PřF:C4050 Analytical Chemistry II - Course Information
C4050 Analytical Chemistry II
Faculty of ScienceSpring 2009
- Extent and Intensity
- 2/0/0. 2 credit(s) (fasci plus compl plus > 4). Type of Completion: zk (examination).
- Teacher(s)
- prof. RNDr. Přemysl Lubal, Ph.D. (lecturer)
- Guaranteed by
- prof. RNDr. Viktor Kanický, DrSc.
Department of Chemistry – Chemistry Section – Faculty of Science - Timetable
- Tue 15:00–16:50 F1 6/1014
- Prerequisites
- C3100 Analytical Chemistry I
The prerequisite is passing of subjects Analytical chemistry I (C3100), Physical chemistry I (C3140), General chemistry (C1020), Inorganic chemistry I (C1061), Inorganic chemistry II (C2062), Organic chemistry I (C2021), Organic chemistry II (C3022) and relevant Laboratory courses from those subjects. - Course Enrolment Limitations
- The course is also offered to the students of the fields other than those the course is directly associated with.
- fields of study / plans the course is directly associated with
- Analytical Chemistry (programme PřF, B-CH)
- Analytical Chemistry (programme PřF, M-CH)
- Analytical Chemistry (programme PřF, N-CH)
- Inorganic Chemistry (programme PřF, B-CH)
- Inorganic Chemistry (programme PřF, M-CH)
- Inorganic Chemistry (programme PřF, N-CH)
- Applied Biochemistry (programme PřF, B-CH)
- Biochemistry (programme PřF, B-CH)
- Biochemistry (programme PřF, M-CH)
- Biochemistry (programme PřF, N-CH)
- Physical Chemistry (programme PřF, B-CH)
- Physical Chemistry (programme PřF, M-CH)
- Physical Chemistry (programme PřF, N-CH)
- Chemistry (programme PřF, M-CH)
- Chemistry (programme PřF, B-CH)
- Environmental Chemistry (programme PřF, B-CH)
- Environmental Chemistry (programme PřF, M-CH)
- Environmental Chemistry (programme PřF, N-CH)
- Macromolecular Chemistry (programme PřF, B-CH)
- Macromolecular Chemistry (programme PřF, M-CH)
- Macromolecular Chemistry (programme PřF, N-CH)
- Organic Chemistry (programme PřF, B-CH)
- Organic Chemistry (programme PřF, M-CH)
- Organic Chemistry (programme PřF, N-CH)
- Upper Secondary School Teacher Training in Chemistry (programme PřF, M-CH)
- Course objectives
- A systematic treatment of the basic principles of analytical chemistry for students of chemistry - part II. The course includes electroanalytical, optical and separation methods.
- Syllabus
- 1. Introduction into subject instrumental analytical chemistry. Evaluation of results of analysis - statistics and GLP knowledge. Physical properties and analytical signal, relationship of analytical signal and concentration, calibration curves and their evaluation, standardisation for relative physical methods. Parameters of analytical method (detection limit, limit of determination, sensitivity, robustness, , precision, accuracy, etc.). Rejection of outliers, circle test.
- 2. Chosen electroanalytical methods. Potentiometric methods, basic definitions and terms. Indicator and reference electrodes. pH determination. Potentiometric indication of course of titration and equivalence point. Acid-base, redox, precipitation, complexometric titrations with potentiometric indication. Potentiometric evaluation of equivalence point (Gran linearization of titration curve).
- 3. Conductometric methods - basic definitions and terms. Direct conductometry, application for conductometric determination of equivalence point. 4. Electrogravimetry, coulometry - basic definitions and terms. Polarisation curves, deposition current, faradaic current. Electrolysis under constant potential and constant current. Electrolytic separation of metals, determination of copper and silver. Calculations of potentials for deposition, coulometry under constant current. Coulometric titrations (absolute titration methods).
- 4. Voltametry, polarography - basic definition and terms. Polarographic analysis (quantitative and qualitative analysis). Examples of applications and determinations. Amperometric, biamperometric and bipotentiometric titrations. Karl-Fischer determination of water.
