C9981 Heterogeneous catalysis

Faculty of Science
Autumn 2022
Extent and Intensity
2/0/0. 2 credit(s) (plus extra credits for completion). Recommended Type of Completion: zk (examination). Other types of completion: k (colloquium).
Teacher(s)
Mgr. Aleš Stýskalík, Ph.D. (lecturer)
Guaranteed by
Mgr. Aleš Stýskalík, Ph.D.
Department of Chemistry – Chemistry Section – Faculty of Science
Contact Person: prof. RNDr. Jiří Pinkas, Ph.D.
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science
Timetable
Mon 16:00–17:50 C14/207
Prerequisites
Thorough knowledge of principles and facts covered by the courses of Inorganic, Organic, Physical, and Materials Chemistry is required.
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
there are 20 fields of study the course is directly associated with, display
Course objectives
This course covers advanced principles of heterogeneous catalysis with emphasis on thermodynamics, kinetics, mechanistic investigations, preparation and characterization of catalysts, and development of single-site catalysts. Examples of industrial catalytic reactions will be discussed.
Learning outcomes
Students, after finishing this course, will be able:
- to understand principles of heterogeneous catalysis
- to apply thermodynamics principles to hc
- to apply kinetics principles to hc
- to understand mechanistic investigations
- to suggest methods for preparation of catalysts
- to suggest methods for characterization of catalysts
Syllabus
  • 1. Basic thermodynamics of catalytic reactions: From adsorption of a reactant to desorption of a product – steps in heterogeneous catalysis.
  • 2. Basic kinetics and mechanisms of catalytic reactions. Diffusional limitations.
  • 3. Preparation of catalysts, role of catalyst support.
  • 4. Preparation and application of single-site catalysts.
  • 5. Characterization of catalysts.
  • 6. In situ and operando characterization of catalysts.
  • 7. Three-way catalyst.
  • 8. Haber-Bosch synthesis of ammonia.
  • 9. Zeolites in oil refinement.
Literature
    recommended literature
  • THOMAS, J. M. and W. J. THOMAS. Principles and practice of heterogeneous catalysis. 1st ed. Weinheim: VCH Verlagsgesellschaft, 1997, xxiii, 669. ISBN 352729239X. info
Teaching methods
The course is taught in English. It consists of 13 lectures of 100 minutes each. Course materials, such as lecture slides, supplementary articles, tables, are available to students in the Information System of Masaryk University.
Assessment methods
Written final exam worth 100 pts, minimum 50 pts to pass.
Language of instruction
English
Further Comments
Study Materials
The course is taught annually.
The course is also listed under the following terms Autumn 2019, Autumn 2020, autumn 2021, Autumn 2023, Spring 2024, Autumn 2024.
  • Enrolment Statistics (Autumn 2022, recent)
  • Permalink: https://is.muni.cz/course/sci/autumn2022/C9981