C4680 Physical Chemistry - laboratory course

Faculty of Science
Spring 2011
Extent and Intensity
0/2/0. 2 credit(s). Type of Completion: z (credit).
Teacher(s)
prof. RNDr. Jiří Sopoušek, CSc. (seminar tutor)
Mgr. Jiří Křivohlávek (seminar tutor)
doc. Mgr. Jana Pavlů, Ph.D. (seminar tutor)
doc. RNDr. Pavel Brož, Ph.D. (seminar tutor)
prof. RNDr. Libuše Trnková, CSc. (seminar tutor)
RNDr. Luboš Poláček (alternate examiner)
Guaranteed by
prof. RNDr. Jiří Sopoušek, CSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Timetable of Seminar Groups
C4680/01: Wed 10:00–11:50 C10/213, J. Křivohlávek
C4680/02: Wed 12:00–13:50 C10/213, J. Křivohlávek
Prerequisites
Physical chemistry course. PC skills.
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
The capacity limit for the course is 13 student(s).
Current registration and enrolment status: enrolled: 0/13, only registered: 0/13, only registered with preference (fields directly associated with the programme): 0/13
fields of study / plans the course is directly associated with
Course objectives
At the end of this course the student will be able to: Working with basic laboratory equipment for the determination of pH, ORP, ISE, osmomolarity, dissociation constants, the constants of distribution, transmission numbers and understand the principles of these measurements. Apply UV-VIS spectroscopy, calorimetry, potentiometry, and refractometry for determination of phase diagrams, absorption equilibrium, kinetic and equilibrium constants, determination of molar mass. Understanding the diffusion and transport processes on the interface of micelles and membranes. Understand going in oscillating catalytic systems.
Syllabus
  • Exercise list:
  • Determination of physiological solutions osmomolarity
  • Construction of a binary system phase diagram water-ethanol
  • Determination of partition coefficient in the extraction system
  • Determination of diffusion coefficient of ammonia in the membrane
  • Potentiometric determination of dissociation constants of weak acids
  • Measurement of conductivity and degree of dissociation of strong and weak electrolyte
  • Photochemical determination of dissociation constant of bromocresol green
  • Determination of the heat of neutralization
  • Critical micellar concentration
  • Determination of number of transmission speed on interface
  • Photometric study of reaction kinetics
  • Verification of the Nernst-Peters equation for electrode potential of the redox electrode Ce +4 / Ce +3
  • Using ion-selective electrode for determination of nitrate in waters
  • Determination of the temperature dependence of oxygen solubility in water
  • Determination of molar mass of naphthalene kryoskopicky
  • Tracking oscillations in the catalytic reaction system (Belousov-Jabotinsky)
Literature
  • BROŽ, Pavel, Miroslav HOLÍK, Pavel JANDERKA, Jiří SOPOUŠEK, Jaromír TOUŠEK and Libuše TRNKOVÁ. Laboratorní cvičení z fyzikální chemie (Laboratory Exercises in Physical Chemistry). Brno: Masarykova univerzita, 2003, 80 pp. Fyzikální chemie 1. ISBN 80-210-3203-0. info
  • STUDNIČKOVÁ, Marie. Laboratorní cvičení z fyzikální chemie pro biology a ekology. 1. vyd. Brno: Masarykova univerzita, 2001, 68 s. ISBN 8021012390. info
Teaching methods
Independent laboratory work under the supervision of the instructor.
Assessment methods
Students perform before each laboratory exercise test readiness. Students work individually and after performing the exercises are uploading protocol with the achieved results. Students will receive credit, if planned to execute all tasks and hand over all protocols.
Language of instruction
Czech
Further comments (probably available only in Czech)
Study Materials
The course is taught annually.
The course is also listed under the following terms Spring 2008 - for the purpose of the accreditation, Spring 2011 - only for the accreditation, Spring 2001, Spring 2002, Spring 2003, Spring 2004, Spring 2005, Spring 2006, Spring 2007, Spring 2008, Spring 2009, Spring 2010, Spring 2012, spring 2012 - acreditation, Spring 2013, Spring 2014, Spring 2015, Spring 2016, Spring 2017, spring 2018, Spring 2019, Spring 2021, Spring 2022, Spring 2023, Spring 2024, Spring 2025.
  • Enrolment Statistics (Spring 2011, recent)
  • Permalink: https://is.muni.cz/course/sci/spring2011/C4680