- 5. Chosen optical methods. Introduction - description of electromagnetic radiation, basic definition and terms, relationships (e.g. Bouger - Lambert-Beerův law), origin of absorption and emission of light. Division of optical analytical methods. It is necessary to know the light sources, dispersion elements, detectors, methodology.
- 6. Molecular absorption spectroscopy (UV, VIS, IR). Molecular scattering spectroscopy (turbidimetry and nephelometry). Luminescent methods.
- 7. Atomic absorption and emission spectroscopy.
- 8. Chosen separation methods. Solvent extraction - basic terms and definition. Extraction equilibria in two-phase system. Solvate extraction, ionic and nonionic substances. Analytical use of ion exchangers - basic terms and definition. Solid and liquid ion exchangers - characteristic, relationships and examples of the applications.
- 9. Chromatography on thin layer of sorbent (thin layer chromatography, paper chromatgraphy) - principles and examples of applications. Gas analysis - classic (principle and examples of applications), gas chromatography (theory, basic description of instrumentation, qualitative and quantitative analysis, examples of analytical applications).
- 10. HLPC - high performance chromatography (theory, basic description of instrumentation, qualitative and quantitative analysis, examples of analytical applications). 11. Electromigration methods (zone electrophoresis, electrophoresis on carriers and izotachophoresis} - basic definitions and terms, kinds of methods, basic description of instrumentation, examples of analytical applications). Mass spectrometry.
- 12. Foundations of analysis of organic compounds. Qualitative and quantitative characteristic - general principles. Elemental analysis, analysis of functional groups - examples, determination of compound purity, methodology for structure determination of organic compounds. Determination of compounds in more complex mixtures.
- Literature
- Sommer L a kol., Základy analytické chemie II, VUTium Brno 2000.
- Analytická příručka. Edited by Jaroslav Zýka. 4., upr. vyd. Praha: SNTL - Nakladatelství technické literatury, 1988, 831 s. info
- SKOOG, Douglas A. Fundamentals of analytical chemistry. 8th ed. Belmont, Calif.: Brooks/Cole, 2004, 1 sv. ISBN 0534417965. info
- HARRIS, Daniel C. Quantitative chemical analysis. 7th ed. New York: W. H. Freeman and Company, 2007, 1 sv. ISBN 0716776944. info
- Analytical chemistry : a modern approach to analytical science. Edited by Jean-Michel Mermet - Matthias Otto - M. Valcárcel Cases. 2nd ed. Weinheim: Wiley-VCH, 2004, xxviii, 11. ISBN 3527305904. info
- SCHWEDT, Georg. The essential guide to analytical chemistry. Translated by Brooks Haderlie. 2nd ed. Chichester: John Wiley & Sons, 1997, xii, 248. ISBN 0471974129. info
- CHRISTIAN, Gary D. Analytical chemistry. 6th ed. Hoboken, NJ: John Wiley & Sons, 2003, xix, 828 s. ISBN 0-471-21472-8. info
- Rouessac F., Rouessac A., Chemical Analysis. Modern Instrumentation Methods and Techniques, Wiley Chichester 2007.
- Enke Ch., The Art and Science of Chemical Analysis, Wiley New York 2001
- Assessment methods
- 2 hour lecture
combined exam (written and oral part) - Language of instruction
- Czech
- Follow-Up Courses
- Further comments (probably available only in Czech)
- Study Materials
The course is taught annually. - Listed among pre-requisites of other courses
- C1660 Basic Analytical Chemistry
!C3100 && !C4050 && !C5230 && !NOWANY(C3100,C4050,C5230) - C5190 Instrumental Analytical Chemistry II - laboratory course
(C4050||C1660)&&C7777&&(!C7640) - C5230 Analytical Chemistry
!C3100 && !C4050 && !NOWANY(C3100,C4050) - C5350 Analytical Chemistry III
C4050 - C5355 Analytical Chemistry III - seminar
C4050 && NOW(C5350)
- C1660 Basic Analytical Chemistry
- Enrolment Statistics (Spring 2009, recent)
- Permalink: https://is.muni.cz/course/sci/spring2009/C4050