PřF:C8292 Applied Thermodynamics II - Course Information

C8292 Applied Thermodynamics II

Extent and Intensity

2/0/0. 2 credit(s) (fasci plus compl plus > 4). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).

Teacher(s)

doc. RNDr. Michal Roth, CSc. (lecturer)
prof. RNDr. Jan Vřešťál, DrSc. (lecturer)

Guaranteed by

doc. RNDr. Michal Roth, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Contact Person: prof. RNDr. Jan Vřešťál, DrSc.

Course Enrolment Limitations

The course is also offered to the students of the fields other than those the course is directly associated with.

fields of study / plans the course is directly associated with

• Analytical Chemistry (programme PřF, D-CH) (2)
• Analytical Chemistry (programme PřF, M-CH)
• Inorganic Chemistry (programme PřF, D-CH) (2)
• Inorganic Chemistry (programme PřF, M-CH)
• Biochemistry (programme PřF, D-CH) (2)
• Physical Chemistry (programme PřF, D-CH) (2)
• Physical Chemistry (programme PřF, M-CH)
• Physical Chemistry (programme PřF, N-CH)
• Macromolecular Chemistry (programme PřF, D-CH) (2)
• Environmental Chemistry (programme PřF, D-CH) (2)
• Environmental Chemistry (programme PřF, M-CH)
• Macromolecular Chemistry (programme PřF, M-CH)
• Organic Chemistry (programme PřF, D-CH) (2)
• Organic Chemistry (programme PřF, M-CH)

Course objectives

Wohl's expansion for the excess Gibbs energy. Fugacities in liquid mixtures, theories of solutions. The Flory-Huggins Equation. Solubility of gases in liquids. Solubility of solids in liquids. Distribution of a solid solute between two immiscible liquids. High-pressure equilibria. Supercritical fluid extraction. Numerical exercises and problem classes and associated tutorials for the whole course.

Syllabus

• Aplied thermodynamics II 1. Fugacity in liquid mixtures: theory of solutions. Van Laar theory. Scatchard-Hildebrand theory. 2. Lattice theories. Polymer solutions. Flory-Huggins equation. 3. Solubility of gases in liquids. Ideal solubility. Henry's law. 4. Influence of pressure and temperature on the solubility of gases. 5. Solubility of solid substances in liquids. Thermodynamic approach. Ideal solubility. 6. Non-ideal solutions. Distribution of solid substance in two immiscible liquids. 7. High pressure equilibria. Phase equilibria at high pressures. 8. Thermodynamic analysis. Supercritical fluid extraction.

Assessment methods (in Czech)

Výuka probíha každý týden a je zakončena ústní zkouškou.

Language of instruction

Czech

Further Comments

The course is taught annually.
The course is taught: every week.

• Enrolment Statistics (recent)
  
• Permalink: https://is.muni.cz/course/sci/spring2006/C8292