C2062 Inorganic Chemistry II

Faculty of Science
Spring 2011
Extent and Intensity
2/0/0. 2 credit(s) (fasci plus compl plus > 4). Type of Completion: zk (examination).
Teacher(s)
doc. RNDr. Josef Novosad, CSc. (lecturer)
Guaranteed by
doc. RNDr. Josef Novosad, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Timetable
Wed 10:00–11:50 B11/132
Prerequisites
C1061 Inorganic Chemistry I
Examination from C 1061, knowledge of chemistry on secondary school level
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
Course objectives
The second part of the lecture covers the chemistry of 15th to 18th groups and the transition elements, lanthanoides and actinoides as well as general information on function of metals in biological systems. Nomenclature of inorganic compounds (complexes included) and trends in physico-chemical properties are exercised. At the end of the course students should be able to understand and explain synthesis, reactivity, and properties of main group and transition metal compounds, supported by discussion of structure and bonding and their implications. The aim, on completion of the course, is that a student will be equipped to recognise the key classes of inorganic compound, their methods of synthetic routes and anticipated reactivity.
Syllabus
  • 1. Gallium, indium, thallium, their hydrides, oxides, halogenides and hydroxides, complex and organometallic compounds

    2. Germanium, tin, lead, their hydrides, oxides, halogenides and hydroxides, complex and organometallic compounds

    3. Arsenic, antimony, bismuth, their hydrides, oxides, sulfides and halogenidy in oxidation states III and V, oxo- a thioacids of arsenic and antimony, their salts and derivatives, Bi(III) salts, bismuthates, complex and organometallic compounds

    4. Selenium, tellurium, polonium, hydrogen chalkogenides, chalkogenides, oxides and halogenides, oxoacids, their salts and derivatives, complex compounds

    5. Scandium, yttrium, lanthanum, lanthanoides, their compounds, actinium a actinoides, oxides and halogenides, aktinoyl cations, complex and organometallic compounds, lanthanoid contraction

    6. Titanium, zirconium, hafnium, their oxides and halogenides in oxidation states II-IV, complex and organometallic compounds

    7. Vanadium, niobium, tantalum, their oxides and halogenides in oxidation states II-V, polyvanadates, niobates and tantalates, isopolyanions, peroxocompounds of vanadium, complex a organometallic compounds

    8. Chromium, molybdenum, tungsten, their oxides and halogenides in oxidation states II-VI, chromates, molybdates and tungstates, iso- a heteropolyanions, peroxocompounds of chromium, complex and organometallic compounds

    9. Manganese, technetium, rhenium, their oxides and halogenides in oxidation states II-VII, Mn(II) and Mn(III) salts, manganates, permanganates, complex compounds

    10. Iron, cobalt, nickel, their oxides, sulfides, halogenides and oxoacids salts in oxidation states II and III, ferrate(III), (IV), and (VI), carbonyl-, cyano-, and sandwich complexes

    11. Light and heavy platinum metals, oxides, sulfides and halogenides of ruthenium and osmium in oxidation states IV and VIII, of rhodium and iridium (III) and (IV), platinum and palladium (II) and (IV), complex and organometallic compounds

    12. Coordination compounds, their structure, nomenclature, and bonding problems, isomerism, mechanisms of substitution reactions, trans-effect

    13. Copper, silver, gold, silver and copper compounds in oxidation states I and II, gold compounds in oxidation states I and III, complex and organometallic compounds

    14. Zinc, cadmium, mercury, their compounds in oxidation state II, compounds of Hg(I), complex and organometallic compounds

    15. Role of metals in biological systems, iron, cobalt, chromium, molybdenum, copper, zinc, lithium, natrium, potassium, magnesium, and calcium

Literature
  • Toužín, Jiří - Stručný přehled chemie prvků, Brno 2000.
  • GREENWOOD, N. N. and Alan EARNSHAW. Chemistry of the elements. Second edition. Oxford: Butterworth-Heinemann, 1997, xxii, 1341. ISBN 0750633654. info
  • Chemie prvků. Edited by N.N Greenwood - A. Earnshaw, Translated by F. Jursík. Praha: Informatorium, 1993, 793 s. ISBN 80-85427-38-9. info
Teaching methods
The course has a form of lectures.
Assessment methods
Oral exam.
Language of instruction
Czech
Further Comments
The course is taught annually.
Listed among pre-requisites of other courses
The course is also listed under the following terms Spring 2008 - for the purpose of the accreditation, Spring 2011 - only for the accreditation, Spring 2000, Spring 2001, Spring 2002, Spring 2003, Spring 2004, Spring 2005, Spring 2006, Spring 2007, Spring 2008, Spring 2009, Spring 2010, Spring 2012, spring 2012 - acreditation, Spring 2013, Spring 2014, Spring 2015, Spring 2016, Spring 2017, spring 2018, Spring 2019, Spring 2020, Spring 2021, Spring 2022, Spring 2023, Spring 2024, Spring 2025.
  • Enrolment Statistics (Spring 2011, recent)
  • Permalink: https://is.muni.cz/course/sci/spring2011/C2062