C6710 Initiation of Polyreactions

Faculty of Science
Spring 2003
Extent and Intensity
1/0/0. 1 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).
Teacher(s)
doc. RNDr. Pavel Janderka, CSc. (lecturer)
Guaranteed by
doc. RNDr. Pavel Janderka, CSc.
Chemistry Section – Faculty of Science
Prerequisites
The preliminary pass out of the basic lecture from organic chemistry is supposed.
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
there are 9 fields of study the course is directly associated with, display
Course objectives
This lecture is an advanced lecture for students of chemistry interested in polymer chemistry. It extends the concepts developed in the elementary course of macromolecule chemistry and chemical kinetics of complex reaction particularly the reactions and processes of formation of an initiating particles in chain and stepwise polymerization. The key words of the lecture are following: Classification and kinetics of polyreactions, initiation of chain reactions on multiple bond (radical, cation, anion and complex polymerization. Initiation by photochemistry, by irradition, plasma initiation, electrochemical initiation.
Syllabus
  • 1.Clasification of polyreactions - the chain reactions on the double bond, - polyadition, - polycondensation.

    2.Kinetics of chain reactions, first and zeroth order initiation.

    3.Chain polymerization,typical monomers, structure and thermodynamics aspects.

    4.Initiation of radical polymerization, breaking of unstable chemical bonds, thermal decomposition of peroxo-,azo- a diazocompounds.

    5.Red-ox initiatory systems, non-clasical initiators.

    6.Cation polymerization-iniciator systems.

    7.Anion polymerization-initiator systems, complex catalyzers.

    8.Fotochemical initiation.

    9.Radical initiation.

    10.Plasma initiation.

    11.Electrochemical initiation of polymerization (ECP), clasification, direct and indirect ECP.

    12.ECP-influence of experimental conditions.

    13.ECP of conducting polymers.

Literature
  • MLEZIVA, Josef and Jaroslav KÁLAL. Základy makromolekulární chemie. 1. vyd. Praha: Státní nakladatelství technické literatury, 1986, 380 s. info
  • KUČERA, Miloslav. Mechanismus a kinetika polymerací. Vyd. 1. Praha: Academia, 1984, 482 s. URL info
Assessment methods (in Czech)
Výuka je organizována ve čtrnácti hodinových lekcích. Obsah lekcí odpovídá členění sylabu.
Language of instruction
Czech
Further Comments
The course is taught annually.
The course is taught: every week.
The course is also listed under the following terms Spring 2008 - for the purpose of the accreditation, Spring 2004, Spring 2005, Spring 2006, Spring 2007, Spring 2008.
  • Enrolment Statistics (Spring 2003, recent)
  • Permalink: https://is.muni.cz/course/sci/spring2003/C6710