C1660 Basic Analytical Chemistry

Faculty of Science
Autumn 2008
Extent and Intensity
2/0/0. 2 credit(s) (fasci plus compl plus > 4). Type of Completion: zk (examination).
Teacher(s)
prof. RNDr. Josef Komárek, DrSc. (lecturer)
Guaranteed by
prof. RNDr. Josef Komárek, DrSc.
Department of Chemistry – Chemistry Section – Faculty of Science
Timetable
Thu 17:00–18:50 U-aula
Prerequisites
Fundamental knowledge of chemistry
Course Enrolment Limitations
The course is also offered to the students of the fields other than those the course is directly associated with.
fields of study / plans the course is directly associated with
Course objectives
The main objectives of the course are the following: to understand analytical reactions, sampling and analytical methods used in practise. Classical, electrochemical, spectrochemical and separation methods.
Syllabus
  • 1. Analytical chemistry and chemical analysis. Sampling,sample dissolution, destruction of organic materials. Analytical reactions, chemical equilibrium, activity, ionic strength.
  • 2. Qualitative analysis.
  • 3. Gravimetric analysis, precipitation, determination of Fe.
  • 4. Volumetric analysis, equivalence point. Acid-base titrations. Acid-base equilibria, pH calculations, titration curves.
  • 5. Precipitation titrations, the solubility product, adsorption indicators.
  • 6. Complexometric titrations. Complexes, chelates, stability constant. Chelometric titrations, indicators, determination of Ca and Mg. Mercurimetric titrations.
  • 7. Redox titrations, oxidation and reduction, the Nernst equation. Permanganate, dichromate titrations, iodometry.
  • 8. Electroanalytical methods. Potentiometry, pH measurements, the glass pH electrode, ion-selective electrodes, potentiometric titrations, conductometric analysis.
  • 9. Polarography, voltammetry, anodic stripping voltammetry, coulometry.
  • 10. Molecular spectroscopy. Absorption spectrometry in UV/VIS regions, infrared spectrometry, Beer's Law.
  • 11. Fluorometry, phosphorimetry.
  • 12. Atomic spectroscopy. Atomic absorption spectrometry, emission spectroscopy, flame emission spectrometry, ICP.
  • 13. Electromigration methods. Chromatographic methods, classifications, gas chromatography.
  • 14. High-performance liquid chromatography.
Literature
  • Opekar, František - Jelínek, Ivan - Rychlovský, Petr - Plzák, Zbyněk. Základní analytická chemie. Univerzita Karlova v Praze, Nakladatelství Karolinum, Praha 2002. ISBN 80-246-0553-8.
  • HOLZBECHER, Záviš and Jaroslav CHURÁČEK. Analytická chemie. 1. vyd. Praha: Státní nakladatelství technické literatury, 1987, 663 s. info
  • SOMMER, Lumír. Teoretické základy analytické chemie. I. Brno: Vysoké učení technické, 1995. info
  • PÁNEK, Petr and Václav DOMBEK. Základy analytické chemie pro studenty ekologie. 1. vyd. Ostrava: Přírodovědecká fakulta Ostravské univerzity, 1994, 200 s. ISBN 8070427167. info
  • SKOOG, Douglas A., Donald M. WEST and James F. HOLLER. Analytical chemistry : an introduction. 6th ed. Philadelphia: Saunders College Publishing, 1994, 612 s. ISBN 0-03-097285-X. info
Assessment methods
Lectures. Examination consists of two parts: written and oral.
Language of instruction
Czech
Further Comments
The course is taught annually.
Listed among pre-requisites of other courses
The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Spring 2000, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2023, Autumn 2024.
  • Enrolment Statistics (Autumn 2008, recent)
  • Permalink: https://is.muni.cz/course/sci/autumn2008/C1660