RNDr. Miloš Černík, CSc. (seminar tutor)
RNDr. Dalibor Dastych, Dr. (seminar tutor)
doc. RNDr. Josef Novosad, CSc. (seminar tutor)
prof. RNDr. Jiří Pinkas, Ph.D. (seminar tutor)
prof. RNDr. Jiří Příhoda, CSc. (seminar tutor)

Guaranteed by

RNDr. Miloš Černík, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science

Prerequisites

C5380 Special Laboratory Techniques
Succesful completion of Inorganic Chemistry I-III and Special Laboratory Techniques courses.

Course Enrolment Limitations

The course is only offered to the students of the study fields the course is directly associated with.

fields of study / plans the course is directly associated with

• Inorganic Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, N-CH)

Course objectives

The course covers a set of thoroughly choosed experiments that enable to demonstrate the majority of the important laboratory techniques in the context of some interesting chemical problems. In this way rational approaches to the common operations involved in the synthesis, separation and characterization of different, mainly air-sensitive compounds may be exercized.

Syllabus

• 1. Preparation of nitrogen dioxide by thermal decomposition of lead dinitrate. Determination of dissociation grade of gaseous N2O4 at ambient temperature.
  2. Reaction of phosphorus pentachloride with ammonium sulfate. Elucidation of reaction mechanism by 31P NMR spectroscopy.
  3. Synthesis of a cyclic alumazan and its characterization by 1H NMR.
  4. Preparation of gem-diamidotetrachloro-cyclo-triphosphazene by amonolysis of P3N3Cl6. Determonation of product purity by 1H, 31P NMR and thin-layer chromatography.
  5. Synthesis of cyclohexylphosphonic acid dichloride, crystalline cyclohexylphosphonic acid and its dimethylester.
  6. Preparation of dinuclear Mo(II) complexes with quadruple Mo-Mo bond and their characterization by 1H NMR and IR spectra.
  7. Reaction of boron trichloride with phosphorus(III) chloride in liquid thionyl chloride. Elucidation of the reaction course by 31P NMR and Raman spectroscopy.

Literature

• Woolins J. D. (Ed.): Inorganic experiments, VCH Verlagsgesellschaft mbH, Weinheim 1994, ISBN 3-527-29253-5

Assessment methods (in Czech)

Cvičení v jehož průběhu studenti musí absolvovat všechny vypsané úlohy a odevzdat příslušné protokoly. Výsledky jsou hodnoceny klasifikovaným zápočtem.

Language of instruction

Czech

Follow-Up Courses

• C7001 Diploma Thesis I

Further comments (probably available only in Czech)

The course is taught annually.
The course is taught: every week.
General note: Vyučují učitelé katedry anorganické chemie.

• Enrolment Statistics (recent)