C1660 Basic Analytical Chemistry

Faculty of Science
Autumn 2023
Extent and Intensity
2/0/0. 2 credit(s) (fasci plus compl plus > 4). Type of Completion: zk (examination).
Teacher(s)
doc. Mgr. Karel Novotný, Ph.D. (lecturer)
prof. RNDr. Josef Komárek, DrSc. (lecturer)
Guaranteed by
doc. Mgr. Karel Novotný, Ph.D.
Department of Chemistry – Chemistry Section – Faculty of Science
Supplier department: Department of Chemistry – Chemistry Section – Faculty of Science
Timetable
Tue 16:00–17:50 B11/205
Prerequisites
! C3100 Analytical Chemistry I && ! C4050 Analytical Chemistry II && ! C5230 Analytical Chemistry && !NOWANY( C3100 Analytical Chemistry I , C4050 Analytical Chemistry II , C5230 Analytical Chemistry )
Fundamental knowledge of chemistry
Course Enrolment Limitations
The course is offered to students of any study field.
Course objectives
The main objective of the course is to obtain an overview and knowledge in the field of analytical chemistry from classical methods to instrumental (electrochemical, spectrometric and separation) methods. At the end of the course, students should be able to: - understand the use of analytical reactions by analysis - choose technique of samples treatment - characterize parameters important by instrumental methods - compare capacities for classical, electrochemical, spectrometric and separation methods - gain an idea of practical application of methods
Learning outcomes
The student is able to: - utilize analytical reactions by analysis - characterize parameters important by instrumental methods - assess posibilities of practical use of classical, electrochemical, spectrometric and separation methods
Syllabus
  • 1. Analytical chemistry and chemical analysis. Sampling, sample dissolution, destruction of organic materials. Analytical reactions, chemical equilibrium, activity, ionic strength.
  • 2. Qualitative analysis.
  • 3. Gravimetric analysis, precipitation, determination of Fe.
  • 4. Volumetric analysis, equivalence point. Acid-base titrations. Acid-base equilibria, pH calculations, titration curves.
  • 5. Precipitation titrations, the solubility product, adsorption indicators.
  • 6. Complexometric titrations. Complexes, chelates, stability constant. Chelometric titrations, indicators, determination of Ca and Mg. Mercurimetric titrations.
  • 7. Redox titrations, oxidation and reduction, the Nernst equation. Permanganate, dichromate titrations, iodometry.
  • 8. Electroanalytical methods. Potentiometry, pH measurements, the glass pH electrode, ion-selective electrodes, potentiometric titrations, conductometric analysis.
  • 9. Polarography, voltammetry, anodic stripping voltammetry, coulometry.
  • 10. Molecular spectroscopy. Absorption spectrometry in UV/VIS regions, infrared spectrometry, Beer's Law.
  • 11. Fluorometry, phosphorimetry.
  • 12. Atomic spectroscopy. Atomic absorption spectrometry, emission spectroscopy, flame emission spectrometry, ICP.
  • 13. Electromigration methods. Chromatographic methods, classifications, gas chromatography.
  • 14. High-performance liquid chromatography.
Literature
  • HOLZBECHER, Záviš and Jaroslav CHURÁČEK. Analytická chemie. 1. vyd. Praha: Státní nakladatelství technické literatury, 1987, 663 s. info
  • SOMMER, Lumír. Teoretické základy analytické chemie. I. Brno: Vysoké učení technické, 1995. info
  • PÁNEK, Petr and Václav DOMBEK. Základy analytické chemie pro studenty ekologie. 1. vyd. Ostrava: Přírodovědecká fakulta Ostravské univerzity, 1994, 200 s. ISBN 8070427167. info
  • SKOOG, Douglas A., Donald M. WEST and James F. HOLLER. Analytical chemistry : an introduction. 6th ed. Philadelphia: Saunders College Publishing, 1994, 612 s. ISBN 0-03-097285-X. info
Teaching methods
Education is performed as lectures with PowerPoint presentation and a few video recording. Understanding of principles of analytical methods, measurements, data evaluation and the use in practical analysis is emphasized.
Assessment methods
Final assessment (at the end of semester) is by attendance written examination. It is not test but 25 questions, which frequently require description, explanation or schematization of asked topic. These questions include also example of pH calculation and example of titration. Questions have points according to their difficulty. Another possibility is a final oral examination in the distance form
Language of instruction
Czech
Further Comments
Study Materials
The course is taught annually.
Listed among pre-requisites of other courses
The course is also listed under the following terms Autumn 2007 - for the purpose of the accreditation, Autumn 1999, Spring 2000, Autumn 2010 - only for the accreditation, Autumn 2000, Autumn 2001, Autumn 2002, Autumn 2003, Autumn 2004, Autumn 2005, Autumn 2006, Autumn 2007, Autumn 2008, Autumn 2009, Autumn 2010, Autumn 2011, Autumn 2011 - acreditation, Autumn 2012, Autumn 2013, Autumn 2014, Autumn 2015, Autumn 2016, autumn 2017, Autumn 2018, Autumn 2019, Autumn 2020, autumn 2021, Autumn 2022, Autumn 2024.
  • Enrolment Statistics (Autumn 2023, recent)
  • Permalink: https://is.muni.cz/course/sci/autumn2023/C1660